摘要:
Provided is a method for producing an active material for a lithium secondary battery to enable efficient removal of iron impurities, which would become a problem in production of an active material for a lithium secondary battery, and attain a high quality. The method includes removing iron impurities in an active material for a lithium secondary battery by means of magnetic force. With this method, use of a magnetic force-generating device within a recess portion, which composes at least one part of the recess portion, enables efficient removal of only iron impurities. Thus, it is expected that a voltage drop caused by dissolution of iron compounds, i.e. impurities in a positive electrode, and their migration to a negative electrode in a battery, and decreases in charge and discharge efficiencies and a voltage drop owing to precipitation of lithium can be suppressed.
摘要:
A nonaqueous electrolyte secondary battery according to an embodiment of the present invention includes, as generating elements, a positive electrode 11 which comprises, as a positive electrode, lithium nickel-cobalt-manganese oxide (LiNixCoyMnzO2) which can intercalate and deintercalate lithium ions or the mixture of lithium nickel-cobalt-manganese oxide (LiNixCoyMnzO2) and lithium manganese oxide whose amount is 0 to 50% by mass relative to the whole amount of the positive electrode active material, a negative electrode 12 which comprises a negative electrode active material which can intercalate and deintercalate lithium ions, and a nonaqueous electrolyte are provided. To the positive electrode 11, 5 to 20% by mass of lithium cobalt oxide relative to the whole amount of the positive electrode active material is added. Consequently, a nonaqueous electrolyte secondary battery with excellent level of safety is provided by adding an additive which enhances thermal stability, even if lithium nickel-cobalt-manganese oxide is used as a positive electrode active material.
摘要翻译:根据本发明实施方式的非水电解质二次电池包括作为发电元件的正极11,其包括作为正极的锂镍钴锰氧化物锂(LiNi x Co x Co x Co 其可以插入和脱嵌锂离子或锂镍钴锰氧化物(LiNi x x O 2)的混合物 相对于全部量,其量为0〜50质量%的锂锰氧化物,和/或其中, 正极活性物质的负极12,其包含可插入和脱嵌锂离子的负极活性物质和非水电解质。 向正极11添加相对于正极活性物质的总量的5〜20质量%的钴酸锂。 因此,即使使用锂镍钴锰氧化物作为正极活性物质,也可以通过添加提高热稳定性的添加剂来提供安全性优异的非水电解质二次电池。
摘要:
The nonaqueous electrolyte secondary battery having high output characteristics and excellent safety when overcharging as well as excellent charge and discharge cycle characteristics according to an aspect of the invention includes a positive electrode having a positive electrode active material, a negative electrode having a negative electrode active material, a separator, and a nonaqueous electrolyte. The positive electrode active material includes lithium iron phosphate having an olivine crystal structure represented by General Formula LixFePO4 (where x is 0