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    Hydroformylation with unmodified rhodium catalysts in supercritical carbon dioxide
    4.
    发明授权
    Hydroformylation with unmodified rhodium catalysts in supercritical carbon dioxide 失效
    在超临界二氧化碳中用未改性的铑催化剂加氢甲酰化

    公开(公告)号：US06388141B1

    公开(公告)日：2002-05-14

    申请号：US09462855

    申请日：2000-01-13

    申请人： Walter Leitner ,  Daniel Koch

    发明人： Walter Leitner ,  Daniel Koch

    IPC分类号： C07C4550

    CPC分类号： C07C403/14 ,  B01J31/20 ,  B01J31/2226 ,  B01J31/2234 ,  B01J31/2282 ,  B01J31/2295 ,  B01J2231/321 ,  B01J2531/0205 ,  B01J2531/822 ,  B01J2531/922 ,  C07C45/50 ,  C07C67/293 ,  C07C67/343 ,  C07C2601/16 ,  Y02P20/544 ,  C07C69/14 ,  C07C69/716 ,  C07C47/02

    摘要： The present invention relates to processes for the preparation of oxo products by the hydroformylation of substrates having C═C double bonds using unmodified rhodium catalysts in a reaction mixture essentially consisting of the substrates, the catalyst and carbon dioxide in a supercritical state (scCO2). In particular, the invention relates to such processes for the preparation of products which contain substantial proportions of branched i-oxo products. Further, the invention relates to such processes for the hydroformylation of substrates which do not correspond to the general formula CnH2n. The invention further relates to such processes in which the separation of product and catalyst is effected using the special solvent properties of scCO2.

    摘要翻译： 本发明涉及通过使用未改性的铑催化剂在基本上由底物，催化剂和超临界状态的二氧化碳（scCO2）组成的反应混合物中，通过使用C = C双键加成甲基化制备羰基合成产物的方法。 特别地，本发明涉及制备含有相当比例的支链α-氧代产物的产物的这种方法。 此外，本发明涉及用于不对应于通式C n H 2n的底物的加氢甲酰化的这种方法。 本发明还涉及使用scCO 2的特殊溶剂性质来分离产物和催化剂的方法。

    TIME BASE DEVICE FOR A WATCH
    6.
    发明申请
    TIME BASE DEVICE FOR A WATCH 有权
    用于手表的时基设备

    公开(公告)号：US20100080088A1

    公开(公告)日：2010-04-01

    申请号：US12563675

    申请日：2009-09-21

    申请人： Daniel Koch

    发明人： Daniel Koch

    IPC分类号： G04F5/06 ,  G04F5/00

    CPC分类号： G04C3/008 ,  G04C3/14 ,  G04F5/063 ,  G04G17/00

    摘要： The time base device for a watch includes at least one electric motor coil (30), an electronic module (1) that has at least one time base oscillator circuit mounted in a case of the module, and an electric power source (8). The electric motor coil (30), the electronic module (1) with an oscillator circuit and the voltage source (8), which is preferably a battery, are connected to each other mechanically and electrically without the use of a printed circuit board to form a compact unit. The electronic module includes four connection terminals (14, 15, 16, 17) on an external surface for connecting the voltage source on one side and the wires (31, 32) of a winding of the coil (30) on the other side.

    摘要翻译： 手表的时基装置包括至少一个电动机线圈（30），具有安装在模块的情况下的至少一个时基振荡器电路的电子模块（1）和电源（8）。 电动机线圈（30），具有振荡电路的电子模块（1）和优选为电池的电压源（8）在不使用印刷电路板的情况下机械地和电气地彼此连接形成 一个紧凑的单位。 电子模块包括在外表面上的四个连接端子（14,15,16,17），用于将一侧上的电压源和另一侧的线圈（30）的绕组的线（31,32）连接。

    Analogue display timeplace able to provide alphanumerical information concerning the state of an operation mode or of a programmed event
    9.
    发明授权
    Analogue display timeplace able to provide alphanumerical information concerning the state of an operation mode or of a programmed event 失效
    模拟显示时计能够提供关于操作模式或编程事件的状态的字母数字信息

    公开(公告)号：US5465239A

    公开(公告)日：1995-11-07

    申请号：US303460

    申请日：1994-09-09

    申请人： Daniel Koch

    发明人： Daniel Koch

    IPC分类号： G04B19/00 ,  G04B19/04 ,  G04B45/00 ,  G04C3/00 ,  G04C3/14 ,  G04B23/02

    CPC分类号： G04B45/0007 ,  G04B19/04 ,  G04C3/146

    摘要： An analogue display timepiece having at least one operation mode, time-related or non time-related, and able to provide information relating to the state of this mode and/or the state of a programmed event linked to the latter. The timepiece includes at least two analogue display organs providing an hour hand (H) and a minute hand (MN), an electronic control (22) to control the operation mode, and a display arrangement capable of providing the user with at least one alphanumerical message informing him of the state of the mode and/or the state of the event. The state display arrangement is formed by the hands (H, MN) themselves which, as a function of their relative angular position driven under the control of the electronic control (22), can act structurally upon the message to make it intelligible in the selected angular position of the hands.

    摘要翻译： 具有至少一种操作模式，时间相关或非时间相关的模拟显示时计，能够提供与该模式的状态有关的信息和/或与后者相关联的编程事件的状态。 该钟表包括提供时针（H）和分针（MN）的至少两个模拟显示器具，用于控制操作模式的电子控制器（22）以及能够向用户提供至少一个字母数字 消息通知他状态和/或事件的状态。 状态显示装置由手（H，MN）本身形成，它们作为在电子控制（22）的控制下驱动的它们的相对角度位置的函数，可在结构上对该消息起作用以使其在选定的 手的角位置。

    Analog timepiece including means for signalling a change of mode
    10.
    发明授权
    Analog timepiece including means for signalling a change of mode 失效
    模拟时计包括用于发信号通知模式改变的装置

    公开(公告)号：US5379281A

    公开(公告)日：1995-01-03

    申请号：US119587

    申请日：1993-09-13

    申请人： Daniel Koch

    发明人： Daniel Koch

    IPC分类号： G04B19/00 ,  G04C3/00 ,  G04C3/14 ,  G04C9/08 ,  G04B23/02

    CPC分类号： G04C3/14

    摘要： The invention concerns a timepiece. Such timepiece exhibits at least two selectable modes of operation, a first referred to as time and a second referred to as nontime, and it comprises at least one hours hand (h) and one minutes hand (m) capable of being independently actuated by motor means (18, 20), electronic management means (22) for said modes of operation and an external control organ capable of operating on said management means, such timepiece being characterized in that it includes visual means for signalling entry into the non-time mode of operation, such signalling means being formed by said hours (h) and minutes (m) hands acting in an automatic and systematic fashion at least, upon entry into the nontime operating mode. The invention is applicable to an electronic timepiece having an analog display.

    摘要翻译： 本发明涉及一种钟表。 这种钟表具有至少两种可选择的操作模式，首先被称为时间，另一种被称为非时间，并且它包括能够被马达独立地驱动的至少一小时手（h）和一分钟手（m） 装置（18,20），用于所述操作模式的电子管理装置（22）和能够在所述管理装置上操作的外部控制装置，其特征在于，其包括可视装置，用于信令进入非时间模式 至少在进入非时间操作模式时，这种信令装置由所述时间（h）和分钟（m）形成，手以自动和系统的方式起作用。 本发明适用于具有模拟显示器的电子钟表。