ONLINE MONITOR FOR TRACE SODIUM IN HIGH-PURITY WATER, AND ONLINE MONITORING METHOD AND DEVICE THEREOF

    公开(公告)号:US20190178864A1

    公开(公告)日:2019-06-13

    申请号:US16236368

    申请日:2018-12-29

    摘要: An online monitor for trace sodium in high-purity water, and an online monitoring method and device thereof are provided. Under the control of an embedded industrial computer, an injection-calibration system conveys calibrated water samples and to-be-measured water samples to a flame atomization system continuously and stably. The flame atomization system forms a negative pressure field using a high-purity hydrogen-oxygen mixture as carrier gas, draws in the to-be-measured water samples for atomization, mixing and droplet separation, and then ignites a characteristic spectrum which emits sodium at a high-temperature inner cone. A photoelectric sensor system quickly scans the characteristic spectrum of sodium, and outputs a second-order differential modulation sodium spectrum after removing background interferences. A data acquisition system acquires an analog signal of the second-order differential modulation sodium spectrum, converts the analog signal into a digital signal and outputs the digital signal to the embedded industrial computer for real-time monitoring and control.

    Gas analysis apparatus
    2.
    发明授权

    公开(公告)号:US10132785B2

    公开(公告)日:2018-11-20

    申请号:US15592992

    申请日:2017-05-11

    申请人: HORIBA, Ltd.

    摘要: In a gas analysis apparatus including analyzers that need ignition, such as FIDs, in order to make it possible to surely ignite the analyzers while downsizing the entire apparatus, the apparatus includes first and second analyzers to accept a sample gas, a first gas line provided with the first analyzer, a second gas line provided with the second analyzer and joined downstream of the first analyzer in the first gas line. At least one of the first analyzer and the second analyzer is configured to cause pressure fluctuations in the gas line including the analyzer when analyzing the sample gas. A first backflow prevention mechanism is disposed between another of the analyzers and a junction of the gas lines. The first backflow prevention mechanism is configured to prevent a fluid from flowing backward from the one of the analyzers through the junction toward the another of the analyzers.

    Online detection method of gaseous alkali metal concentration in boiler burning flame

    公开(公告)号:US09651480B2

    公开(公告)日:2017-05-16

    申请号:US15104427

    申请日:2015-06-04

    发明人: Chun Lou Yanfei Tian

    摘要: Provided is an online detection method of gaseous alkali metal concentration in boiler burning flame. The method includes selecting the user characteristic spectral line to be measured; based on the characteristic spectral line of the alkali metal, constructing a fitting model between radiation strength of the characteristic spectral line of the alkali metal in the burning flame and the gaseous alkali metal concentration and flame temperature; calibrating the spectrograph under absolute radiation strength; measuring a flame object corresponding to an alkali metal concentration by the calibrated spectrograph to obtain the radiation strength and flame temperature of the characteristic spectral line of the alkali metal. The detection method can detect the concentration of the gaseous alkali metal in the burning flame of the detection furnace quickly and accurately as well as detect the content of the base metals, involves simple devices, low cost, and is suitable for field measurement.

    Method of detecting defects in ion exchange membranes of electrochemical cells by chemochromic sensors
    5.
    发明授权
    Method of detecting defects in ion exchange membranes of electrochemical cells by chemochromic sensors 有权
    通过化学传感器检测电化学电池离子交换膜缺陷的方法

    公开(公告)号:US09228954B2

    公开(公告)日:2016-01-05

    申请号:US13594163

    申请日:2012-08-24

    IPC分类号: G01N21/72 G01N21/78 H01M8/10

    CPC分类号: G01N21/78 H01M2008/1095

    摘要: A method of detecting defects in membranes such as ion exchange membranes of electrochemical cells. The electrochemical cell includes an assembly having an anode side and a cathode side with the ion exchange membrane in between. In a configuration step a chemochromic sensor is placed above the cathode and flow isolation hardware lateral to the ion exchange membrane which prevents a flow of hydrogen (H2) between the cathode and anode side. The anode side is exposed to a first reactant fluid including hydrogen. The chemochromic sensor is examined after the exposing for a color change. A color change evidences the ion exchange membrane has at least one defect that permits H2 transmission therethrough.

    摘要翻译: 检测电化学电池的离子交换膜等缺陷的方法。 电化学电池包括具有阳极侧和阴极侧的组件,其间具有离子交换膜。 在配置步骤中,化学发光传感器被放置在阴极上方,并且离子交换膜侧面具有流动隔离硬件,其防止阴极和阳极侧之间的氢(H2)流动。 阳极侧暴露于包括氢的第一反应物流体。 化学感光体在曝光后进行颜色变化检查。 颜色变化证明离子交换膜具有至少一个允许H 2透过的缺陷。

    Corrosion simulator and corresponding method
    7.
    发明授权
    Corrosion simulator and corresponding method 失效
    腐蚀模拟器及相应的方法

    公开(公告)号:US08084267B2

    公开(公告)日:2011-12-27

    申请号:US12531528

    申请日:2008-03-19

    CPC分类号: G01N17/002

    摘要: A laboratory degradation test system for testing degradation of a test specimen in a test fluid flow includes a reactor assembly, which reactor assembly comprises: a reactor vessel, the reactor vessel having a reaction space, an inlet and an outlet and a specimen holder for retaining a test specimen inside the reactor vessel, a heater for heating the reactor vessel, a fluid circulation system generating a test fluid flow over the test specimen, which fluid circulation system comprises: a circulation line which extends between the outlet of the reactor vessel and the inlet of the reactor vessel, which circulation line is arranged outside the reactor vessel, a pump for providing fluid circulation through the circulation line and the reactor vessel, which pump is arranged in the circulation line. The volume available to the test fluid inside the reaction space after insertion of the degradation test specimen is less than or equal to 10 ml.

    摘要翻译: 用于测试测试流体流中的测试样品的降解的实验室降解测试系统包括反应器组件,该反应器组件包括:反应器容器,具有反应空间的反应器容器,入口和出口以及用于保持 反应器容器内的试样,用于加热反应容器的加热器,在试样上产生测试流体流体的流体循环系统,该流体循环系统包括:循环管线,其在反应堆容器的出口和 反应器容器的入口,该循环管线布置在反应器容器的外部,用于通过循环管线和反应器容器提供流体循环的泵,该泵布置在循环管线中。 插入降解试样后反应空间内的测试液体的体积可以小于或等于10毫升。

    Method, particle sensor and particle sensor system for measuring particles
    8.
    发明授权
    Method, particle sensor and particle sensor system for measuring particles 有权
    方法,粒子传感器和粒子传感器系统测量粒子

    公开(公告)号:US08030086B2

    公开(公告)日:2011-10-04

    申请号:US11629740

    申请日:2005-04-26

    IPC分类号: G01N21/72

    摘要: A method and a particle sensor for measuring particles, especially soot particles, in which the particles to be detected accumulate in a measuring region of the particle sensor. The particles located in the gas stream or the particles already accumulated in the measuring region are burned by a combustion device, the combustion being controlled via a control signal from a control unit, which is electrically connected to a measuring device, in such a way that the quantity of the particles adhering in the measuring region remains constant. The physical variable of the combustion device, which leads to the controlled combustion of the particles, is drawn upon as the signal amplitude of the particle sensor.

    摘要翻译: 一种用于测量颗粒,特别是烟灰颗粒的方法和颗粒传感器,其中待检测的颗粒聚集在颗粒传感器的测量区域中。 位于气流中的颗粒或已经积聚在测量区域中的颗粒被燃烧装置燃烧,燃烧通过控制信号控制,该控制信号与控制单元电连接,测量装置以这样一种方式 附着在测量区域中的颗粒的量保持恒定。 导致颗粒受控燃烧的燃烧装置的物理变量被绘制为颗粒传感器的信号幅度。

    Method and apparatus for measuring isotopic characteristics
    9.
    发明授权
    Method and apparatus for measuring isotopic characteristics 有权
    用于测量同位素特征的方法和装置

    公开(公告)号:US07976780B2

    公开(公告)日:2011-07-12

    申请号:US11203796

    申请日:2005-08-15

    摘要: Methods and apparatus are provided to measure isotopic characteristics of a number of sample types. Embodiments of the invention combine novel and existing components to produce more accurate isotopic information. Further, embodiments of the invention allow for isotopic readings to be taken and analyzed outside of a laboratory. An example of such an embodiment is an apparatus comprising a combustion furnace; a reactant tube passing through the combustion furnace; an injector coupled to one, or a combination of, the combustion furnace, and reactant tube, to introduce a sample; a laser isotopic measurement device coupled to the reactant tube on the exit end; and a processor electrically coupled to one, or a combination of, the injector, the combustion furnace, the reactant tube, and the isotopic measurement device, in which a carrier gas transports the sample through the apparatus.

    摘要翻译: 提供了用于测量多种样品类型的同位素特征的方法和装置。 本发明的实施方案结合了新颖的和现有的组分以产生更精确的同位素信息。 此外,本发明的实施例允许在实验室外采取和分析同位素读数。 这种实施例的一个实例是包括燃烧炉的装置; 通过燃烧炉的反应物管; 连接到燃烧炉和反应物管的一个或组合的喷射器以引入样品; 在出口端耦合到反应物管的激光同位素测量装置; 以及处理器,电耦合到喷射器,燃烧炉,反应物管和同位素测量装置中的一个或其组合,其中载气将样品输送通过装置。

    Method for influencing and monitoring the oxide layer on metallic components of hot CO2/H20 cycle systems
    10.
    发明授权
    Method for influencing and monitoring the oxide layer on metallic components of hot CO2/H20 cycle systems 有权
    影响和监测热CO2 / H20循环系统金属部件氧化层的方法

    公开(公告)号:US07618825B2

    公开(公告)日:2009-11-17

    申请号:US11033166

    申请日:2005-01-12

    申请人: Werner Balbach

    发明人: Werner Balbach

    IPC分类号: G01N21/72

    摘要: A method for influencing and monitoring the oxide layer on metallic components of hot CO2/H2O cycle systems, in particular of CO2/H2O gas turbine installations, in which a hydrocarbon-containing fuel is burnt with oxygen, and the excess CO2 and H2O formed is removed from the cycle system at a suitable location. To protect the oxide layer of the components which are under thermal load, an excess of oxygen is used, the level of which is dependent on the current state of the oxide layer, the state of the oxide layer being determined by periodic and/or continuous measurements.

    摘要翻译: 一种影响和监测热二氧化碳/水循环系统的金属组分,特别是CO2 / H2O燃气轮机装置的氧化物层的方法,其中含烃燃料用氧气燃烧,并且形成的过量CO 2和H 2 O是 在适当的位置从循环系统中移除。 为了保护热负荷下的组分的氧化物层,使用过量的氧,其水平取决于氧化物层的当前状态,氧化物层的状态由周期性和/或连续性决定 测量。