Contaminant removal from hydrocarbon streams with lewis acidic ionic liquids
    4.
    发明授权
    Contaminant removal from hydrocarbon streams with lewis acidic ionic liquids 有权
    污染物从含有路易斯酸性离子液体的烃流中去除

    公开(公告)号:US09574139B2

    公开(公告)日:2017-02-21

    申请号:US14552345

    申请日:2014-11-24

    Applicant: UOP LLC

    CPC classification number: C10G17/07 C10G21/18 C10G55/06 C10G67/08 C10G2300/202

    Abstract: Processes for removing sulfur and nitrogen contaminants from hydrocarbon streams are described. The processes include contacting the hydrocarbon stream comprising the contaminant with lean halometallate ionic liquid an organohalide resulting in a mixture comprising the hydrocarbon and rich halometallate ionic liquid comprising the contaminant. The mixture is separated to produce a hydrocarbon effluent and a rich halometallate ionic liquid effluent comprising the rich halometallate ionic liquid comprising the contaminant.

    Abstract translation: 描述了从烃流中除去硫和氮污染物的方法。 所述方法包括使包含污染物的烃流与贫卤金属离子液体接触,产生包含烃和富含卤代金属离子液体的混合物的有机卤化物,所述混合物包含污染物。 将混合物分离以产生烃流出物和富含卤代金属离子液体流出液,其包含含有污染物的富含卤代金属离子液体。

    PROCESS FOR REGENERATING IONIC LIQUIDS BY ADDING LIGHT HYDROCARBON STREAM
    6.
    发明申请
    PROCESS FOR REGENERATING IONIC LIQUIDS BY ADDING LIGHT HYDROCARBON STREAM 审中-公开
    通过添加轻烃循环再生离子液的方法

    公开(公告)号:US20140291208A1

    公开(公告)日:2014-10-02

    申请号:US13851509

    申请日:2013-03-27

    Applicant: UOP LLC

    CPC classification number: C10G21/28 C10G21/27 C10G2300/201

    Abstract: A process for removing at least one impurity from a hydrocarbon feed such as vacuum gas oil in which the process includes the steps of contacting the feed with a hydrocarbon-immiscible phosphonium ionic liquid to produce a hydrocarbon and hydrocarbon-immiscible phosphonium ionic liquid mixture, and separating the mixture to produce a hydrocarbon effluent having a reduced impurity content relative to the hydrocarbon feed.

    Abstract translation: 一种从烃进料如真空瓦斯油中除去至少一种杂质的方法,其中该方法包括使进料与烃不混溶的鏻离子液体接触以产生烃和烃不混溶的鏻离子液体混合物的步骤,以及 分离混合物以产生相对于烃进料具有降低的杂质含量的烃流出物。

    SLURRY HYDROCRACKING PROCESS
    7.
    发明申请
    SLURRY HYDROCRACKING PROCESS 有权
    水泥加工工艺

    公开(公告)号:US20140102944A1

    公开(公告)日:2014-04-17

    申请号:US13652439

    申请日:2012-10-15

    Applicant: UOP LLC

    CPC classification number: C10G47/02 C10G47/04 C10G47/26

    Abstract: One exemplary embodiment can be a slurry hydrocracking process. The process can include providing one or more hydrocarbon compounds having an initial boiling point temperature of at least about 340° C., and a slurry catalyst to a slurry hydrocracking zone. The slurry catalyst may have about 32- about 50%, by weight, iron; about 3- about 14%, by weight, aluminum; no more than about 10%, by weight, sodium; and about 2- about 10%, by weight, calcium. Typically, all catalytic component percentages are as metal and based on the weight of the dried slurry catalyst.

    Abstract translation: 一个示例性实施方案可以是浆料加氢裂化方法。 该方法可以包括提供一种或多种具有至少约340℃的初始沸点温度的烃化合物,以及将淤浆催化剂提供给浆料加氢裂化区。 浆料催化剂可以具有约32-约50重量%的铁; 约3-约14重量%的铝; 不超过约10重量%的钠; 和约2-约10重量%的钙。 通常,所有的催化组分百分数都是金属,并且基于干浆料催化剂的重量。

    DECONTAMINATION OF DEOXYGENATED BIOMASS-DERIVED PYROLYSIS OIL USING IONIC LIQUIDS
    8.
    发明申请
    DECONTAMINATION OF DEOXYGENATED BIOMASS-DERIVED PYROLYSIS OIL USING IONIC LIQUIDS 有权
    使用离子液体去除生物质衍生的热解油的去除

    公开(公告)号:US20140005451A1

    公开(公告)日:2014-01-02

    申请号:US13633637

    申请日:2012-10-02

    Applicant: UOP LLC

    Abstract: Embodiments of methods for purifying a biomass-derived pyrolysis oil are provided. The method comprises the step of contacting the biomass-derived pyrolysis oil with a first deoxygenating catalyst in the presence of hydrogen at first predetermined hydroprocessing conditions to form a first low-oxygen biomass-derived pyrolysis oil effluent. The low-oxygen biomass-derived pyrolysis oil effluent is contacted with an ionic liquid to remove phenolic compounds, nitrogen compounds and other impurities. This ionic liquid step may be followed by a second deoxygenation step or the deoxygenating may be completed and then followed by the ionic liquid purification step.

    Abstract translation: 提供了用于纯化生物质衍生的热解油的方法的实施方案。 该方法包括在第一预定加氢处理条件下,在氢存在下使生物质衍生的热解油与第一脱氧催化剂接触的步骤,以形成第一低氧生物质衍生的热解油流出物。 将低氧生物质衍生的热解油流出物与离子液体接触以除去酚类化合物,氮化合物和其他杂质。 该离子液体步骤可以之后是第二脱氧步骤,或者可以完成脱氧,然后进行离子液体纯化步骤。

    PROCESS FOR REMOVING SULFUR COMPOUNDS FROM VACUUM GAS OIL
    9.
    发明申请
    PROCESS FOR REMOVING SULFUR COMPOUNDS FROM VACUUM GAS OIL 审中-公开
    从真空气体中除去硫化氢的方法

    公开(公告)号:US20140001099A1

    公开(公告)日:2014-01-02

    申请号:US13899670

    申请日:2013-05-22

    Applicant: UOP LLC

    Abstract: A process for removing a sulfur compound from a low nitrogen content vacuum gas oil feed includes contacting the low nitrogen content vacuum gas oil feed comprising the sulfur compound with a VGO-immiscible phosphonium ionic liquid to produce a vacuum gas oil and VGO-immiscible phosphonium ionic liquid mixture, and separating the mixture to produce a vacuum gas oil effluent having a reduced sulfur compound content relative to the vacuum gas oil feed. It was found that the amount of the sulfur compound being removed was significantly improved by treating a low nitrogen content vacuum gas oil. The low nitrogen content and especially a low level of polar nitrogen compounds increases the amount of sulfur compounds that can be removed.

    Abstract translation: 从低氮含量真空瓦斯油原料中除去硫化合物的方法包括将包含硫化合物的低氮含量真空瓦斯油原料与VGO不混溶的鏻离子液体接触以产生真空瓦斯油和VGO不混溶的鏻离子 液体混合物,并分离混合物以产生相对于真空瓦斯油进料具有降低的硫化合物含量的减压瓦斯油流出物。 发现通过处理低氮含量的真空瓦斯油,可以显着地提高除去的硫化合物的量。 低氮含量,特别是低水平的极性氮化合物增加可以除去的硫化合物的量。

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