摘要:
Provided is a method for producing an active material for a lithium secondary battery to enable efficient removal of iron impurities, which would become a problem in production of an active material for a lithium secondary battery, and attain a high quality. The method includes removing iron impurities in an active material for a lithium secondary battery by means of magnetic force. With this method, use of a magnetic force-generating device within a recess portion, which composes at least one part of the recess portion, enables efficient removal of only iron impurities. Thus, it is expected that a voltage drop caused by dissolution of iron compounds, i.e. impurities in a positive electrode, and their migration to a negative electrode in a battery, and decreases in charge and discharge efficiencies and a voltage drop owing to precipitation of lithium can be suppressed.
摘要:
A non-aqueous electrolyte secondary battery has a negative electrode, a non-aqueous electrolyte, and a positive electrode containing a positive electrode active material composed of an olivine lithium-containing metal phosphate represented by the general formula LixMPO4, where M is at least one element selected from the group consisting of Co, Ni, Mn, and Fe, and 0
摘要:
A method of producing an active material for a lithium secondary battery, by which impurities causing problems in synthesizing an active material for a lithium secondary battery, including a lithium transition metal oxyanion compound are removed efficiently and enhancement of an energy density is realized, is provided. By cleaning the active material for a lithium secondary battery, including a lithium transition metal oxyanion compound, with a pH buffer solution, for example, it is possible to efficiently remove just only impurities such as Li3PO4 or Li2CO3, or a substance, other than LiFePO4, in which the valence of Fe is bivalent such as FeSO4, FeO or Fe3(PO4)2 without dissolving Fe of LiFePO4.
摘要翻译:提供一种生产用于锂二次电池的活性材料的方法,其中提供了有效地除去包含锂过渡金属氧阴离子化合物的锂二次电池的活性材料合成的问题的杂质并实现能量密度的提高 。 通过例如利用pH缓冲溶液清洗包含锂过渡金属氧阴离子化合物的锂二次电池的活性物质,可以仅仅有效地除去Li 3 PO 4或Li 2 CO 3等杂质,或除了LiFePO 4以外的物质 ,其中铁的价数是二价的,如FeSO 4,FeO或Fe 3(PO 4)2,而不溶解LiFePO 4的Fe。
摘要:
A method of producing an active material for a lithium secondary battery, by which impurities causing problems in synthesizing an active material for a lithium secondary battery, including a lithium transition metal oxyanion compound are removed efficiently and enhancement of an energy density is realized, is provided. By cleaning the active material for a lithium secondary battery, including a lithium transition metal oxyanion compound, with a pH buffer solution, for example, it is possible to efficiently remove just only impurities such as Li3PO4 or Li2CO3, or a substance, other than LiFePO4, in which the valence of Fe is bivalent such as FeSO4, FeO or Fe3(PO4)2 without dissolving Fe of LiFePO4.
摘要翻译:提供一种生产用于锂二次电池的活性材料的方法,其中提供了有效地除去包含锂过渡金属氧阴离子化合物的锂二次电池的活性材料合成的问题的杂质并实现能量密度的提高 。 通过例如利用pH缓冲溶液清洗包含锂过渡金属氧阴离子化合物的锂二次电池的活性物质,可以仅仅有效地除去Li 3 PO 4或Li 2 CO 3等杂质,或除了LiFePO 4以外的物质 ,其中铁的价数是二价的,如FeSO 4,FeO或Fe 3(PO 4)2,而不溶解LiFePO 4的Fe。
摘要:
A method of producing an active material for a lithium secondary battery, by which impurities causing problems in synthesizing an active material for a lithium secondary battery, including a lithium transition metal oxyanion compound are removed efficiently and enhancement of an energy density is realized, is provided. By cleaning the active material for a lithium secondary battery, including a lithium transition metal oxyanion compound, with a pH buffer solution, for example, it is possible to efficiently remove just only impurities such as Li3PO4 or Li2CO3, or a substance, other than LiFePO4, in which the valence of Fe is bivalent such as FeSO4, FeO or Fe3(PO4)2 without dissolving Fe of LiFePO4.
摘要:
An alkaline storage battery including a positive electrode (1), a negative electrode (2) using a hydrogen-absorbing alloy, and an alkaline electrolyte solution employs, as the hydrogen-absorbing alloy in the negative electrode, a hydrogen-absorbing alloy for alkaline storage batteries including at least a rare-earth element, magnesium, nickel, and aluminum, and having an intensity ratio IA/IB of 1.00 or greater, wherein IA is the strongest peak intensity appearing in the range 2θ=32°-33° and IB is the strongest peak intensity appearing in the range 2θ=35°-36° in an X-ray diffraction analysis using CuαKα radiation as the X-ray source.
摘要翻译:包括正极(1),使用吸氢合金的负极(2)和碱性电解液的碱性蓄电池作为负极中的吸氢合金,使用碱性吸氢合金 包括至少一种稀土元素,镁,镍和铝的并且具有1.00或更大的强度比I A / I B B的蓄电池,其中I < SUB> A SUB>是在2θ= 32°-33°的范围内出现的最强峰强度,I B是在2θ= 35°-36°的范围内出现的最强峰强度 使用CualphaKalpha辐射作为X射线源的X射线衍射分析。
摘要:
An alkaline storage battery including a positive electrode (1), a negative electrode (2) using a hydrogen-absorbing alloy, and an alkaline electrolyte solution employs, as the hydrogen-absorbing alloy in the negative electrode, a hydrogen-absorbing alloy for alkaline storage batteries including at least a rare-earth element, magnesium, nickel, and aluminum, and having an intensity ratio IA/IB of 1.00 or greater, wherein IA is the strongest peak intensity appearing in the range 2θ=32°-33° and IB is the strongest peak intensity appearing in the range 2θ=35°-36° in an X-ray diffraction analysis using Cu- Kα radiation as the X-ray source.
摘要:
Middle point voltage of discharge is increased and at the same time cycle life improved in a nickel-metal hydride storage battery having a negative electrode utilizing a rare earth-nickel hydrogen-absorbing alloy containing Mg and the like and having a crystal structure other than a CaCu5 structure. A nickel-metal hydride storage battery contains a positive electrode (1), a negative electrode (2) including a hydrogen-absorbing alloy, and an alkaline electrolyte solution. The hydrogen-absorbing alloy contains at least a rare-earth element, magnesium, nickel, and aluminum, and has an intensity ratio IA/IB of 0.1 or greater as determined by X-ray diffraction analysis using Cu-Kα radiation as an X-ray source, where IA is the strongest peak intensity that appears in the range of 20=30° to 34°, and IB is the strongest peak intensity that appears in the range of 2θ=40° to 44°. The negative electrode contains a cobalt compound.
摘要:
A hydrogen absorbing alloy containing at least a rare-earth element, magnesium (Mg), nickel (Ni) and aluminum (Al), having an intensity ratio (IA/IB) of not smaller than 0.6 (where IA represents an intensity of the highest peak in a range of 2θ=30°˜34° in the X-ray diffraction pattern using CuKα-radiation as the X-ray source and IB represents the intensity of the highest peak in a range of 2θ=40°˜44°), and not substantially including La as the rare-earth element.
摘要翻译:含有至少含有稀土元素的镁(Mg),镍(Ni)和铝(Al))的吸氢合金,其强度比(I A / A / SUB>)不大于0.6(其中I A表示使用CuKα的X射线衍射图中在2θ= 30°〜34°的范围内的最高峰的强度 作为X射线源的辐射,I B表示在2θ= 40°〜44°的范围内的最高峰的强度),并且基本上不包括作为稀有的La 地面元素