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公开(公告)号：US20100184884A1
公开(公告)日：2010-07-22
申请号：US12602571
申请日：2008-05-28
CPC分类号： C08K5/5313 , C08G64/0208 , C08G64/0216 , C08G64/186 , C08L69/00 , C08L2666/04
摘要： There is provided a resin composition that comprises a polycarbonate resin derived from an ether diol such as isosorbide and that is excellent in flame retardancy, heat resistance, thermal stability, rigidity, transparency and moldability.The resin composition is a flame-retardant resin composition comprising 1 to 60 parts by weight of phosphorus compound (component B) having a thermal decomposition temperature of not higher than 340° C. based on 100 parts by weight of polycarbonate resin (component A) that mainly comprises a recurring unit represented by the following formula (1).
摘要翻译： 提供一种树脂组合物，其包含衍生自醚二醇的聚碳酸酯树脂，例如异山梨醇，并且其阻燃性，耐热性，热稳定性，刚性，透明性和成型性优异。 该树脂组合物是含有1〜60重量份的基于100重量份聚碳酸酯树脂（A成分）的热分解温度不高于340℃的磷化合物（B成分）的阻燃性树脂组合物， 其主要包括由下式（1）表示的重复单元。
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公开(公告)号：US20100076130A1
公开(公告)日：2010-03-25
申请号：US12597135
申请日：2008-04-23
申请人： Toshiyuki Miyake , Masami Kinoshita , Mizuho Saito , Katsuhiko Hironaka , Eiichi Kitazono , Akimichi Oda
发明人： Toshiyuki Miyake , Masami Kinoshita , Mizuho Saito , Katsuhiko Hironaka , Eiichi Kitazono , Akimichi Oda
CPC分类号： C08K5/005 , C08G64/0208 , C08G64/0216 , C08G64/186 , C08G64/305 , C08L69/00
摘要： An object of the present invention is to provide a polycarbonate resin composition which has a high content of biogenic matter and is excellent in heat resistance, heat stability, moldability, hue and transparency.The present invention related to a resin composition comprising 0.0005 to 0.5 part by weight of at least one heat stabilizer (component S) selected from the group consisting of phosphorus-based heat stabilizers (PS) and hindered phenol-based heat stabilizers (HS) based on 100 parts by weight of a polycarbonate resin (component A) which contains a recurring unit represented by the following formula (1) as the main constituent, and a molded article thereof.
摘要翻译： 本发明的目的是提供一种具有高生物量的含量且耐热性，热稳定性，成型性，色相和透明度优异的聚碳酸酯树脂组合物。 本发明涉及一种树脂组合物，其包含0.0005至0.5重量份的至少一种选自磷基热稳定剂（PS）和受阻酚基热稳定剂（HS）的热稳定剂（组分S） 在100重量份含有由下式（1）表示的重复单元作为主要成分的聚碳酸酯树脂（组分A）及其模制品中。
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公开(公告)号：US08034894B2
公开(公告)日：2011-10-11
申请号：US12530437
申请日：2008-03-05
IPC分类号： C08G64/02
CPC分类号： C08G64/0216
摘要： A terminal modified polycarbonate having a high content of biogenic matter, excellent heat resistance, heat stability, moldability and moist absorption resistance and high surface energy and a manufacturing process thereof are provided. The terminal modified polycarbonate has a main chain essentially composed of a recurring unit represented by the following formula (1): has a specific viscosity at 20° C. of a solution obtained by dissolving 0.7 g of the polycarbonate in 100 ml of methylene chloride of 0.2 to 0.5, and contains a terminal group represented by the following formula (2) or (3) in an amount of 0.3 to 9 wt % based on the main chain:
摘要翻译： 提供具有高生物量含量，优异的耐热性，热稳定性，成型性和耐潮湿吸收性以及高表面能的末端改性聚碳酸酯及其制造方法。 末端改性聚碳酸酯具有基本上由下述式（1）表示的重复单元构成的主链：在20℃下具有通过将0.7g聚碳酸酯溶解在100ml二氯甲烷中得到的溶液的比粘度 0.2〜0.5，并且含有由下式（2）或（3）表示的末端基团：相对于主链为0.3〜9重量％
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公开(公告)号：US20100160563A1
公开(公告)日：2010-06-24
申请号：US12600909
申请日：2008-05-16
CPC分类号： C08L69/00 , C08G64/0208 , C08L21/00 , C08L25/10 , C08L51/04 , C08L55/02 , C08L2666/08 , C08L2666/04 , C08L2666/24
摘要： A resin composition comprising a polycarbonate resin derived from an ether diol residue such as isosorbide and has excellent impact resistance, heat resistance, heat stability and moldability.The resin composition comprises a rubber polymer (component B) in an amount of 1 to 30 parts by weight based on 100 parts by weight of a polycarbonate resin (component A) which contains a recurring unit represented by the following formula (1) as the main constituent and has a glass transition temperature (Tg) of 145 to 165° C. and a 5% weight loss temperature (Td) of 320 to 400° C.
摘要翻译： 一种树脂组合物，其含有衍生自醚二醇残基如异山梨醇的聚碳酸酯树脂，并且具有优异的耐冲击性，耐热性，热稳定性和成型性。 树脂组合物包含相对于100重量份的含有下述式（1）表示的重复单元的聚碳酸酯树脂（A成分）为1〜30重量份的橡胶聚合物（B成分），作为 主要成分，玻璃化转变温度（Tg）为145〜165℃，5％重量损失温度（Td）为320〜400℃。
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公开(公告)号：US08604107B2
公开(公告)日：2013-12-10
申请号：US12602571
申请日：2008-05-28
IPC分类号： C08K3/32
CPC分类号： C08K5/5313 , C08G64/0208 , C08G64/0216 , C08G64/186 , C08L69/00 , C08L2666/04
摘要： There is provided a resin composition that comprises a polycarbonate resin derived from an ether diol such as isosorbide and that is excellent in flame retardancy, heat resistance, thermal stability, rigidity, transparency and moldability. The resin composition is a flame-retardant resin composition comprising 1 to 60 parts by weight of phosphorus compound (component B) having a thermal decomposition temperature of not higher than 340° C. based on 100 parts by weight of polycarbonate resin (component A) that mainly comprises a recurring unit represented by the following formula (1)
摘要翻译： 提供一种树脂组合物，其包含衍生自醚二醇的聚碳酸酯树脂，例如异山梨醇，并且其阻燃性，耐热性，热稳定性，刚性，透明性和成型性优异。 该树脂组合物是含有1〜60重量份的基于100重量份聚碳酸酯树脂（A成分）的热分解温度不高于340℃的磷化合物（B成分）的阻燃性树脂组合物， 其主要包括由下式（1）表示的重复单元，
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公开(公告)号：US08106143B2
公开(公告)日：2012-01-31
申请号：US12600909
申请日：2008-05-16
CPC分类号： C08L69/00 , C08G64/0208 , C08L21/00 , C08L25/10 , C08L51/04 , C08L55/02 , C08L2666/08 , C08L2666/04 , C08L2666/24
摘要： A resin composition includes a polycarbonate resin derived from an ether diol residue such as isosorbide and has excellent impact resistance, heat resistance, heat stability and moldability. The resin composition includes a rubber polymer (component B) in an amount of 1 to 30 parts by weight based on 100 parts by weight of a polycarbonate resin (component A) which contains a recurring unit represented by the following formula (1) as the main constituent and has a glass transition temperature (Tg) of 145 to 165° C. and a 5% weight loss temperature (Td) of 320 to 400° C.
摘要翻译： 树脂组合物包括衍生自醚二醇残基如异山梨醇的聚碳酸酯树脂，并且具有优异的耐冲击性，耐热性，热稳定性和成型性。 树脂组合物包含相对于100重量份的含有下述式（1）表示的重复单元的聚碳酸酯树脂（A成分）为1〜30重量份的橡胶聚合物（B成分），为 主要成分，玻璃化转变温度（Tg）为145〜165℃，5％重量损失温度（Td）为320〜400℃。
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公开(公告)号：US08008381B2
公开(公告)日：2011-08-30
申请号：US12597135
申请日：2008-04-23
申请人： Toshiyuki Miyake , Masami Kinoshita , Mizuho Saito , Katsuhiko Hironaka , Eiichi Kitazono , Akimichi Oda
发明人： Toshiyuki Miyake , Masami Kinoshita , Mizuho Saito , Katsuhiko Hironaka , Eiichi Kitazono , Akimichi Oda
CPC分类号： C08K5/005 , C08G64/0208 , C08G64/0216 , C08G64/186 , C08G64/305 , C08L69/00
摘要： An object of the present invention is to provide a polycarbonate resin composition which has a high content of biogenic matter and is excellent in heat resistance, heat stability, moldability, hue and transparency. The present invention relates to a resin composition including 0.0005 to 0.5 part by weight of at least one heat stabilizer (component S) selected from the group consisting of phosphorus-based heat stabilizers (PS) and hindered phenol-based heat stabilizers (HS) based on 100 parts by weight of a polycarbonate resin (component A) which contains a recurring unit represented by the following formula (1) as the main constituent, and a molded article thereof:
摘要翻译： 本发明的目的是提供一种具有高生物量的含量且耐热性，热稳定性，成型性，色相和透明度优异的聚碳酸酯树脂组合物。 本发明涉及一种树脂组合物，其包含0.0005〜0.5重量份的至少一种选自磷系热稳定剂（PS）和受阻酚系热稳定剂（HS）的热稳定剂（成分S） 在100重量份含有下述式（1）所示的重复单元作为主要成分的聚碳酸酯树脂（A成分）及其成型品中，
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公开(公告)号：US20100105854A1
公开(公告)日：2010-04-29
申请号：US12530437
申请日：2008-03-05
CPC分类号： C08G64/0216
摘要： A terminal modified polycarbonate having a high content of biogenic matter, excellent heat resistance, heat stability, moldability and moist absorption resistance and high surface energy and a manufacturing process thereof.The terminal modified polycarbonate has a main chain essentially composed of a recurring unit represented by the following formula (1): has a specific viscosity at 20° C. of a solution obtained by dissolving 0.7 g of the polycarbonate in 100 ml of methylene chloride of 0.2 to 0.5, and contains a terminal group represented by the following formula (2) or (3) in an amount of 0.3 to 9 wt % based on the main chain: wherein R1 is an alkyl group having 4 to 30 carbon atoms, aralkyl group having 7 to 30 carbon atoms, perfluoroalkyl group having 4 to 30 carbon atoms or a group represented by the following formula (4): wherein R2, R3, R4, R5 and R6 are each independently at least one group selected from the group consisting of an alkyl group having 1 to 10 carbon atoms, cycloalkyl group having 6 to 20 carbon atoms, alkenyl group having 2 to 10 carbon atoms, aryl group having 6 to 10 carbon atoms and aralkyl group having 7 to 20 carbon atoms, b is an integer of 0 to 3, and c is an integer of 4 to 100, X is at least one bond selected from the group consisting of a single bond, ether bond, thioether bond, ester bond, amino bond and amide bond, and a is an integer of 1 to 5.
摘要翻译： 具有高生物量含量，优异的耐热性，热稳定性，成型性和耐潮湿吸收性以及高表面能的末端改性聚碳酸酯及其制造方法。 末端改性聚碳酸酯具有基本上由下述式（1）表示的重复单元构成的主链：在20℃下具有通过将0.7g聚碳酸酯溶解在100ml二氯甲烷中得到的溶液的比粘度 0.2〜0.5，并且含有下述通式（2）或（3）所示的末端基，相对于主链为0.3〜9重量％：其中，R1为碳原子数4〜30的烷基，芳烷基 具有7至30个碳原子的基团，具有4至30个碳原子的全氟烷基或由下式（4）表示的基团：其中R 2，R 3，R 4，R 5和R 6各自独立地选自以下基团中的至少一个： 的碳原子数1〜10的烷基，碳原子数6〜20的环烷基，碳原子数2〜10的烯基，碳原子数6〜10的芳基，碳原子数7〜20的芳烷基，b表示 0〜3的整数，c为4的整数 至100，X为选自单键，醚键，硫醚键，酯键，氨基键和酰胺键中的至少一个键，a为1〜5的整数。
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9.发明授权Thermoplastic resin composition, molded article, and process for producing the same 失效热塑性树脂组合物，成型体及其制造方法公开(公告)号：US07098263B2
公开(公告)日：2006-08-29
申请号：US10381103
申请日：2002-07-19
IPC分类号： C08K3/34
CPC分类号： C08L69/00 , C08K3/34 , C08K5/19 , C08K5/50 , C08K5/541 , C08K9/04 , C08K9/06 , C08L25/08 , C08L67/025 , C08L101/08 , C08L2666/18 , C08L2666/06 , C08L2666/02
摘要： A thermoplastic resin composition comprising: (A) 100 parts by weight of a noncrystalline thermoplastic resin component (component A); (B) 0.1 to 50 parts by weight of a layered silicate (component B) which satisfies the following (i) to (iii): (i) it has a cation exchange capacity of 50 to 200 milliequivalents/100 g, and at least 40% of the cation exchange capacity being exchanged with an organic onium ion, (ii) 60% or more of the layered silicate particles have a thickness of 100 nm or less in the resin composition, and (iii) the interlayer spacing of the layered silicate (component B) in the resin composition is smaller than the interlayer spacing of the layered silicate alone by 0.5 nm or more; and (C) 0 to 50 parts by weight of a compound (component C) having affinity for the noncrystalline thermoplastic resin component as the component A and a hydrophilic component; and molded articles thereof. According to the present invention, a noncrystalline thermoplastic resin composition having excellent stiffness, surface appearance and heat stability, especially a polycarbonate resin composition and molded articles thereof are obtained.
摘要翻译： 一种热塑性树脂组合物，其包含：（A）100重量份的非结晶性热塑性树脂组分（组分A）; （B）0.1〜50重量份满足以下（i）〜（iii）的层状硅酸盐（B成分）：（i）阳离子交换容量为50〜200毫当量/ 100g，至少 阳离子交换容量的40％与有机鎓离子交换，（ii）60％以上的层状硅酸盐颗粒在树脂组合物中的厚度为100nm以下，（iii）层状间隔 树脂组合物中的硅酸盐（组分B）小于层状硅酸盐的层间距离为0.5nm以上; 和（C）0〜50重量份对作为组分A的非结晶性热塑性树脂组分具有亲和性的化合物（组分C）和亲水性组分; 及其成型品。 根据本发明，获得具有优异的刚度，表面外观和热稳定性的非结晶性热塑性树脂组合物，特别是聚碳酸酯树脂组合物及其模塑制品。
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公开(公告)号：US07189796B2
公开(公告)日：2007-03-13
申请号：US10531914
申请日：2003-10-29
IPC分类号： C08G64/00
摘要： An object of the present invention is to provide an aromatic polycarbonate resin composition having good rigidity and good hydrolysis resistance.The present invention is an aromatic polycarbonate resin composition comprising: (A) 100 parts by weight of aromatic polycarbonate (component A) (B) 0.1 to 20 parts by weight of layer silicate (component B) having 50 to 200 milliequivalents/100 g of cation exchange capacity and ion-exchanged by an organic onium ion represented by the following general formula (I): (wherein M represents a nitrogen atom or a phosphorus atom, R1 and R2 represent an alkyl group having 6 to 16 carbon atoms and may be the same as or different from each other, and R3 and R4 represent an alkyl group having 1 to 4 carbon atoms and may be the same as or different from each other), (C) 0.1 to 50 parts by weight of compound (component C) having an affinity for the component A and having a hydrophilic component, and (D) 0.005 to 1 part by weight of ester (component D) of a higher fatty acid and a polyhydric alcohol.
摘要翻译： 本发明的目的是提供一种刚性好，耐水解性好的芳香族聚碳酸酯树脂组合物。 本发明是一种芳族聚碳酸酯树脂组合物，其包含：（A）100重量份芳族聚碳酸酯（组分A）（B）0.1至20重量份具有50至200毫当量的层状硅酸盐（组分B）/ 100g 阳离子交换容量，并由以下通式（I）表示的有机鎓离子离子交换：（其中M表示氮原子或磷原子，R 1和R 2， 表示具有6〜16个碳原子的烷基，可以相同或不同，R 3和R 4表示具有 1〜4个碳原子，可以相同或不同），（C）0.1〜50重量份对组分A具有亲和性且具有亲水性成分的化合物（C成分），（D） 0.005〜1重量份的高级脂肪酸和多元醇的酯（组分D）。
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