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1.发明申请Process for the preparation of di- and polyamines of the diphenylmethane series 失效制备二苯基甲烷系列的二胺和多胺的方法公开(公告)号：US20060224018A1
公开(公告)日：2006-10-05
申请号：US11392367
申请日：2006-03-28
IPC分类号： C07C209/24
CPC分类号： C07C209/78 , C07C211/50
摘要： Di- and polyamines of the diphenylmethane series are prepared by a) mixing a first portion of aniline with an acid catalyst, b) mixing a second portion of aniline with formaldehyde, and c) mixing and reacting the mixtures prepared in each of steps a) and b). The diamines produced by this process may then be phosgenated to produce the corresponding di-/polyisocyanate.
摘要翻译： 二苯基甲烷系列的二胺和多胺通过以下步骤制备：a）将第一部分苯胺与酸催化剂混合，b）将第二部分苯胺与甲醛混合，和c）将在步骤a）中制备的混合物混合和反应， 和b）。 然后通过该方法产生的二胺可以光气化以产生相应的二 - 多异氰酸酯。
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2.发明授权Process for the preparation of di- and polyamines of the diphenylmethane series 失效制备二苯基甲烷系列的二胺和多胺的方法公开(公告)号：US07205439B2
公开(公告)日：2007-04-17
申请号：US11392367
申请日：2006-03-28
IPC分类号： C07C209/78 , C07C263/10
CPC分类号： C07C209/78 , C07C211/50
摘要： Di- and polyamines of the diphenylmethane series are prepared by a) mixing a first portion of aniline with an acid catalyst, b) mixing a second portion of aniline with formaldehyde, and c) mixing and reacting the mixtures prepared in each of steps a) and b). The diamines produced by this process may then be phosgenated to produce the corresponding di-/polyisocyanate.
摘要翻译： 二苯基甲烷系列的二胺和多胺通过以下步骤制备：a）将第一部分苯胺与酸催化剂混合，b）将第二部分苯胺与甲醛混合，和c）将在步骤a）中制备的混合物混合和反应， 和b）。 然后通过该方法产生的二胺可以光气化以产生相应的二 - 多异氰酸酯。
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3.发明申请Process for the preparation of polyamines of the diphenylmethane series at a low degree of protonation 有权在低质子化程度下制备二苯基甲烷系列的多胺的方法公开(公告)号：US20060287555A1
公开(公告)日：2006-12-21
申请号：US11170624
申请日：2005-06-29
申请人： Torsten Hagen , Daniel Koch , Hans-Georg Pirkl , Fritz Pohl , Stefan Wershofen , Rudolf Uchdorf , Richard Adamson
发明人： Torsten Hagen , Daniel Koch , Hans-Georg Pirkl , Fritz Pohl , Stefan Wershofen , Rudolf Uchdorf , Richard Adamson
IPC分类号： C07C209/26
CPC分类号： C08G18/7664 , C07C209/78 , C07C263/10 , C07C211/50 , C07C265/14
摘要： The invention provides a process for the preparation of polyamines of the diphenylmethane series. This process comprises a) reacting aniline and formaldehyde in a molar ratio of 1.5:1 to 6:1, in the presence of an acid catalyst at temperatures of 20° C. to 100° C., in which the water content in the acid reaction mixture is
摘要翻译： 本发明提供了制备二苯基甲烷系列多胺的方法。 该方法包括a）在酸催化剂存在下，在20℃至100℃的温度下，使摩尔比为1.5:1至6:1的苯胺和甲醛反应，其中酸中的水含量 反应混合物<20wt。 ％，质子化度<15％，b）当对氨基苄基苯胺的重量含量与4,4'-二苯胺的比例时，将反应温度升高至110℃至250℃。 '-MDA在反应混合物中低于1.00的值。
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4.发明授权Process for the preparation of polyamines of the diphenylmethane series at a low degree of protonation 有权在低质子化程度下制备二苯基甲烷系列的多胺的方法公开(公告)号：US07253321B2
公开(公告)日：2007-08-07
申请号：US11170624
申请日：2005-06-29
申请人： Torsten Hagen , Daniel Koch , Hans-Georg Pirkl , Fritz Pohl , Stefan Wershofen , Rudolf Uchdorf , Richard Adamson
发明人： Torsten Hagen , Daniel Koch , Hans-Georg Pirkl , Fritz Pohl , Stefan Wershofen , Rudolf Uchdorf , Richard Adamson
IPC分类号： C07C209/78
CPC分类号： C08G18/7664 , C07C209/78 , C07C263/10 , C07C211/50 , C07C265/14
摘要： The invention provides a process for the preparation of polyamines of the diphenylmethane series. This process comprises a) reacting aniline and formaldehyde in a molar ratio of 1.5:1 to 6:1, in the presence of an acid catalyst at temperatures of 20° C. to 100° C., in which the water content in the acid reaction mixture is
摘要翻译： 本发明提供了制备二苯基甲烷系列多胺的方法。 该方法包括a）在酸催化剂存在下，在20℃至100℃的温度下，使摩尔比为1.5:1至6:1的苯胺和甲醛反应，其中酸中的水含量 反应混合物<20wt。 ％，质子化度<15％，b）当对氨基苄基苯胺的重量含量与4,4'-二苯胺的比例时，将反应温度升高至110℃至250℃。 '-MDA在反应混合物中低于1.00的值。
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5.发明授权Process for the production of polyisocyanates of the diphenylmethane series by phosgenation of non-neutralized polyamine of the diphenylmethane series 失效通过二苯基甲烷系列的非中和多胺的光气化生产二苯基甲烷系列的多异氰酸酯的方法公开(公告)号：US07041776B2
公开(公告)日：2006-05-09
申请号：US10672440
申请日：2003-09-26
申请人： Daniel Koch , Hans-Georg Pirkl , Torsten Hagen , Stefan Wershofen
发明人： Daniel Koch , Hans-Georg Pirkl , Torsten Hagen , Stefan Wershofen
IPC分类号： C08G12/06
CPC分类号： C08G18/7664 , C07C209/78 , C07C263/10 , C07C265/14
摘要： The invention relates to a method of producing polyisocyanates of the diphenylmethane series including the steps of a) reacting aniline and formaldehyde in the presence of HCl to provide a product mixture containing polyamines of the diphenylmethane series, HCl, aniline and water; b) removing excess aniline and water by distillation to provide a product mixture comprising polyamines of the diphenylmethane series, HCl, no more than 10 wt. % aniline based on the polyamines, and no more than 5 wt. % water based on the polyamines; and c) phosgenating the product mixture in (b).
摘要翻译： 本发明涉及一种生产二苯基甲烷系列的多异氰酸酯的方法，包括以下步骤：a）在HCl存在下使苯胺和甲醛反应，得到含有二苯基甲烷系列，HCl，苯胺和水的多胺的产物混合物; b）通过蒸馏除去过量的苯胺和水，以提供包含二苯基甲烷系列的多胺（HCl）的产物混合物，不超过10wt。 基于多胺的％苯胺，不超过5重量％ 基于多胺的％水; 和c）使（b）中的产物混合物光气化。
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6.发明授权Process for producing polyisocyanates of the diphenyl methane series having a reduced color value 有权具有降低的颜色值的二苯基甲烷系列的多异氰酸酯的制备方法公开(公告)号：US06639102B2
公开(公告)日：2003-10-28
申请号：US10384890
申请日：2003-03-10
IPC分类号： C07C26310
CPC分类号： C08G18/7664 , C07C209/78 , C07C263/10 , C07C211/50 , C07C265/14
摘要： Polyisocyanates of the diphenyl methane series having reduced color values are obtained by a) reacting aniline and formaldehyde in the presence of an acid catalyst to form a polyamine, b) neutralizing the reaction mixture containing polyamine with a base, c) separating the neutralized mixture into the aqueous and the organic phases, d) adding a base to the organic phase and then e) phosgenating the resulting polyamine to produce the corresponding polyisocyanate.
摘要翻译： 通过a）在酸催化剂存在下使苯胺和甲醛反应形成多胺，b）使含有多胺的反应混合物与碱中和，c）将中和的混合物分离成 水相和有机相，d）向有机相中加入碱，然后e）使得到的多胺光气化以产生相应的多异氰酸酯。
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7.发明授权Process for the production of polyisocyanates of the diphenylmethane series with a reduced color value 失效用于生产具有降低的颜色值的二苯基甲烷系列的多异氰酸酯的方法公开(公告)号：US06720455B2
公开(公告)日：2004-04-13
申请号：US10224003
申请日：2002-08-20
IPC分类号： C07C20984
CPC分类号： C08G18/7664 , C07C209/78 , C07C263/10 , C07C211/50 , C07C265/14
摘要： Polyisocyanates of the diphenylmethane series are produced by a) reacting aniline and formaldehyde in the presence of an acidic catalyst to produce a polyamine, b) neutralizing the reaction mixture from step a) with a base at a temperature of more than 110° C. or neutralizing the reaction mixture from step a) with a base and heating the neutralized mixture to a temperature of more than 110° C., and c) phosgenating the polyamine from step b) to convert it to the corresponding polyisocyanate.
摘要翻译： 二苯基甲烷系列的多异氰酸酯通过以下方法制备：a）在酸性催化剂存在下使苯胺和甲醛反应以产生多胺，b）用碱在大于110℃的温度下使步骤a）中的反应混合物中和;或 将来自步骤a）的反应混合物与碱中和并将中和的混合物加热至大于110℃的温度，和c）将来自步骤b）的多胺光气化以将其转化为相应的多异氰酸酯。
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公开(公告)号：US09353386B2
公开(公告)日：2016-05-31
申请号：US14125409
申请日：2012-06-15
申请人： Daniel Koch , Guido Meurer , Jürgen Eck
发明人： Daniel Koch , Guido Meurer , Jürgen Eck
CPC分类号： C12P7/24 , C12N9/0006 , C12N9/0008 , C12N9/13 , C12P7/18 , C12Y101/01077 , C12Y102/01 , C12Y208/03001 , Y02P20/52
摘要： The present invention relates to a host cell having an elevated expression or activity of an enzyme as compared with the parent cell from which it has been derived, said enzyme having lactoyl-CoA reductase activity. Furthermore, provided is a method of producing lactaldehyde and/or 1,2-propanediol, said method comprising culturing said host cell and/or utilizing said enzyme to produce said compound.
摘要翻译： 本发明涉及一种具有升高的酶表达或活性的宿主细胞，与其衍生的亲本细胞相比，所述酶具有乳酰基-CoA还原酶活性。 此外，提供了生产乳醛和/或1,2-丙二醇的方法，所述方法包括培养所述宿主细胞和/或利用所述酶产生所述化合物。
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公开(公告)号：US20070069742A1
公开(公告)日：2007-03-29
申请号：US11236369
申请日：2005-09-27
申请人： Rajesh Iyer , Ryan Jensen , Curtis Burgardt , Susan Tettemer , Daniel Koch , Simon Goldman
发明人： Rajesh Iyer , Ryan Jensen , Curtis Burgardt , Susan Tettemer , Daniel Koch , Simon Goldman
IPC分类号： G01R27/08
CPC分类号： G01R1/0408 , A61N1/08 , A61N1/37 , G01R27/02 , G01R31/2822
摘要： A determination of an equivalent series resistance (ESR) effect for high frequency filtering performance of a filtered feed-through assembly is described. A low frequency signal is introduced to a filtered feed-through assembly. ESR limit of the filtered feed-through is determined based on the low frequency signal.
摘要翻译： 描述了对过滤的馈通组件的高频滤波性能的等效串联电阻（ESR）效应的确定。 将低频信号引入过滤的馈通组件。 基于低频信号确定滤波后的馈通的ESR限制。
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10.发明授权Hydroformylation with unmodified rhodium catalysts in supercritical carbon dioxide 失效在超临界二氧化碳中用未改性的铑催化剂加氢甲酰化公开(公告)号：US06388141B1
公开(公告)日：2002-05-14
申请号：US09462855
申请日：2000-01-13
申请人： Walter Leitner , Daniel Koch
发明人： Walter Leitner , Daniel Koch
IPC分类号： C07C4550
CPC分类号： C07C403/14 , B01J31/20 , B01J31/2226 , B01J31/2234 , B01J31/2282 , B01J31/2295 , B01J2231/321 , B01J2531/0205 , B01J2531/822 , B01J2531/922 , C07C45/50 , C07C67/293 , C07C67/343 , C07C2601/16 , Y02P20/544 , C07C69/14 , C07C69/716 , C07C47/02
摘要： The present invention relates to processes for the preparation of oxo products by the hydroformylation of substrates having C═C double bonds using unmodified rhodium catalysts in a reaction mixture essentially consisting of the substrates, the catalyst and carbon dioxide in a supercritical state (scCO2). In particular, the invention relates to such processes for the preparation of products which contain substantial proportions of branched i-oxo products. Further, the invention relates to such processes for the hydroformylation of substrates which do not correspond to the general formula CnH2n. The invention further relates to such processes in which the separation of product and catalyst is effected using the special solvent properties of scCO2.
摘要翻译： 本发明涉及通过使用未改性的铑催化剂在基本上由底物，催化剂和超临界状态的二氧化碳（scCO2）组成的反应混合物中，通过使用C = C双键加成甲基化制备羰基合成产物的方法。 特别地，本发明涉及制备含有相当比例的支链α-氧代产物的产物的这种方法。 此外，本发明涉及用于不对应于通式C n H 2n的底物的加氢甲酰化的这种方法。 本发明还涉及使用scCO 2的特殊溶剂性质来分离产物和催化剂的方法。
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