Abstract:
A copolyimide polymer membrane is provided for separation of hydrocarbons including separation of olefins from paraffins and isoparaffins from other paraffins. The copolyimide polymer membranes include a poly(3,3′-diaminobenzophenone-3,3′,5,5′-tetramethyl-4,4′-methylene dianiline-pyromellitic dianhydride) (abbreviated as poly(DAB-TMMDA-PMDA)). The copolyimide membranes prepared from poly(DAB-TMMDA-PMDA) with varying molar ratios of DAB to TMMDA (abbreviated as PI-DAB-T) showed excellent separation properties for propylene/propane separation.
Abstract:
The invention is a process of making a chemically and UV treated polymer of intrinsic microporosity membrane comprising preparing a polymer of intrinsic microporosity, chemically cross-linking said polymer of intrinsic microporosity with a cross-linking compound to produce a chemically cross-linked polymer of intrinsic microporosity and then treating said chemically cross-linked polymer with UV radiation for a period of time sufficient to provide a product membrane. This product membrane is useful in the separation of C3 and higher hydrocarbons, as well as CO2, from natural gas and other gas streams.
Abstract:
A process is provided for separation of light olefins and paraffins and particular for the separation of propylene and propane comprising sending at least one olefin/paraffin stream to a distillation column and a membrane unit to produce an olefin stream comprising at least 92 mol % olefin. In an embodiment of the invention where the membrane unit is placed downstream from the column which can produce propylene streams at polymer grade of over 99.5 mol % propylene.
Abstract:
Polyimide membranes are provided that provide extremely high permeability. The polyimides do not contain carbonyl or sulfonyl functional groups. These membranes are useful in separating gases including the separation of gas pairs including carbon dioxide/methane, hydrogen/methane and propylene/propane as well as other gas mixtures. The membrane selectivity can be adjusted by exposure to ultraviolet light.
Abstract:
Polyimide membranes are provided that provide extremely high permeability. The polyimides do not contain carbonyl or sulfonyl functional groups. These membranes are useful in separating gases including the separation of gas pairs including carbon dioxide/methane, hydrogen/methane and propylene/propane as well as other gas mixtures. The membrane selectivity can be adjusted by exposure to ultraviolet light.
Abstract:
This invention provides a new facilitated transport membrane comprising a relatively hydrophilic, very small pore, nanoporous support membrane, a hydrophilic polymer inside the very small nanopores on the skin layer surface of the support membrane, a thin, nonporous, hydrophilic polymer layer coated on the surface of the support membrane, and metal salts incorporated in the hydrophilic polymer layer coated on the surface of the support membrane and the hydrophilic polymer inside the very small nanopores, a method of making this membrane, and the use of this membrane for olefin/paraffin separations, particularly for C3=/C3 and C2=/C2 separations.
Abstract:
A process is provided for separation of light olefins and paraffins and particular for the separation of propylene and propane comprising sending at least one olefin/paraffin stream to a distillation column and a membrane unit to produce an olefin stream comprising at least 92 mol % olefin. In an embodiment of the invention where the membrane unit is placed downstream from the column which can produce propylene streams at polymer grade of over 99.5 mol % propylene.
Abstract:
This invention provides a new facilitated transport membrane comprising a relatively hydrophilic, very small pore, nanoporous support membrane, a hydrophilic polymer inside the very small nanopores on the skin layer surface of the support membrane, a thin, nonporous, hydrophilic polymer layer coated on the surface of the support membrane, and metal salts incorporated in the hydrophilic polymer layer coated on the surface of the support membrane and the hydrophilic polymer inside the very small nanopores, a method of making this membrane, and the use of this membrane for olefin/paraffin separations, particularly for C3=/C3 and C2=/C2 separations.
Abstract:
A process is provided of making facilitated transport membrane comprising a relatively hydrophilic, very small pore, nanoporous support membrane, a hydrophilic polymer inside the very small nanopores on the skin layer surface of the support membrane, a thin, nonporous, hydrophilic polymer layer coated on the surface of the support membrane, and metal salts incorporated in the hydrophilic polymer layer coated on the surface of the support membrane and the hydrophilic polymer inside the very small nanopores. In addition, the process provides a new method of making facilitated transport membrane spiral wound elements or hollow fiber modules for olefin/paraffin separations, particularly for C3=/C3 and C2=/C2 separations.
Abstract:
A co-cast thin film composite flat sheet membrane is provided that comprises an asymmetric porous non-selective support layer with a thickness of 10-50 micrometers and an asymmetric integrally skinned polyimide-containing selective layer with a thickness of 5-40 micrometers on top of said support layer, wherein said asymmetric integrally skinned polyimide-containing selective layer comprises a porous non-selective polyimide-containing support layer with a thickness of ˜5-40 micrometers and a relatively porous, thin, dense, polyimide-containing top skin layer with a thickness of 0.02-0.2 micrometers.