Isoparaffin-olefin alkylation utilizing crystalline aluminosilicate catalyst in an adsorption zone
    10.
    发明授权
    Isoparaffin-olefin alkylation utilizing crystalline aluminosilicate catalyst in an adsorption zone 失效
    在吸附区使用结晶硅铝酸盐催化剂的异链烷烃烯烃烷基化

    公开(公告)号:US3917738A

    公开(公告)日:1975-11-04

    申请号:US47041374

    申请日:1974-05-16

    IPC分类号: C07C2/58 C07C3/52

    CPC分类号: C07C2/58 C07C2529/10

    摘要: A process for alkylating an isoparaffin with an olefin using a solid, particulate catalyst capable of adsorbing the olefin. The isoparaffin and the olefin are admixed to form a reactants stream in contact with catalyst particles at the upstream end of an adsorption zone; the reactants stream and catalyst particles are passed cocurrently through the adsorption zone without back mixing, at controlled relative velocities, so that a controlled amount of olefin is adsorbed onto the catalyst and removed from the reactants stream as the catalyst and hydrocarbons are passed cocurrently through the adsorption zone; reactants stream and catalyst particles having olefin adsorbed thereon are withdrawn from the downstream end of the adsorption zone and contacted in an alkylation reaction zone to alkylate the isoparaffin with previously adsorbed olefin; and the alkylation reaction product is recovered from the hydrocarbon effluent from the alkylation zone.

    摘要翻译: 使用能够吸附烯烃的固体颗粒催化剂用烯烃烷基化异链烷烃的方法。 将异链烷烃和烯烃混合以在吸附区的上游端形成与催化剂颗粒接触的反应物流; 反应物流和催化剂颗粒在受控的相对速度下并流通过吸附区,而不受反相混合的影响,使得受控量的烯烃吸附到催化剂上并从反应物流中除去,因为催化剂和烃通过并流通过 吸附区; 从吸附区的下游端排出具有吸附有烯烃的反应物料流和催化剂颗粒,并在烷基化反应区中与预先吸附的烯烃烷基化异构烷烃; 并从烷基化区的烃流出物回收烷基化反应产物。