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公开(公告)号:US4942149A
公开(公告)日:1990-07-17
申请号:US398844
申请日:1989-08-25
IPC分类号: B01J20/22 , C07C43/20 , C07D323/00
CPC分类号: C07D323/00 , C07C43/202
摘要: A crown ether compound is shown below and useful as a separating agent for chemical compounds. ##STR1## (In the formula, A and B represent hydrogen atoms, straight chain or branched alkyl groups having 1-6 carbon atoms, allyl groups having 6-10 carbon atoms, or aralkyl groups having 7-9 carbon atoms. Although A and B may be different groups, it is preferable that they be the same.R.sub.1 represents a hydrogen atom, a straight chain or branched alkyl group having 1-20 carbon atoms, or preferably an alkyl group having 6-16 carbon atoms. R.sub.1 may be bonded to any carbon atom on the cyclical ester group and its number is 1-12, and preferably 1-3. n represents an integer from 3-10, and preferably 4-8, with 5 or 6 being even more preferable.In addition R.sub.2 and R.sub.3 represent straight chain or branched alkyl groups having 1-30, and preferably 6-20 carbon atoms, or aryl groups having 6-18 carbon atoms, or aralkyl groups having 7-30 carbon atoms. The location of R.sub.2 and R.sub.3 may be anywhere other than the A and B substitution positions on the condensed ring, and although one of each of R.sub.2 and R.sub.3 is satisfactory, a maximum of 5 groups may be substituted. In addition, R.sub.2 and R.sub.3 may also be different.)
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公开(公告)号:US4842935A
公开(公告)日:1989-06-27
申请号:US22039
申请日:1987-03-05
IPC分类号: B01J20/22 , B01D15/00 , B01J20/291 , B01J20/32 , C07B57/00 , C07C227/34 , C07C229/02 , C07C319/28 , C07C323/58 , G01N30/88
CPC分类号: B01J20/29 , B01J20/28004 , B01J20/3092 , B01J20/3204 , B01J20/3253 , B01J20/3255 , B01J2220/54 , B01J2220/58 , Y10S435/803 , Y10T428/2991 , Y10T428/2993 , Y10T428/2998
摘要: A filler for separating an optical isomer comprising a surface-hydrophobic filler component and an optically active lipophilic crown compound carried on the filler component by adsorption. The filler may be charged in a column to carry out separation of a sample such as amino acid or the like in the form of an aqueous solution.
摘要翻译: 一种用于通过吸附分离载体在填料组分上的表面疏水性填料组分和旋光亲油性冠状化合物的旋光异构体填料。 可以将填料装入柱中以进行水溶液形式的样品例如氨基酸等的分离。
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