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公开(公告)号：US20140127095A1
公开(公告)日：2014-05-08
申请号：US13670737
申请日：2012-11-07
申请人： Troy Allan Bednarski , Violina Antoneta Cocalia , Matthew Dean Soderstrom , Eduardo Alberto Kamenetzky , Andrew Michael Cameron , Douglas HARRIS
发明人： Troy Allan Bednarski , Violina Antoneta Cocalia , Matthew Dean Soderstrom , Eduardo Alberto Kamenetzky , Andrew Michael Cameron , Douglas HARRIS
CPC分类号： C22B3/1683 , C22B3/0005 , C22B34/34 , C22B60/0226 , Y02P10/234
摘要： Provided herein are processes for recovering molybdenum and/or other value metals (e.g., uranium) present in aqueous solutions from a large range of concentrations: from ppm to grams per liter via a solvent extraction process by extracting the molybdenum and/or other value metal from the aqueous solution by contacting it with an organic phase solution containing a phosphinic acid, stripping the molybdenum and/or other value metal from the organic phase solution by contacting it with an aqueous phase strip solution containing an inorganic compound and having a ≦1.0 M concentration of free ammonia, and recovering the molybdenum and/or other value metal by separating it from the aqueous phase strip solution. When the molybdenum and/or other value metal are present only in low concentration, the processes can include an organic phase recycle step and/or an aqueous phase strip recycle step in order to concentrate the metal prior to recover.
摘要翻译： 本文提供了从大范围的浓度回收存在于水溶液中的钼和/或其它价值金属（例如铀）的方法，即通过萃取钼和/或其它金属值的溶剂萃取方法，从ppm到克/升 通过使其与含有次膦酸的有机相溶液接触，从有机相溶液中除去钼和/或其它金属的金属，使其与含有无机化合物的水相条带溶液接触并具有＆lt; M浓度的游离氨，并通过将其与水相条带溶液分离来回收钼和/或其它金属金属。 当钼和/或其它金属金属仅存在于低浓度时，该方法可以包括有机相循环步骤和/或水相条带再循环步骤，以便在回收之前浓缩金属。
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公开(公告)号：US08968698B2
公开(公告)日：2015-03-03
申请号：US13670737
申请日：2012-11-07
申请人： Troy Allan Bednarski , Violina Antoneta Cocalia , Matthew Dean Soderstrom , Eduardo Alberto Kamenetzky , Andrew Michael Cameron , Douglas Harris
发明人： Troy Allan Bednarski , Violina Antoneta Cocalia , Matthew Dean Soderstrom , Eduardo Alberto Kamenetzky , Andrew Michael Cameron , Douglas Harris
IPC分类号： C22B3/00
CPC分类号： C22B3/1683 , C22B3/0005 , C22B34/34 , C22B60/0226 , Y02P10/234
摘要： Provided herein are processes for recovering molybdenum and/or other value metals (e.g., uranium) present in aqueous solutions from a large range of concentrations: from ppm to grams per liter via a solvent extraction process by extracting the molybdenum and/or other value metal from the aqueous solution by contacting it with an organic phase solution containing a phosphinic acid, stripping the molybdenum and/or other value metal from the organic phase solution by contacting it with an aqueous phase strip solution containing an inorganic compound and having a ≦1.0 M concentration of free ammonia, and recovering the molybdenum and/or other value metal by separating it from the aqueous phase strip solution. When the molybdenum and/or other value metal are present only in low concentration, the processes can include an organic phase recycle step and/or an aqueous phase strip recycle step in order to concentrate the metal prior to recover.
摘要翻译： 本文提供了从大范围的浓度回收存在于水溶液中的钼和/或其它价值金属（例如铀）的方法，即通过萃取钼和/或其它金属值的溶剂萃取方法，从ppm到克/升 通过使其与含有次膦酸的有机相溶液接触，从有机相溶液中除去钼和/或其它金属的金属，使其与含有无机化合物的水相条带溶液接触并具有＆lt; M浓度的游离氨，并通过将其与水相条带溶液分离来回收钼和/或其它金属金属。 当钼和/或其它金属金属仅存在于低浓度时，该方法可以包括有机相循环步骤和/或水相条带再循环步骤，以便在回收之前浓缩金属。
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公开(公告)号：US08328900B2
公开(公告)日：2012-12-11
申请号：US12830660
申请日：2010-07-06
申请人： Troy Allan Bednarski , Violina Antoneta Cocalia , Matthew Dean Soderstrom , Eduardo Alberto Kamenetzky , Andrew Michael Cameron , Douglas Harris
发明人： Troy Allan Bednarski , Violina Antoneta Cocalia , Matthew Dean Soderstrom , Eduardo Alberto Kamenetzky , Andrew Michael Cameron , Douglas Harris
CPC分类号： C22B3/0005 , C22B3/0043 , C22B3/0066 , C22B34/34 , Y02P10/234
摘要： Provided herein are processes for recovering molybdenum and/or other value metals (e.g., uranium) present in aqueous solutions from a large range of concentrations: from ppm to grams per liter via a solvent extraction process by extracting the molybdenum and/or other value metal from the aqueous solution by contacting it with an organic phase solution containing a phosphinic acid, stripping the molybdenum and/or other value metal from the organic phase solution by contacting it with an aqueous phase strip solution containing an inorganic compound and having a ≦1.0 M concentration of free ammonia, and recovering the molybdenum and/or other value metal by separating it from the aqueous phase strip solution. When the molybdenum and/or other value metal are present only in low concentration, the processes can include an organic phase recycle step and/or an aqueous phase strip recycle step in order to concentrate the metal prior to recover.
摘要翻译： 本文提供了从大范围的浓度回收存在于水溶液中的钼和/或其它价值金属（例如铀）的方法，即通过萃取钼和/或其它金属值的溶剂萃取方法，从ppm到克/升 通过使其与含有次膦酸的有机相溶液接触，从有机相溶液中除去钼和/或其它金属的金属，使其与含有无机化合物的水相条带溶液接触并具有＆lt; M浓度的游离氨，并通过将其与水相条带溶液分离来回收钼和/或其它金属金属。 当钼和/或其它金属金属仅存在于低浓度时，该方法可以包括有机相循环步骤和/或水相条带再循环步骤，以便在回收之前浓缩金属。
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公开(公告)号：US20110005354A1
公开(公告)日：2011-01-13
申请号：US12830660
申请日：2010-07-06
申请人： Troy Allan Bednarski , Violina Antoneta Cocalia , Matthew Dean Soderstrom , Eduardo Alberto Kamenetzky , Andrew Michael Cameron , Douglas Harris
发明人： Troy Allan Bednarski , Violina Antoneta Cocalia , Matthew Dean Soderstrom , Eduardo Alberto Kamenetzky , Andrew Michael Cameron , Douglas Harris
CPC分类号： C22B3/0005 , C22B3/0043 , C22B3/0066 , C22B34/34 , Y02P10/234
摘要： Provided herein are processes for recovering molybdenum and/or other value metals (e.g., uranium) present in aqueous solutions from a large range of concentrations: from ppm to grams per liter via a solvent extraction process by extracting the molybdenum and/or other value metal from the aqueous solution by contacting it with an organic phase solution containing a phosphinic acid, stripping the molybdenum and/or other value metal from the organic phase solution by contacting it with an aqueous phase strip solution containing an inorganic compound and having a ≦1.0 M concentration of free ammonia, and recovering the molybdenum and/or other value metal by separating it from the aqueous phase strip solution. When the molybdenum and/or other value metal are present only in low concentration, the processes can include an organic phase recycle step and/or an aqueous phase strip recycle step in order to concentrate the metal prior to recover.
摘要翻译： 本文提供了从大范围的浓度回收存在于水溶液中的钼和/或其它价值金属（例如铀）的方法，即通过萃取钼和/或其它金属值的溶剂萃取方法，从ppm到克/升 通过使其与含有次膦酸的有机相溶液接触，从有机相溶液中除去钼和/或其它金属的金属，使其与含有无机化合物的水相条带溶液接触并具有＆lt; M浓度的游离氨，并通过将其与水相条带溶液分离来回收钼和/或其它金属金属。 当钼和/或其它金属金属仅存在于低浓度时，该方法可以包括有机相循环步骤和/或水相条带再循环步骤，以便在回收之前浓缩金属。
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