摘要:
A method and system for desulfurizing flue gas in which desulfurization is effected by bringing absorbent slurry containing limestone into contact with flue gas. The method classifies absorbent slurry extracted from a desulfurization absorber, returns a fine-side fluid to the desulfurization absorber, and sends a coarse-side fluid to a solid-liquid separator. Supplied limestone powder is mixed to yield limestone slurry by a solid-liquid mixer, and the limestone slurry is classified, sending the small-particle fluid component thereof to the desulfurization absorber, and sending the large-particle fluid component thereof to a limestone fine grinder. And, limestone contained in the large-particle fluid component is finely ground by the limestone fine grinder and the finely ground limestone is sent to the desulfurization absorber. According to the desulfurization method and system, the concentration of limestone in the desulfurization absorber is increased while the concentration of residual limestone in by-product gypsum is kept low, whereby the desulfurization performance of the absorber can be enhanced, and the operation power for the whole system can be decreased.
摘要:
A method of producing solid molding products from a slurry which has undergone absorption in wet-limestone gypsum desulfurization of flue gas includes the steps of concentrating the gypsum-containing absorption slurry, mixing and kneading the solid concentrated slurry with flyash and quicklime or slaked lime, molding the mixture into a given shape using a mold and then curing a resulting molding product in a reaction chamber wherein a part of desulfurized gas is passed. The method also includes solidifying a molded product by drying with water-saturated hot air produced with heat recovered from the flue gas and with water added into a heat recovery process.
摘要:
A method for desulfurizing an exhaust gas containing SO.sub.2 and NO.sub.x in accordance with a wet lime process, the aforesaid desulfurizing method being characterized by comprising the steps of drawing a part of an absorbing slurry, subjecting a filtrate obtained by the solid-liquid separation of the drawn absorbing slurry to an electrolysis treatment in the presence of chlorine ions, or after adjusting the filtrate to pH 3-4, mixing a hydrochlorite with the filtrate, and then refeeding the filtrate as a make-up water to an absorbing tower.
摘要:
For the purposes of solving a problem due to a fly ash and HF in an exhaust gas, maintaining the activity of calcium carbonate as an absorbent, and recovering a high-purity gypsum, there is here provided a method for desulfurizing an exhaust smoke which comprises the steps of leading the exhaust gas containing the fly ash to a gas absorbing step, removing SO.sub.2 and the fly ash from the exhaust gas by the use of an absorbing solution slurry containing calcium carbonate as an absorbent in the gas absorbing step, and blowing air into the absorbing solution slurry circulating through the gas absorbing step to oxidize it and to thereby produce the gypsum, the aforesaid method being characterized by drawing a portion of the absorbing solution slurry therefrom, leading it to a magnetic field to separate and recover the fly ash from the absorbing solution slurry, and then returning, to the gas absorbing step, a portion or all of the absorbing solution slurry from which the fly ash has been separated.
摘要:
A wet-type exhaust gas desulfurization system comprises a reservoir for trapping an absorbing solution which has absorbed SO.sub.2 from exhaust gas; an absorbing solution circulating tank disposed directly under the reservoir; a plurality of bottom pipes which are installed at the bottom of reservoir and extend downward into the absorbing solution in the circulating tank and whose lower end is open, or drop pipes which depend into the absorbing solution and whose lower ends are open; and air supply pipe at least one end of which is open to the atmosphere; a pipe for discharging the air above the surface of absorbing solution onto the surface of solution in the reservoir; and a pipe for supplying the absorbing solution in the circulating tank to a spray nozzle at the upper part of the absorbing tower.
摘要:
Five combustion exhaust gas treatment systems capable of removing dust and selenium (Se) in combustion exhaust gas and making harmless are proposed: (1) combustion exhaust gas is cooled to 350° C. or less, dust is separated, Se is transformed into insoluble compound, and Se is separated; (2) combustion exhaust gas is cooled to 350° C. or less, dust is separated, Se elution preventive agent is added, and dust is formed into scale; (3) dust in combustion exhaust gas is collected by dust collector, dust is formed into slurry by making use of part of circulation liquid in desulfurization apparatus, and tetravalent Se in dust slurry is transformed into insoluble compound, which is separated into solid and liquid; (4) dust is separated from combustion exhaust gas by dust collector, and it is heated to gasify Se, and is led into desulfurization apparatus, etc., and formed into slurry, and Se is made into insoluble compound; and (5) a treating agent for making tetravalent Se insoluble is added to part of circulation liquid in desulfurization apparatus, and it is sprayed into combustion exhaust gas to make Se insoluble.
摘要:
In a flue gas treating system, an absorption tower (21), a reheating section (22) and a fan (23) are arranged in line on a vertical axis so as to function as at least a part of a stack for emitting the treated flue gas into the atmosphere. Moreover, in a flue gas treating process, the amount of ammonia injected in the denitration step (a denitrator (2)) and/or the amount of ammonia at a point downstream of the denitration step are determined so as to be on such an excessive level that ammonia or ammonium salt will remain in the flue gas introduced into the desulfurization step (absorption tower (21)). Thus, the size and cost of the equipment can be reduced.
摘要:
Five combustion exhaust gas treatment systems capable of removing dust and selenium (Se) in combustion exhaust gas and making harmless are proposed: (1) combustion exhaust gas is cooled to 350° C. or less, dust is separated, Se is transformed into insoluble compound, and Se is separated; (2) combustion exhaust gas is cooled to 350° C. or less, dust is separated, Se elution preventive agent is added, and dust is formed into scale; (3) dust in combustion exhaust gas is collected by dust collector, dust is formed into slurry by making use of part of circulation liquid in desulfurization apparatus, and tetravalent Se in dust slurry is transformed into insoluble compound, which is separated into solid and liquid; (4) dust is separated from combustion exhaust gas by dust collector, and it is heated to gasify Se, and is led into desulfurization apparatus, etc., and formed into slurry, and Se is made into insoluble compound; and (5) a treating agent for making tetravalent Se insoluble is added to part of circulation liquid in desulfurization apparatus, and it is sprayed into combustion exhaust gas to make Se insoluble.
摘要:
A gas-liquid contacting apparatus in which spray nozzles for spraying slurry solution upward are arranged in a tower body through which gas passes, wherein a liquid inlet portion of the spray nozzle is of a bell shape having a radius of curvature of 0.2 times or more of the diameter of a liquid discharge port of the spray nozzle, and a ceramic nozzle support structure comprises: (A) a ceramic nozzle having a ridge portion on the outer peripheral surface of a nozzle body; (B) a tightening flange including a flange body having an aperture larger than the outside shape of the nozzle body and a central cylindrical portion extending substantially concentrically with the nozzle body from lower surface of the flange body, the tightening flange having through holes in the wall of central cylindrical portion thereof; (C) a support nozzle consisting of a cylindrical body having an inside diameter larger than the central cylindrical portion of tightening flange and connected to the tightening flange by bolting via the flange body at the upper portion of the cylindrical body; and (D) an elastomeric resin filled in a space between the nozzle and the support nozzle so that the outside and inside of the central cylindrical portion of tightening flange are integrated via the through holes.
摘要:
Five combustion exhaust gas treatment systems capable of removing dust and selenium (Se) in combustion exhaust gas and making harmless are proposed: (1) combustion exhaust gas is cooled to 350° C. or less, dust is separated, Se is transformed into insoluble compound, and Se is separated; (2) combustion exhaust gas is cooled to 350° C. or less, dust is separated, Se elution preventive agent is added, and dust is formed into scale; (3) dust in combustion exhaust gas is collected by dust collector, dust is formed into slurry by making use of part of circulation liquid in desulfurization apparatus, and tetravalent Se in dust slurry is transformed into insoluble compound, which is separated into solid and liquid; (4) dust is separated from combustion exhaust gas by dust collector, and it is heated to gasify Se, and is led into desulfurization apparatus, etc., and formed into slurry, and Se is made into insoluble compound; and (5) a treating agent for making tetravalent Se insoluble is added to part of circulation liquid in desulfurization apparatus, and it is sprayed into combustion exhaust gas to make Se insoluble.