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公开(公告)号：US3830752A
公开(公告)日：1974-08-20
申请号：US29761872
申请日：1972-10-16
Applicant: UNION OIL CO
Inventor： MICKELSON G
IPC: B01J23/85 , B01J27/185 , B01J27/188 , B01J35/04 , B01J37/02 , C10G49/04 , B01J11/06 , B01J11/82
CPC classification number: B01J37/0201 , B01J23/85 , B01J27/1853 , B01J27/188 , B01J35/04 , C10G49/04
Abstract: HYDROCARBON CONVERSION CATALYSTS OF IMPROVED ACTIVITY ARE OBTAINED BY ACTIVATING FORMAMINOUS REFRACTORY OXIDES COMBINED WITH AT LEAST ONE THERMALLY DECOMPOSABLE AND/ OR OXIDIZABLE COMPOUND OF A CATALYTICALLY ACTIVE METAL UPON CALCINATION WHILE CONTACTING THE COMPOSITE WITH AN ACCELERATED FLOW OF AN OXIDIZING GAS AT A RATE OF AT LEAST ABOUT 2 S.C.F.M. PER POUND OF SAID COMPOSITE. FURTHER ADVANTAGE IS REALIZED BY HEATING THE COMPOSITE TO THE PRESCRIBED CALCINATION TEMPERATURE AT A CONTROLLED GRADUAL RATE. IT IS ALSO GENERALLY DESIRABLE TO ASSURE THAT THE INLET TEMPERATURE OF THE OXIDIZING GAS PRIOR TO CONTACT WITH THE COMPOSITE IS LESS THAN ABOUT 500*F.
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公开(公告)号：US3755150A
公开(公告)日：1973-08-28
申请号：US3755150D
申请日：1971-04-01
Applicant: UNION OIL CO
Inventor： MICKELSON G
CPC classification number: C10G45/08
Abstract: A superior hydrogenative desulfurization process includes reacting hydrogen with a hydrocarbon feed under conditions sufficient to promote said reaction and in the presence of a catalytic combination of at least one molybdenum compound and at least one Group VIII metal or metal compound prepared by impregnating a foraminous refractory oxide support with a highly stable solution of the metal compounds and an acid of phosphorus wherein the impregnating solution has a P/MoO3 weight ratio of about 0.1 to about 0.25 and an initial pH of about 1 to about 2. Even a greater advantage relative to previously available hydrogenative hydrocarbon conversion systems is realized when operating on feed-stocks containing substantial amounts of organonitrogen compounds.
Abstract translation: 优异的氢化脱硫方法包括在足以促进所述反应的条件下和在至少一种钼化合物和至少一种通过浸渍有孔耐火氧化物制备的至少一种VIII族金属或金属化合物的催化组合的存在下，使氢气与烃进料反应 用金属化合物和磷酸的高度稳定的溶液支撑，其中浸渍溶液的P / MoO 3重量比为约0.1至约0.25，初始pH为约1至约2.即使相对于先前的更大的优点 当对含有大量有机氮化合物的原料进行操作时，实现可用的氢化烃转化体系。
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公开(公告)号：US3749664A
公开(公告)日：1973-07-31
申请号：US3749664D
申请日：1971-04-01
Applicant: UNION OIL CO
Inventor： MICKELSON G
Abstract: HYDROCARBONS CONTAINING ORGANONITROGEN COMPOUNDS ARE DENITROGENATED BY REACTING HYDROGEN WITH THE HYDROCARBON FEED UNDER DENITROGENATION CONDITIONS IN THE PRESENCE OF A CATALYTIC COMBINATION OF AT LEAST ONE MOLYBDENUM COMPOUND AND AT LEAST ONE GROUP VIII METAL OR METAL COMPOUND PREPARED BY IMPREGNATING A FORAMINOUS REFRACTORY OXIDE SUPPORT WITH A HIGHLY STABLE SOLUTION OF THE METAL COMPOUNDS AND AN ACID OF PHOSPHORUS WHEREIN THE IMPREGNATING SOLUTION HAS A P/M0O3 WEIGHT RATIO OF ABOUT 0.1 TO ABOUT 0.25 AND AN INITIAL PH OF ABOUT 1 TO ABOUT 2.
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Patent Agency Ranking
公开(公告)号：US3755196A
公开(公告)日：1973-08-28
申请号：US3755196D
申请日：1971-04-01
Applicant: UNION OIL CO
Inventor： MICKELSON G
Abstract: Highly active catalysts of molybdenum and Group VIII metals are prepared by impregnating a support with highly stable solutions of the active metal compounds and an acid of phosphorus having a P/MoO3 weight ratio of 0.1-0.25 and an initial pH of 1 to about 2.
Abstract translation: 通过用活性金属化合物的高度稳定的溶液浸渍载体和P / MoO 3重量比为0.1-0.25，初始pH为1至约2的磷的酸制备钼和Ⅷ族金属的高活性催化剂。
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公开(公告)号：US3749663A
公开(公告)日：1973-07-31
申请号：US3749663D
申请日：1971-04-01
Applicant: UNION OIL CO
Inventor： MICKELSON G
Abstract: A SUPERIOR HYDROGENATIVE HYDROCARBON CONVERSION PROCESS INCLUDES REACTING HYDROGEN WITH A HYDROCARBON FEED UNDER CONDITIONS SUFFICIENT TO PROMOTE SAID REACTION IN THE PRESENCE OF A CATALYTIC COMBINATION OF AT LEAST ONE MOLYBDENUM COMPOUND AND AT LEAST ONE GROUP VIII METAL OR METAL COMPOUND PREPARED BY IMPREGNATING A FORAMINOUS REFRACTORY OXIDE SUPPORT WITH A HIGHLY STABLE SOLUTION OF THE METAL COMPOUNDS AND AN ACID OF PHOSPHORUS WHEREIN THE IMPREGNATING SOLUTION HAS A P/M0O3 WEIGHT RATIO OF ABOUT 0.1 TO ABOUT 0.25 AND AN INITIAL PH OF ABOUT 1 TO ABOUT 2. WVEN GREATER ADVANTAGE RELATIVE TO PREVIOUSLY AVAILABLE HYDROGENATIVE HYDROCARBON CONVERSION SYSTEMS IS REALIZED WHEN OPERATING ON FEEDSTOCKS CONTAINING SUBSTANTIAL AMOUNTS OF ORGANONITROGEN AND/OR AROMATIC COMPOUNDS.
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公开(公告)号：US3817873A
公开(公告)日：1974-06-18
申请号：US32628173
申请日：1973-01-24
Applicant: UNION OIL CO
Inventor： MICKELSON G
IPC: B01J23/85 , B01J27/185 , B01J27/188 , B01J35/04 , C10G49/04 , B01J11/82 , B01J11/40
CPC classification number: B01J35/04 , B01J23/85 , B01J27/1853 , B01J27/188 , C10G49/04
Abstract: HYDROCARBON CONVERSION PROCESSES INCLUDING HYDROCRACKING, DENITROGENATION AND HYDROGENATION OF IMPROVED ACTIVITY ARE OBTAINED BY THE USE OF CATALYSTS PREPARED BY ACTIVATING FORAMINOUS REFRACTORY OXIDES COMBINED WITH AT LEAST ONE THERMALLY DECOMPOSABLE AND/OR OXIDIZABLE COMPOUND OF A CATALYTICALLY ACTIVE METAL UPON CALCINATION WHILE CONTACTING THE COMPOSITE WITH AN ACCELERATED FLOW OF AN OXIDIZING GAS AT A RATE OF AT LEAST ABOUT 2 S.C.F.M. PER POUND OF SAID COMPOSITE. FURTHER ADVANTAGE IS REALIZED BY HEATING THE COMPOSITE TO THE PRESCRIBED CALCINATION TEMPERATURE AT A CONTROLLED GRADUAL RATE. IT IS ALSO GENERALLY DESIRABLE TO ASSURE THAT THE INLET TEMPERATURE OF THE OXIDIZING GAS PRIOR TO CONTACT WITH THE COMPOSITE IS LESS THAN ABOUT 500*F.
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公开(公告)号：US3755148A
公开(公告)日：1973-08-28
申请号：US3755148D
申请日：1971-04-01
Applicant: UNION OIL CO
Inventor： MICKELSON G
CPC classification number: C10G45/00 , C10G45/50 , Y10S585/906
Abstract: Hydrocarbons having at least one point of carbon-to-carbon unsaturation are reacted with hydrogen under hydrogenation conditions including a catalytic combination of at least one molybdenum compound and at least one Group VIII metal or metal compound prepared by impregnating a foraminous refractory oxide support with a highly stable solution of the metal compounds and an acid of phosphorus wherein the impregnating solution has a P/MoO3 weight ratio of about 0.1 to about 0.25 and an initial pH of about 1 to about 2. Even greater advantage relative to previously available hydrogenation systems is realized when operating on feedstocks containing substantial amounts of organonitrogen compounds.
Abstract translation: 具有至少一个碳 - 碳不饱和点的碳氢化合物在氢化条件下与氢气反应，包括至少一种钼化合物和至少一种第Ⅷ族金属或金属化合物的催化组合，所述金属或金属化合物通过将有孔耐火氧化物载体浸渍在 金属化合物和磷酸的高度稳定的溶液，其中浸渍溶液具有约0.1至约0.25的P / MoO 3重量比和约1至约2的初始pH。相对于先前可获得的氢化体系，更大的优点是 当对含有大量有机氮化合物的原料进行操作时实现。
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8.发明授权
公开(公告)号：US3725243A
公开(公告)日：1973-04-03
申请号：US3725243D
申请日：1970-07-10
Applicant: UNION OIL CO
CPC classification number: B01J29/061 , C10G49/08
Abstract: HYDROCARBON CONVERSION CATALYSTS HAVING MARKEDLY IMPROVED CHARACTERISTICS ARE PREPARED FROM INTIMATE ADMIXTURES OF FORAMINOUS ALUMINA-CONTAINING REFRACTORY OXIDES AND ION EXCHANGEABLE CRYSTALLINE ALUMINOSILICATE ZEOLITES BY IMPREGNATION WITH A STRONG ACIDIC SOLUTION CONTAINING GROUP VIII AND GROUP VI METAL COMPOUNDS AND AN ACID OF PHOSPHORUS AT A PH BELOW 3, TO SUBSTANTIALLY DESTROY THE ZEOLITE CRYSTALLINITY.
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