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16 条记录 (耗时 0.016 秒)

    Sulphonated chiral phosphines, their preparation and their use
    1.
    发明授权
    Sulphonated chiral phosphines, their preparation and their use 失效
    磺化手性膦，其制备及其用途

    公开(公告)号：US4654176A

    公开(公告)日：1987-03-31

    申请号：US635185

    申请日：1984-07-27

    申请人： Tuan-Phat Dang ,  Jean Jenck ,  Didier Morel

    发明人： Tuan-Phat Dang ,  Jean Jenck ,  Didier Morel

    IPC分类号： C07B53/00 ,  B01J31/24 ,  C07B31/00 ,  C07C45/50 ,  C07C67/00 ,  C07F9/50 ,  C07C143/24 ,  C07C143/42

    CPC分类号： B01J31/2404 ,  B01J31/2409 ,  B01J31/2414 ,  C07C45/505 ,  C07F9/5022 ,  C07F9/5027 ,  B01J2231/645 ,  B01J2531/822 ,  B01J2531/96

    摘要： The invention provides novel sulphonated chiral phosphines of the formula: ##STR1## in which R represents an alkyl radical, a cycloalkyl radical optionally substituted with an alkyl radical, a cycloalkylalkyl radical optionally substituted with an alkyl radical, a phenyl, phenylalkyl, binaphthyl or binaphthylalkyl radical, in which the alkyl, cycloalkyl, phenyl and binaphthyl radicals, and the alkyl portions of the other radicals, can be substituted by a radical of general formula: ##STR2## R.sub.1 represents an alkyl, cycloalkyl, phenyl, or phenylalkyl radical, Ar represents a phenyl or naphthyl radical, m.sup.+ represents a proton or alkali metal ion or alkaline earth metal ion, m=1 or 2, n=0, 1 or 2, p=1 or 2, (p+m) .ltoreq.3, and R and R.sub.1 can be chiral or achiral. These chiral phosphines form water-soluble metal complexes useful as catalysts in asymmetric organic synthesis.

    摘要翻译： 本发明提供下式的新型磺化手性膦：其中R表示烷基，任选被烷基取代的环烷基，任选被烷基取代的环烷基烷基，苯基，苯基烷基，联萘或联萘基 其中烷基，环烷基，苯基和联萘基以及其它基团的烷基部分可以被下列基团取代：R 1表示烷基，环烷基，苯基或苯基烷基，Ar 表示苯基或萘基，m +表示质子或碱金属离子或碱土金属离子，m = 1或2，n = 0,1或2，p = 1或2，（p + m） ，R和R 1可以是手性或非手性的。 这些手性膦形成水溶性金属络合物，可用作不对称有机合成中的催化剂。

    Preparation of tri-(m-sulfophenyl)-phosphine
    2.
    发明授权
    Preparation of tri-(m-sulfophenyl)-phosphine 失效
    三（间 - 磺苯基） - 膦的制备

    公开(公告)号：US4668824A

    公开(公告)日：1987-05-26

    申请号：US635829

    申请日：1984-07-30

    申请人： Jean Jenck ,  Didier Morel

    发明人： Jean Jenck ,  Didier Morel

    IPC分类号： C07F9/50 ,  C07F9/53

    CPC分类号： C07F9/5054 ,  C07F9/5095

    摘要： Essentially pure tri-(m-sulfophenyl)-phosphine, well suited as a ligand for the formation of, e.g., rhodium-based olefin hydroformylation catalysts, is facilely prepared by (i) sulfonating triphenylphosphine with oleum, H.sub.2 SO.sub.4 /SO.sub.3, wherein the temperature of sulfonation ranges from 15.degree. to about 25.degree. C., the molar ratio of SO.sub.3 /triphenylphosphine is at least 8, and the amount by weight of SO.sub.3 in the mixture (SO.sub.3 +H.sub.2 SO.sub.4 +triphenylphosphine) at the beginning of said sulfonation reaction is at least 33%; and (ii) thence terminating said sulfonation reaction via hydrolysis of the reaction mixture.

    摘要翻译： 通过（i）用发烟硫酸，H 2 SO 4 / SO 3磺化三苯基膦，可以容易地制备基本上纯的三 - （间 - 磺基苯基）膦，非常适合作为形成例如铑基烯烃加氢甲酰化催化剂的配体，其中温度 的磺化范围为15〜25℃，SO 3 /三苯基膦的摩尔比为8以上，磺化反应开始时混合物（SO 3 + H 2 SO 4 +三苯基膦）中SO 3的重量比为 至少33％; 和（ii）然后通过反应混合物的水解终止所述磺化反应。

    Preparation of .beta., .gamma.-unsaturated carboxylic acids
    4.
    发明授权
    Preparation of .beta., .gamma.-unsaturated carboxylic acids 失效
    制备β，γ-不饱和羧酸

    公开(公告)号：US5041642A

    公开(公告)日：1991-08-20

    申请号：US814807

    申请日：1985-12-30

    申请人： Jean Jenck

    发明人： Jean Jenck

    IPC分类号： C07C57/03 ,  B01J23/00 ,  B01J23/44 ,  B01J31/00 ,  B01J31/28 ,  C07B61/00 ,  C07C51/00 ,  C07C51/14 ,  C07C67/00

    CPC分类号： C07C51/14

    摘要： .beta.,.gamma.-Unsaturated carboxylic acids are facilely prepared by carbonylating a conjugated diene with carbon monoxide in the presence of (i) water, (ii) a halogenated hydracid, (iii) a palladium catalyst comprising palladium metal or supported palladium metal, a palladium oxide, or a complex salt of palladium, the anion coordinated to the palladium cation of which comprising a hard or borderline base, and (iv) a quaternary onium salt of nitrogen, phosphorus or arsenic, said N, P or As being tetra-coordinated to a carbon atom, the anion of which comprising a hard or borderline base.

    摘要翻译： β，γ-不饱和羧酸通过在（i）水，（ⅱ）卤化氢化物，（ⅲ）包含钯金属或负载钯金属的钯催化剂，钯 氧化物或钯的络合盐，所述阴离子与其包含硬或边界碱的钯阳离子配位，和（iv）氮，磷或砷的季铵盐，所述N，P或As是四配位的 碳原子，其阴离子包含硬或边界碱。

    Preparation of alkyl adipates
    8.
    发明授权
    Preparation of alkyl adipates 失效
    己二酸烷基酯的制备

    公开(公告)号：US4508917A

    公开(公告)日：1985-04-02

    申请号：US479937

    申请日：1983-03-29

    申请人： Jean Jenck

    发明人： Jean Jenck

    IPC分类号： B01J31/00 ,  C07B61/00 ,  C07C67/38 ,  C07C69/44

    CPC分类号： C07C67/38

    摘要： Alkyl adipates are prepared by reacting an alcohol and carbon monoxide with an alkyl pentenoate in the presence of (i) a catalytically effective amount of a cobalt catalyst, (ii) a tertiary nitrogen base, and (iii) hydrogen, with the hydrogen comprising at least 0.1% by volume of the carbon monoxide, and said reaction being carried out in (iv) an aromatic hydrocarbon or substituted aromatic hydrocarbon reaction medium.

    摘要翻译： 在（i）催化有效量的钴催化剂，（ii）叔氮碱和（iii）氢的存在下，使醇和一氧化碳与戊烯酸烷基酯反应制备己二酸烷基酯，其中氢包含 至少0.1体积％的一氧化碳，所述反应在（iv）芳族烃或取代的芳烃反应介质中进行。

    Preparation of .beta., .gamma.-unsaturated carboxylic acids
    9.
    发明授权
    Preparation of .beta., .gamma.-unsaturated carboxylic acids 失效
    （BETA），（氨基） - 脲基羧酸的制备

    公开(公告)号：US5081292A

    公开(公告)日：1992-01-14

    申请号：US516737

    申请日：1990-04-30

    申请人： Philippe Denis ,  Jean Jenck ,  Robert Perron

    发明人： Philippe Denis ,  Jean Jenck ,  Robert Perron

    IPC分类号： B01J27/13 ,  B01J31/04 ,  B01J31/24 ,  C07B61/00 ,  C07C51/12 ,  C07C57/02 ,  C07C57/13 ,  C07C57/30 ,  C07C61/08

    CPC分类号： C07C51/12

    摘要： .beta., .gamma.-Unsaturated carboxylic acids, e.g., 3-hexene-1,6-dioic acid, are selectively prepared by carbonylating (with carbon monoxide) an allyl alcohol, e.g., a butenediol, at an elevated temperature and under superatmospheric pressure, in the presence of a catalytically effective amount of a palladium-based catalyst and at least one quaternary onium chloride of one of the Group VB elements nitrogen or phosphorus, such element being tetracoordinated via carbon atoms and with the proviso that such nitrogen atom may be coordinated to two pentavalent phosphorus atoms.

    摘要翻译： β，γ-不饱和羧酸，例如3-己烯-1,6-二酸，通过在升高的温度和超大气压下羰基化（用一氧化碳）烯丙醇，例如丁烯二醇来选择性地制备， 存在催化有效量的钯基催化剂和至少一种VB族元素氮或磷之一的季铵氯化物，该元素通过碳原子四配位，条件是这样的氮原子可以配位到 两个五价磷原子。

    Preparation of hexene-1,6-dioic acids
    10.
    发明授权
    Preparation of hexene-1,6-dioic acids 失效
    HEXENE-1,6-DIOIC酸的制备

    公开(公告)号：US5077433A

    公开(公告)日：1991-12-31

    申请号：US516743

    申请日：1990-04-30

    申请人： Jean Jenck ,  Philippe Denis ,  Philippe Kalck ,  Helene Deweerdt

    发明人： Jean Jenck ,  Philippe Denis ,  Philippe Kalck ,  Helene Deweerdt

    IPC分类号： B01J23/44 ,  B01J27/13 ,  B01J31/04 ,  B01J31/12 ,  C07B61/00 ,  C07C51/12 ,  C07C51/14 ,  C07C57/13

    CPC分类号： C07C51/12

    摘要： The hexene-1,6-dioic acids, e.g., hex-3-ene-1,6-dioic acid, are prepared by reacting carbon monoxide and water with at least one diacyloxylated butene, in the presence of a catalytically effective amount of palladium and at least one quaternary onium chloride of one of the Group VB elements nitrogen or phosphorus, such element being tetracoordinated via carbon atoms and with the proviso that such nitrogen atom may be coordinated to two pentavalent phosphorus atoms.

    摘要翻译： 己烯-1,6-二酸，例如己-3-烯-1,6-二酸，是通过使一氧化碳和水与至少一种二酰氧基化丁烯在催化有效量的钯 和至少一种VB族元素氮或磷之一的季铵氯化物，该元素通过碳原子四配位，条件是这样的氮原子可以配位成两个五价磷原子。