公开(公告)号：US5055491A

公开(公告)日：1991-10-08

申请号：US503664

申请日：1990-04-02

申请人： Toshihiko Yano ,  Takao Ishiwatari ,  Hiroko Sekihachi ,  Noritada Matsuo ,  Tohei Takagaki ,  Akiko Kakimizu

发明人： Toshihiko Yano ,  Takao Ishiwatari ,  Hiroko Sekihachi ,  Noritada Matsuo ,  Tohei Takagaki ,  Akiko Kakimizu

IPC分类号： A01N53/00 ,  A01N53/10 ,  C07C69/743

CPC分类号： A01N53/00 ,  C07C69/743

摘要： This invention relates to novel carboxylic acid esters represented by the formula (I) below, methods for their production and insecticides and/or acaricides containing them as an active ingredient, ##STR1## wherein R.sup.1 represents a hydrogen atom, a fluorine atom or a methyl group; and R.sup.2 represents a C.sub.1-5 alkyl group, a C.sub.3-6 cycloalkyl group, a C.sub.3-6 alkenyl group, a C.sub.3-6 alkynyl group or a C.sub.1-5 haloalkyl group.

公开(公告)号：US5019595A

公开(公告)日：1991-05-28

申请号：US585627

申请日：1990-09-20

申请人： Toshihiko Yano ,  Yoko Torisu ,  Hiroko Sekihachi ,  Noritada Matsuo ,  Tohei Takagaki ,  Kazunori Tsushima

发明人： Toshihiko Yano ,  Yoko Torisu ,  Hiroko Sekihachi ,  Noritada Matsuo ,  Tohei Takagaki ,  Kazunori Tsushima

IPC分类号： C07C69/743 ,  A01N53/00 ,  A01N53/02 ,  A01N53/10

CPC分类号： A01N53/00

摘要： This invention relates to a novel carboxylic acid esters represented by the formula (I) below and insecticides containing them as an active ingredient, ##STR1## wherein R represents a C.sub.1-5 alkyl group, a C.sub.3-6 cycloalkyl group, a C.sub.3-6 alkenyl group, a C.sub.3-6 alkynyl group or a C.sub.1-5 haloalkyl group.

公开(公告)号：US5130136A

公开(公告)日：1992-07-14

申请号：US745359

申请日：1991-08-15

申请人： Yoshinori Shono ,  Keisuke Watanabe ,  Hiroko Sekihachi ,  Akiko Kakimizu ,  Masaya Suzuki ,  Noritada Matsuo

发明人： Yoshinori Shono ,  Keisuke Watanabe ,  Hiroko Sekihachi ,  Akiko Kakimizu ,  Masaya Suzuki ,  Noritada Matsuo

IPC分类号： A01N31/06

CPC分类号： A01N31/06 ,  Y10S424/10 ,  Y10S514/919

摘要： An insect repellent comprising as an active ingredient a monoterpenediol compound having the formula, ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 have either one of the following definitions:(i) all of R.sub.1, R.sub.2 and R.sub.3 are hydrogen,(ii) R.sub.1 is hydrogen and R.sub.2 and R.sub.3, taken together, form a carbon-carbon single bond, or(iii) R.sub.2 is hydrogen, R.sub.1 and R.sub.3, taken together, form a carbon-carbon single bond, and the hydroxyl bonded to the carbon atom marked with an asterisk takes an .alpha.-configuration.

摘要翻译： 一种驱虫剂，其包含具有下式的单萜二醇化合物作为活性成分：其中R1，R2和R3具有以下定义之一：（ⅰ）R1，R2和R3全部为氢，（ⅱ）R1为 氢和R 2和R 3一起形成碳 - 碳单键，或（iii）R 2是氢，R 1和R 3一起形成碳 - 碳单键，并且与标记有碳原子的碳原子键合的羟基 一个星号需要一个alpha配置。

公开(公告)号：US4985457A

公开(公告)日：1991-01-15

申请号：US359395

申请日：1989-05-31

申请人： Hiroko Kishino ,  Noritada Matsuo ,  Tohei Takagaki ,  Kazunori Tsushima ,  Toshihiko Yano ,  Yoko Torisu

发明人： Hiroko Kishino ,  Noritada Matsuo ,  Tohei Takagaki ,  Kazunori Tsushima ,  Toshihiko Yano ,  Yoko Torisu

IPC分类号： C07C69/743 ,  A01N53/00 ,  A01N53/02 ,  A01N53/10

CPC分类号： A01N53/00

摘要： This invention relates to novel carboxylic acid esters represented by the formula (I) below, methods for their production and insecticides and/or acaricides containing them as an active ingredient, ##STR1## wherein R.sup.1 represents a C.sub.1-5 alkyl group, a C.sub.2-4 alkenyl group or a C.sub.2-4 alkynyl group; R.sup.2 represents a fluorine atom or a methyl group; and R.sup.3 represents a hydrogen atom or a methyl group.

公开(公告)号：US5225605A

公开(公告)日：1993-07-06

申请号：US897064

申请日：1992-06-11

申请人： Tohei Takagaki ,  Noritada Matsuo

发明人： Tohei Takagaki ,  Noritada Matsuo

IPC分类号： B01J31/30 ,  C07B61/00 ,  C07C45/62 ,  C07C45/68 ,  C07C49/707 ,  C07C49/743

CPC分类号： C07C45/62 ,  C07C45/68

摘要： Pyrethrolone of the formula [II], ##STR1## is produced by reacting a cyclopentenolone derivative of the formula [I], ##STR2## with zinc in an aqueous alcohol solvent. And the cyclopentenolone derivative of the formula [I] is produced by reacting a propargylcyclopentenolone derivative of the formula [III], ##STR3## with vinyl halide in the presence of a palladium catalyst, a copper catalyst and a tertiary amine. These processes permit easy production of pyrethrolone of the formula [II] and an intermediate compound of the formula [I] for the production of the pyrethrolone.

公开(公告)号：US4496586A

公开(公告)日：1985-01-29

申请号：US543226

申请日：1983-10-20

申请人： Masanao Matsui ,  Liau Chun-Eng ,  Kunio Kogami ,  Toshihiko Yano ,  Noritada Matsuo

发明人： Masanao Matsui ,  Liau Chun-Eng ,  Kunio Kogami ,  Toshihiko Yano ,  Noritada Matsuo

IPC分类号： C07C69/743 ,  A01N53/00 ,  A01N53/10 ,  C07C45/59 ,  C07C45/67 ,  C07D307/42 ,  C07C69/747

CPC分类号： C07D307/42 ,  A01N53/00 ,  C07C45/59 ,  C07C45/67

摘要： The present invention relates to carboxylic acid esters of the formula (I), ##STR1## wherein R.sub.1 is a hydrogen atom or a methyl group, and when R.sub.1 is a hydrogen atom, R.sub.2 is a group of the formula, ##STR2## (in which X is a methyl group, a chlorine, bromine or fluorine atom), and when R.sub.1 is a methyl group, R.sub.2 is a methyl group; and Y is a 1-methyl-2-propenyl, 1-methyl-2-propynyl, 2-cyclopentenyl or 2-cyclohexenyl group, and their production and use as an insecticide.

摘要翻译： 本发明涉及式（I）的羧酸酯，其中R1是氢原子或甲基，当R1是氢原子时，R2是下式的基团：IMAGE >（其中X为甲基，氯，溴或氟原子），当R 1为甲基时，R 2为甲基; Y是1-甲基-2-丙烯基，1-甲基-2-丙炔基，2-环戊烯基或2-环己烯基，它们的生产和用作杀虫剂。

公开(公告)号：US5091183A

公开(公告)日：1992-02-25

申请号：US577103

申请日：1990-09-04

申请人： Toshihiko Yano ,  Noritada Matsuo ,  Yoko Torisu ,  Kazunobu Dohara

发明人： Toshihiko Yano ,  Noritada Matsuo ,  Yoko Torisu ,  Kazunobu Dohara

IPC分类号： A01N53/00 ,  A01N53/02 ,  A01N53/08

CPC分类号： A01N53/00

摘要： An insecticidal and/or acaricidal composition comprising as active ingredients 2-methyl-4-oxo-3-(2-propynyl)cyclopent-2-enyl chrysanthemate and a phenoxybenzyl ester compound having the formula [I], ##STR1## wherein R.sup.1 is hydrogen or cyano, R.sup.2 is hydrogen or fluorine, and X is chlorine or bromine, is markedly effective against insect pests having a low sensitivity to pyrethroid and acarine pests which cannot be effectively controlled by the use of a single agent.

摘要翻译： 包含作为活性成分的2-甲基-4-氧代-3-（2-丙炔基）环戊-2-烯基菊酸酯和具有式[I]的苯氧基苄基酯化合物的杀虫和/或杀螨组合物， 其中R1为氢或氰基，R2为氢或氟，X为氯或溴，对拟除虫菊酯和螨类害虫的敏感性较低的昆虫害虫显着有效，这不能通过使用单一药剂进行有效控制。

公开(公告)号：US4772633A

公开(公告)日：1988-09-20

申请号：US831180

申请日：1986-02-20

申请人： Noritada Matsuo ,  Kazunori Tsushima ,  Sumio Nishida ,  Toshihiko Yano ,  Masachika Hirano

发明人： Noritada Matsuo ,  Kazunori Tsushima ,  Sumio Nishida ,  Toshihiko Yano ,  Masachika Hirano

IPC分类号： C07C43/20 ,  A01N31/14 ,  A01N31/16 ,  A01N33/10 ,  A01N37/00 ,  A01N43/30 ,  A01N43/40 ,  C07C1/00 ,  C07C1/30 ,  C07C15/12 ,  C07C17/00 ,  C07C17/25 ,  C07C17/26 ,  C07C22/00 ,  C07C22/08 ,  C07C25/02 ,  C07C25/13 ,  C07C25/18 ,  C07C43/257 ,  C07C43/285 ,  C07C43/29 ,  C07C67/00 ,  C07C209/00 ,  C07C213/00 ,  C07C217/80 ,  C07C217/92 ,  C07C313/00 ,  C07C321/30 ,  C07C323/09 ,  C07C323/18 ,  C07C323/20 ,  C07D213/64 ,  C07D213/643 ,  C07D317/52 ,  C07D317/54 ,  C07D317/56 ,  C07D317/58 ,  C07D405/06 ,  C07C149/31 ,  C07D405/10

CPC分类号： C07D213/643 ,  A01N31/14 ,  A01N33/10 ,  A01N37/00 ,  A01N43/30 ,  A01N43/40 ,  C07C25/18 ,  C07C323/00 ,  C07C43/285 ,  C07C43/29 ,  C07D317/52 ,  C07D317/54 ,  C07D317/56 ,  C07D317/58 ,  C07D405/06

摘要： This invention relates to a novel compound represented by the following general formula (I), its production, and an insecticidal and acaricidal composition containing it as an active ingredient: ##STR1## wherein R.sub.1 and R.sub.2, which may be the same or different, are a hydrogen atom, a halogen atom, a lower alkyl group, a trifluoromethyl group, a lower alkoxyl group, a lower alkenyloxy group or a halogenated lower alkoxyl group or are, taken together, a methylenedioxy group; R.sub.3 is a vinyl group or a ethynyl group; R.sub.4 is a hydrogen atom or a lower alkyl group; R.sub.5 is a hydrogen atom or a fluorine atom; R.sub.6 is a hydrogen atom, a halogen atom, a lower alkyl group, a lower alkoxyl group or a trifluoromethyl group; Z is a nitrogen atom or a group represented by the formula --CH.dbd.; when Z is a nitrogen atom, Y is an oxygen atom; and when Z is a group of the formula --CH.dbd., Y is an oxygen atom, a sulfur atom, a methylene group or a group represented by the formula --NH--.

摘要翻译： 本发明涉及由以下通式（I）表示的新型化合物及其制备方法及含有它作为活性成分的杀虫和杀螨组合物：其中R1和R2，其中R1和R2， 可以相同或不同，为氢原子，卤素原子，低级烷基，三氟甲基，低级烷氧基，低级链烯氧基或卤代低级烷氧基，或一起为亚甲二氧基; R3是乙烯基或乙炔基; R4是氢原子或低级烷基; R5是氢原子或氟原子; R6是氢原子，卤素原子，低级烷基，低级烷氧基或三氟甲基; Z是氮原子或由式-CH =表示的基团; 当Z是氮原子时，Y是氧原子; 当Z为式-CH =的基团时，Y为氧原子，硫原子，亚甲基或式-NH-表示的基团。

公开(公告)号：US4714712A

公开(公告)日：1987-12-22

申请号：US853607

申请日：1986-04-18

申请人： Noritada Matsuo ,  Kazunori Tsushima ,  Sumio Nishida ,  Toshihiko Yano

发明人： Noritada Matsuo ,  Kazunori Tsushima ,  Sumio Nishida ,  Toshihiko Yano

IPC分类号： A61K9/08 ,  A01N53/00 ,  A01N53/10 ,  A61K31/435 ,  A61P31/04 ,  A61P43/00 ,  C07C33/42 ,  C07D498/18 ,  C07C69/743 ,  C07C69/747

CPC分类号： A01N53/00 ,  C07C33/42 ,  C07D498/18

摘要： This invention relates to novel carboxylic acid esters represented by the formula (I) below, methods for production thereof and insecticides containing them as the active ingredient, and an alcohol compound useful as an intermediate for manufacturing carboxylic acid esters represented by the formula (I). ##STR1## wherein R.sub.1 represents a hydrogen atom or a methyl group; when R.sub.1 is a hydrogen atom, R.sub.2 represents a group of the formula ##STR2## in which X and Y are the same or different and represent a hydrogen atom, a methyl group, a halogen atom or a halogenated lower alkyl group, and when R.sub.1 is a methyl group, R.sub.2 represents a methyl group; R.sub.3 represents hydrogen atom or a methyl group; and R.sub.4 represents a hydrogen atom, a lower alkyl group, a lower alkenyl group or a lower alkynyl group.

摘要翻译： 本发明涉及由下式（I）表示的新型羧酸酯，其制备方法和含有它们作为活性成分的杀虫剂，以及可用作制备由式（I）表示的羧酸酯的中间体的醇化合物， 。 （I）其中R1表示氢原子或甲基; 当R 1是氢原子时，R 2表示其中X和Y相同或不同并表示氢原子，甲基，卤素原子或卤代低级烷基的式“IMAGE”的基团，当R1 是甲基，R2表示甲基; R3表示氢原子或甲基; R4表示氢原子，低级烷基，低级烯基或低级炔基。

公开(公告)号：US4664698A

公开(公告)日：1987-05-12

申请号：US773615

申请日：1985-09-09

申请人： Kazunori Tsushima ,  Noritada Matsuo ,  Hirosi Kisida ,  Toshihiko Yano

发明人： Kazunori Tsushima ,  Noritada Matsuo ,  Hirosi Kisida ,  Toshihiko Yano

IPC分类号： A01N31/14 ,  A01N31/16 ,  A01N33/08 ,  A01N33/10 ,  A01N37/00 ,  A01N43/40 ,  C07C43/29 ,  C07D213/64 ,  C07D213/643 ,  C07C43/02 ,  C07D213/61 ,  C07D213/62

CPC分类号： C07D213/643 ,  A01N31/14 ,  A01N31/16 ,  A01N33/08 ,  A01N33/10 ,  A01N37/00 ,  A01N43/40 ,  C07C43/29

摘要： An ether compound represented by the following general formula (I), its production method and an insecticidal and acaricidal composition containing as an active ingredient: ##STR1## wherein X represents an oxygen atom or a group represented by the formula --NH--; when X represents an oxygen atom, Z represents a nitrogen atom or a group represented by the formula --CH.dbd.; when X represents --NH--, Z represents --CH.dbd.; when X represents an oxygen atom and Z represents a nitrogen atom, or when X represents --NH--, R.sub.1 represents a hydrogen or fluorine atom; when X represents an oxygen atom and Z represents --CH.dbd., R.sub.1 represents a fluorine atom; Y.sub.1 and Y.sub.2, which may be identical or different, represent a hydrogen or halogen atom or an alkyl, haloalkyl, alkoxyl or haloalkoxyl group; m and n represent an integer of 1 to 4 and the sum of them is not more than 5; R.sub.2 represents a methyl group or a chlorine atom; and R.sub.3 represents a methyl group, a halogen atom or a methoxy group.

摘要翻译： 由以下通式（I）表示的醚化合物，其制备方法和含有作为活性成分的杀虫杀螨组合物：其中X表示氧原子或式-NH- ; 当X表示氧原子时，Z表示氮原子或由式-CH =表示的基团; 当X表示-NH-时，Z表示-CH =; 当X表示氧原子且Z表示氮原子时，或当X表示-NH-时，R 1表示氢或氟原子; 当X表示氧原子且Z表示-CH =时，R 1表示氟原子; Y1和Y2可以相同或不同，表示氢或卤素原子或烷基，卤代烷基，烷氧基或卤代烷氧基; m和n表示1〜4的整数，并且它们之和不大于5; R2表示甲基或氯原子; R 3表示甲基，卤素原子或甲氧基。