Copolyimide membranes with high permeability and selectivity for olefin/paraffin separations
    1.
    发明授权
    Copolyimide membranes with high permeability and selectivity for olefin/paraffin separations 有权
    对于烯烃/石蜡分离具有高渗透性和选择性的共聚酰亚胺膜

    公开(公告)号:US09327248B1

    公开(公告)日:2016-05-03

    申请号:US14560207

    申请日:2014-12-04

    Applicant: UOP LLC

    CPC classification number: B01D71/64 B01D53/228 B01D71/76 B01D2053/224

    Abstract: A copolyimide polymer membrane is provided for separation of hydrocarbons including separation of olefins from paraffins and isoparaffins from other paraffins. The copolyimide polymer membranes include a poly(3,3′-diaminobenzophenone-3,3′,5,5′-tetramethyl-4,4′-methylene dianiline-pyromellitic dianhydride) (abbreviated as poly(DAB-TMMDA-PMDA)). The copolyimide membranes prepared from poly(DAB-TMMDA-PMDA) with varying molar ratios of DAB to TMMDA (abbreviated as PI-DAB-T) showed excellent separation properties for propylene/propane separation.

    Abstract translation: 提供了用于分离烃的共聚酰亚胺聚合物膜,包括从链烷烃中分离烯烃和来自其它石蜡的异构烷烃。 共聚酰亚胺聚合物膜包括聚(3,3'-二氨基二苯甲酮-3,3',5,5'-四甲基-4,4'-亚甲基二苯胺 - 均苯四酸二酐)(缩写为聚(DAB-TMMDA-PMDA)) 。 由具有不同摩尔比的DAB与TMMDA(缩写为PI-DAB-T)的聚(DAB-TMMDA-PMDA)制备的共聚酰亚胺膜显示出优异的丙烯/丙烷分离分离性能。

    Gas separation membranes from chemically and UV treated polymers of intrinsic microporosity
    2.
    发明授权
    Gas separation membranes from chemically and UV treated polymers of intrinsic microporosity 有权
    化学和UV处理聚合物的气体分离膜具有固有的微孔性

    公开(公告)号:US09238202B2

    公开(公告)日:2016-01-19

    申请号:US14104492

    申请日:2013-12-12

    Applicant: UOP LLC

    Abstract: The invention is a process of making a chemically and UV treated polymer of intrinsic microporosity membrane comprising preparing a polymer of intrinsic microporosity, chemically cross-linking said polymer of intrinsic microporosity with a cross-linking compound to produce a chemically cross-linked polymer of intrinsic microporosity and then treating said chemically cross-linked polymer with UV radiation for a period of time sufficient to provide a product membrane. This product membrane is useful in the separation of C3 and higher hydrocarbons, as well as CO2, from natural gas and other gas streams.

    Abstract translation: 本发明是制备本征微孔膜的化学和UV处理的聚合物的方法,包括制备本征微孔的聚合物,与所述交联化合物化学交联所述本征微孔的聚合物以产生本征的化学交联聚合物 微孔,然后用UV辐射处理所述化学交联的聚合物足以提供产物膜的时间。 该产品膜可用于从天然气和其他气体流中分离C3和更高级烃以及二氧化碳。

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