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1.发明授权公开(公告)号：US08002953B2
公开(公告)日：2011-08-23
申请号：US11827896
申请日：2007-07-13
申请人： Fu-Ming Lee , Kuang-Yeu Wu , Lindsey Vuong , Fong-Cheng Su , Tzong-Bin Lin , Jyh-Haur Hwang , Hung-Chung Shen , Po-Sung Cheng , Tai-Ping Chang
发明人： Fu-Ming Lee , Kuang-Yeu Wu , Lindsey Vuong , Fong-Cheng Su , Tzong-Bin Lin , Jyh-Haur Hwang , Hung-Chung Shen , Po-Sung Cheng , Tai-Ping Chang
CPC分类号： C07C29/84 , B01D3/002 , B01D3/143 , B01D3/40 , Y02P20/125 , Y02P20/57 , Y10S203/14 , Y10S203/20 , C07C31/08
摘要： An energy-efficient extractive distillation process for producing anhydrous ethanol from aqueous/ethanol feeds containing any range of ethanol employs an extractive distillation column (EDC) that operates under no or greatly reduced liquid reflux conditions. The EDC can be incorporated into an integrated process for producing anhydrous ethanol used for gasoline blending from fermentation broth. By using a high-boiling extractive distillation solvent, no solvent is entrained by the vapor phase to the EDC overhead stream, even under no liquid reflux conditions. The energy requirement and severity of the EDC can be further improved by limiting ethanol recovery in the EDC. In this partial ethanol recovery design, ethanol which remains in the aqueous stream from the EDC is recovered in a post-distillation column or the aqueous stream is recycled to a front-end pre-distillation column where the ethanol is readily recovered since the VLE curve for ethanol/water is extremely favorable for distillation.
摘要翻译： 从含有任何范围的乙醇的含水/乙醇进料中生产无水乙醇的节能萃取蒸馏方法采用在没有或大大降低的液体回流条件下运行的萃取蒸馏塔（EDC）。 EDC可以并入用于从发酵液中生产用于汽油混合的无水乙醇的整合方法。 通过使用高沸点萃取蒸馏溶剂，即使在没有液体回流条件下，没有溶剂被气相夹带到EDC塔顶馏出物中。 通过限制EDC中的乙醇回收，可以进一步提高EDC的能量需求和严重程度。 在该部分乙醇回收设计中，保留在来自EDC的水流中的乙醇在后蒸馏塔中回收，或将水流循环至前端预蒸馏塔，其中乙醇容易回收，因为VLE曲线 对于乙醇/水非常有利于蒸馏。
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公开(公告)号：US07909966B2
公开(公告)日：2011-03-22
申请号：US11266124
申请日：2005-11-02
CPC分类号： B01D3/009 , B01D3/324 , Y10S261/72
摘要： The invention disclosed relates to catalytic distillation column internals providing improved liquid reaction mixture and catalyst contacting for simultaneous catalytic reaction and separation of the reaction mixture. The invention is an improved catalytic distillation apparatus providing optimum balance of catalytic reaction and mass transfer steps, wherein distribution, mixing and feeding of liquid reaction mixture to the reaction zone and distillation section are better controlled and more uniformly applied. At least one catalyst bed is situated in at least one receiving pan of a distillation tray so that the tray performs the functions of both of the reaction section and the distillation section of the catalytic distillation column simultaneously within a stage.
摘要翻译： 所公开的本发明涉及提供改进的液体反应混合物和催化剂接触以用于同时催化反应和分离反应混合物的催化蒸馏塔内部物质。 本发明是提供催化反应和传质步骤的最佳平衡的改进的催化蒸馏装置，其中液体反应混合物向反应区和蒸馏段的分配，混合和进料被更好地控制和更均匀地施加。 至少一个催化剂床位于蒸馏托盘的至少一个接收盘中，使得塔板在一个阶段内同时执行催化蒸馏塔的反应段和蒸馏段的功能。
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公开(公告)号：US20070095646A1
公开(公告)日：2007-05-03
申请号：US11266124
申请日：2005-11-02
申请人： Kuang-Yeu Wu , Pai-Yu Chiang , Tzong-Bin Lin , Hung-Chung Shen , Karl Chuang
发明人： Kuang-Yeu Wu , Pai-Yu Chiang , Tzong-Bin Lin , Hung-Chung Shen , Karl Chuang
CPC分类号： B01D3/009 , B01D3/324 , Y10S261/72
摘要： The invention disclosed relates to catalytic distillation column internals providing improved liquid and catalyst contacting for simultaneous catalytic reaction and separation of the reaction mixture. The invention provides an improved catalytic distillation system providing optimum balance of catalytic reaction and mass transfer steps, wherein distribution, mixing and application of liquid to the reaction zone and separation zones is better controlled and more uniformly applied. At least one catalyst bed is situated in at least one receiving pan of a distillation tray so that said tray performs the functions of both of the reaction section and the separation section of the catalytic distillation column simultaneously within a stage.
摘要翻译： 所公开的本发明涉及提供改进的液体和催化剂接触以用于同时催化反应和分离反应混合物的催化蒸馏塔内部物质。 本发明提供改进的催化蒸馏系统，其提供催化反应和传质步骤的最佳平衡，其中液体分配，混合和施加到反应区和分离区被更好地控制和更均匀地施加。 至少一个催化剂床位于蒸馏盘的至少一个容纳盘中，使得所述塔在阶段内同时执行催化蒸馏塔的反应段和分离段的功能。
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公开(公告)号：US07727383B2
公开(公告)日：2010-06-01
申请号：US11173317
申请日：2005-06-30
申请人： Tzong-Bin Lin , Hung-Chung Shen , Kuang-Yeu Wu
发明人： Tzong-Bin Lin , Hung-Chung Shen , Kuang-Yeu Wu
IPC分类号： C10G17/04
CPC分类号： C10G53/10 , C10G17/04 , C10G21/00 , C10G21/06 , C10G53/04 , C10G53/08 , C10G2300/104 , C10G2300/1044 , C10G2300/202 , C10G2300/301 , C10G2300/44 , C10G2300/805 , C10G2400/30
摘要： A highly effective liquid-liquid extraction process to remove nitrogen compounds and especially basic nitrogen compounds from aromatic light petroleum oils with excellent recovery employs de-ionized water, which can be acidified, as the extractive solvent. The product is an aromatic hydrocarbon with ultra-low amounts of nitrogen poisons that can deactivate acidic catalysts. The extracted oils are suitable feedstock for the subsequent catalytic processes that are promoted with the high performance solid catalysts, which are extremely sensitive to nitrogen poison.
摘要翻译： 作为提取溶剂，可以将能够酸化的去离子水用于从优异回收的芳族轻质石油中除去氮化合物，特别是碱性氮化合物的高效液 - 液萃取方法。 该产品是具有超低量氮氧化物的芳族烃，可以使酸性催化剂失活。 提取的油是用于随后的催化过程的合适的原料，其用对氮毒素非常敏感的高性能固体催化剂来促进。
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5.发明申请Integrated process for removing benzene from gasoline and producing cyclohexane 有权从汽油中除去苯并生产环己烷的综合工艺公开(公告)号：US20070299294A1
公开(公告)日：2007-12-27
申请号：US11475304
申请日：2006-06-27
申请人： Tzong-Bin Lin , Jyh-Haur Hwang , Hung-Chung Shen , Kuang-Yeu Wu
发明人： Tzong-Bin Lin , Jyh-Haur Hwang , Hung-Chung Shen , Kuang-Yeu Wu
IPC分类号： C07C7/17
CPC分类号： C07C13/18 , C07C5/10 , C07C7/08 , Y02P20/125 , C07C15/04
摘要： An integrated, continuous process for transforming feedstock, e.g., reformate, which contains high levels of benzene into a low-benzene content feedstock that is suitable for gasoline blending initially removes benzene from the reformate by extractive distillation, then partially hydrogenating the high purity benzene into cyclohexane under mild conditions in a one-stage hydrogenation reactor, and thereafter recovering a cyclohexane product with high purity from the hydrogenation reactor effluent in a back-end purification step using extractive distillation. The initial or front-end separation step yields a low-benzene content reformate.
摘要翻译： 将含有高含量苯的高含量苯转化为适用于汽油混合的低苯含量原料的重整产品的综合连续方法最初通过萃取蒸馏从重整产物中除去苯，然后将高纯度苯部分氢化 环己烷在一级氢化反应器中的温和条件下，然后使用萃取蒸馏在后端纯化步骤中从氢化反应器流出物回收高纯度的环己烷产物。 初始或前端分离步骤产生低苯含量的重整产物。
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公开(公告)号：US20070000809A1
公开(公告)日：2007-01-04
申请号：US11173317
申请日：2005-06-30
申请人： Tzong-Bin Lin , Hung-Chung Shen , Kuang-Yeu Wu
发明人： Tzong-Bin Lin , Hung-Chung Shen , Kuang-Yeu Wu
IPC分类号： C10G17/00
CPC分类号： C10G53/10 , C10G17/04 , C10G21/00 , C10G21/06 , C10G53/04 , C10G53/08 , C10G2300/104 , C10G2300/1044 , C10G2300/202 , C10G2300/301 , C10G2300/44 , C10G2300/805 , C10G2400/30
摘要： A highly effective liquid-liquid extraction process to remove nitrogen compounds and especially basic nitrogen compounds from aromatic light petroleum oils with excellent recovery employs de-ionized water, which can be acidified, as the extractive solvent. The product is an aromatic hydrocarbon with ultra-low amounts of nitrogen poisons that can deactivate acidic catalysts. The extracted oils are suitable feedstock for the subsequent catalytic processes that are promoted with the high performance solid catalysts, which are extremely sensitive to nitrogen poison.
摘要翻译： 作为提取溶剂，可以将能够酸化的去离子水用于从优异回收的芳族轻质石油中除去氮化合物，特别是碱性氮化合物的高效液 - 液萃取方法。 该产品是具有超低量氮氧化物的芳族烃，可以使酸性催化剂失活。 提取的油是用于随后的催化过程的合适的原料，其用对氮毒素非常敏感的高性能固体催化剂来促进。
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7.发明授权公开(公告)号：US08172987B2
公开(公告)日：2012-05-08
申请号：US13184540
申请日：2011-07-17
申请人： Fu-Ming Lee , Tzong-Bin Lin , Jyh-Haur Hwang , Hung-Chung Shen , Kuang-Yeu Wu , Lindsey Vuong , Fong-Cheng Su , Po-Sung Cheng , Tai-Ping Chang
发明人： Fu-Ming Lee , Tzong-Bin Lin , Jyh-Haur Hwang , Hung-Chung Shen , Kuang-Yeu Wu , Lindsey Vuong , Fong-Cheng Su , Po-Sung Cheng , Tai-Ping Chang
CPC分类号： C07C29/84 , B01D3/002 , B01D3/143 , B01D3/40 , Y02P20/125 , Y02P20/57 , Y10S203/14 , Y10S203/20 , C07C31/08
摘要： An energy-efficient extractive distillation process for producing anhydrous ethanol from aqueous/ethanol feeds containing any range of ethanol employs an extractive distillation column (EDC) that operates under no or greatly reduced liquid reflux conditions. The EDC can be incorporated into an integrated process for producing anhydrous ethanol used for gasoline blending from fermentation broth. By using a high-boiling extractive distillation solvent, no solvent, is entrained by the vapor phase to the EDC overhead stream, even under no liquid reflux conditions. The energy requirement and severity of the EDC can be further improved by limiting ethanol recovery in the EDC. In this partial ethanol recovery design, ethanol which remains in the aqueous stream from the EDC is recovered in a post-distillation column or the aqueous stream is recycled to a front-end pre-distillation column where the ethanol is readily recovered since the VLE curve for ethanol/water is extremely favorable for distillation.
摘要翻译： 从含有任何范围的乙醇的含水/乙醇进料中生产无水乙醇的节能萃取蒸馏方法采用在没有或大大降低的液体回流条件下运行的萃取蒸馏塔（EDC）。 EDC可以并入用于从发酵液中生产用于汽油混合的无水乙醇的整合方法。 通过使用高沸点萃取蒸馏溶剂，即使在没有液体回流条件下，也没有溶剂被气相夹带到EDC塔顶馏出物中。 通过限制EDC中的乙醇回收，可以进一步提高EDC的能量需求和严重程度。 在该部分乙醇回收设计中，保留在来自EDC的水流中的乙醇在后蒸馏塔中回收，或将水流循环至前端预蒸馏塔，其中乙醇容易回收，因为VLE曲线 对于乙醇/水非常有利于蒸馏。
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公开(公告)号：US20120037542A1
公开(公告)日：2012-02-16
申请号：US12854150
申请日：2010-08-10
申请人： Kuang-Yeu Wu , Tzong-Bin Lin , Fu-Ming Lee , Tsung-Min Chiu , Jyh-Haur Hwang , Hung-Chung Shen
发明人： Kuang-Yeu Wu , Tzong-Bin Lin , Fu-Ming Lee , Tsung-Min Chiu , Jyh-Haur Hwang , Hung-Chung Shen
IPC分类号： C10G21/28
CPC分类号： C07C7/08 , C07D333/48 , C10G21/28 , C10G2300/1081 , C10G2300/1088 , C10G2300/1096 , C10G2300/44 , C10G2300/805 , C07C15/04 , C07C15/06
摘要： An improved solvent regeneration system for extractive distillation and liquid-liquid extraction processes capable of effectively removing heavy hydrocarbons and polymeric materials that otherwise develop in a closed solvent loop. The improved process employs a light hydrocarbon displacement agent, which is at least partially soluble in the solvent to squeeze the heavy hydrocarbons and polymeric materials out of the solvent, with virtually no additional energy requirement. It has been demonstrated that the light non-aromatic hydrocarbons in the raffinate stream generated from the extractive distillation or the liquid-liquid extractive process for aromatic hydrocarbons recovery can displace not only the heavy non-aromatic hydrocarbons but also the heavy aromatic hydrocarbons from the extractive solvent, especially when the aromatic hydrocarbons in the solvent are in the C10+ molecular weight range.
摘要翻译： 用于萃取蒸馏和液 - 液萃取方法的改进的溶剂再生系统，其能够有效地除去否则在密闭的溶剂回路中发展的重质烃和聚合材料。 改进的方法采用轻质烃置换剂，其至少部分可溶于溶剂以将重质烃和聚合物材料挤出溶剂，实际上无需额外的能量需求。 已经证明，从萃取蒸馏或用于芳族烃回收的液 - 液萃取过程产生的萃余液流中的轻非芳族烃不仅可以取代重非芳族烃，而且可以取代萃取物中的重芳香烃 溶剂，特别是当溶剂中的芳烃为C10 +分子量范围时。
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9.发明申请公开(公告)号：US20110266134A1
公开(公告)日：2011-11-03
申请号：US13184540
申请日：2011-07-17
申请人： Fu-Ming Lee , Tzong-Bin Lin , Jyh-Haur Hwang , Hung-Chung Shen , Kuang-Yeu Wu , Lindsey Vuong , Fong-Cheng Su , Po-Sung Cheng , Tai-Ping Chang
发明人： Fu-Ming Lee , Tzong-Bin Lin , Jyh-Haur Hwang , Hung-Chung Shen , Kuang-Yeu Wu , Lindsey Vuong , Fong-Cheng Su , Po-Sung Cheng , Tai-Ping Chang
IPC分类号： C07C29/84
CPC分类号： C07C29/84 , B01D3/002 , B01D3/143 , B01D3/40 , Y02P20/125 , Y02P20/57 , Y10S203/14 , Y10S203/20 , C07C31/08
摘要： An energy-efficient extractive distillation process for producing anhydrous ethanol from aqueous/ethanol feeds containing any range of ethanol employs an extractive distillation column (EDC) that operates under no or greatly reduced liquid reflux conditions. The EDC can be incorporated into an integrated process for producing anhydrous ethanol used for gasoline blending from fermentation broth. By using a high-boiling extractive distillation solvent, no solvent, is entrained by the vapor phase to the EDC overhead stream, even under no liquid reflux conditions. The energy requirement and severity of the EDC can be further improved by limiting ethanol recovery in the EDC. In this partial ethanol recovery design, ethanol which remains in the aqueous stream from the EDC is recovered in a post-distillation column or the aqueous stream is recycled to a front-end pre-distillation column where the ethanol is readily recovered since the VLE curve for ethanol/water is extremely favorable for distillation.
摘要翻译： 从含有任何范围的乙醇的含水/乙醇进料中生产无水乙醇的节能萃取蒸馏方法采用在没有或大大降低的液体回流条件下运行的萃取蒸馏塔（EDC）。 EDC可以并入用于从发酵液中生产用于汽油混合的无水乙醇的整合方法。 通过使用高沸点萃取蒸馏溶剂，即使在没有液体回流条件下，也没有溶剂被气相夹带到EDC塔顶馏出物中。 通过限制EDC中的乙醇回收，可以进一步提高EDC的能量需求和严重程度。 在该部分乙醇回收设计中，保留在来自EDC的水流中的乙醇在后蒸馏塔中回收，或将水流循环至前端预蒸馏塔，其中乙醇容易回收，因为VLE曲线 对于乙醇/水非常有利于蒸馏。
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10.发明申请公开(公告)号：US20090014313A1
公开(公告)日：2009-01-15
申请号：US11827896
申请日：2007-07-13
申请人： Fu-Ming Lee , Kuang-Yeu Wu , Lindsey Vuong , Fong-Cheng Su , Tzong-Bin Lin , Jyh-Haur Hwang , Hung-Chung Shen , Po-Sung Cheng , Tai-Ping Chang
发明人： Fu-Ming Lee , Kuang-Yeu Wu , Lindsey Vuong , Fong-Cheng Su , Tzong-Bin Lin , Jyh-Haur Hwang , Hung-Chung Shen , Po-Sung Cheng , Tai-Ping Chang
IPC分类号： C07C31/08
CPC分类号： C07C29/84 , B01D3/002 , B01D3/143 , B01D3/40 , Y02P20/125 , Y02P20/57 , Y10S203/14 , Y10S203/20 , C07C31/08
摘要： An energy-efficient extractive distillation process for producing anhydrous ethanol from aqueous/ethanol feeds containing any range of ethanol employs an extractive distillation column (EDC) that operates under no or greatly reduced liquid reflux conditions. The EDC can be incorporated into an integrated process for producing anhydrous ethanol used for gasoline blending from fermentation broth. By using a high-boiling extractive distillation solvent, no solvent is entrained by the vapor phase to the EDC overhead stream, even under no liquid reflux conditions. The energy requirement and severity of the EDC can be further improved by limiting ethanol recovery in the EDC. In this partial ethanol recovery design, ethanol which remains in the aqueous stream from the EDC is recovered in a post-distillation column or the aqueous stream is recycled to a front-end pre-distillation column where the ethanol is readily recovered since the VLE curve for ethanol/water is extremely favorable for distillation.
摘要翻译： 从含有任何范围的乙醇的含水/乙醇进料中生产无水乙醇的节能萃取蒸馏方法采用在没有或大大降低的液体回流条件下运行的萃取蒸馏塔（EDC）。 EDC可以并入用于从发酵液中生产用于汽油混合的无水乙醇的整合方法。 通过使用高沸点萃取蒸馏溶剂，即使在没有液体回流条件下，没有溶剂被气相夹带到EDC塔顶馏出物中。 通过限制EDC中的乙醇回收，可以进一步提高EDC的能量需求和严重程度。 在该部分乙醇回收设计中，保留在来自EDC的水流中的乙醇在后蒸馏塔中回收，或将水流循环至前端预蒸馏塔，其中乙醇容易回收，因为VLE曲线 对于乙醇/水非常有利于蒸馏。
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