Electrolytic process for dissolving platinum, platinum metal impurities
and/or platinum metal alloys
    2.
    发明授权
    Electrolytic process for dissolving platinum, platinum metal impurities and/or platinum metal alloys 失效
    用于溶解铂,铂金属杂质和/或铂金属合金的电解方法

    公开(公告)号:US5423957A

    公开(公告)日:1995-06-13

    申请号:US170423

    申请日:1993-12-20

    CPC分类号: C22B11/04 C25B1/00

    摘要: The electrolytic process for dissolving platinum, platinum metal impurities and/or platinum metal alloys, in particular with contents of Rh, Pd, Ir, Au and Ag, in 6 to 8N aqueous hydrochloric acid is characterized by a dissolution process that takes place in an electrolysis cell subdivided by a cation exchanger membrane into an anode and cathode compartment containing anode and cathode respectively, and, if appropriate, in the presence of platinum metal salts or platinum metal acids, at temperatures between 50.degree. and 110.degree. C., under potentiostatic or voltage-controlled conditions in the range of 2.5 V to 8 V and under a current density of 0.3 to 7.0 A/dm.sup.2. The potential across the anode and the cathode is controlled so that chlorine gas is generated and the anode is contacted with the aqueous hydrochloric acid solution and the chlorine gas in impulse-form.

    摘要翻译: 在6〜8N盐酸水溶液中,特别是用Rh,Pd,Ir,Au和Ag的含量溶解铂,铂金属杂质和/或铂金属合金的电解方法的特征在于溶解过程发生在 分别由阳离子交换膜细分成阳极和阴极室的电解槽分别含有阳极和阴极,如果合适的话,在铂金属盐或铂金属酸存在下,在50〜110℃的温度下,在恒电位 或电压控制条件在2.5V至8V的范围内,并且在0.3至7.0A / dm 2的电流密度下。 控制阳极和阴极两端的电位,使得产生氯气,阳极与脉冲形式的盐酸水溶液和氯气接触。

    Electrolytic process for the production of fine-grained, single-phase
metallic alloy powders
    3.
    发明授权
    Electrolytic process for the production of fine-grained, single-phase metallic alloy powders 失效
    用于生产细晶,单相金属合金粉末的电解工艺

    公开(公告)号:US5370784A

    公开(公告)日:1994-12-06

    申请号:US81057

    申请日:1993-06-25

    CPC分类号: C25C5/02 C22C1/04

    摘要: A process for electrolytic production of fine-grained, single-phase, metallic alloy powders, especially powders of intermetallic compounds as well as noble metal alloy powders, is described in which powdery metallic precipitates are galvanically produced on the cathode from an electrolytic precipitating bath known in the art, which contains in solution the metals to be precipitated, under electrolysis conditions causing a powder precipitation known in the art. For the production of alloy powders with defined properties, it is determined, first in preliminary tests by gradual increase of the cathode potential with otherwise constant process parameters, the minimum cathode potential at which single-phase alloy powders result and then the powder precipitation is potentiostatically performed in a cathode potential at or above the minimum for the single-phase alloy precipitation.

    摘要翻译: 描述了一种用于电解生产细晶粒,单相金属合金粉末,特别是金属间化合物粉末以及贵金属合金粉末的方法,其中粉末状金属沉淀物在已知的电解沉淀浴的阴极上电镀生产 在本领域中,其在电解条件下在溶液中含有待沉淀的金属,引起本领域已知的粉末沉淀。 对于具有规定性能的合金粉末的生产,首先在初步试验中,通过以其他不同的工艺参数逐渐增加阴极电势,确定单相合金粉末的最小阴极电位,然后粉末沉淀为电位 在单相合金沉淀的最小值处于或高于阴极电位。

    BIOACTIVE, RUTHENIUM-CONTAINING COATING AND DEVICE
    4.
    发明申请
    BIOACTIVE, RUTHENIUM-CONTAINING COATING AND DEVICE 有权
    含生物,含钌涂料和设备

    公开(公告)号:US20100143431A1

    公开(公告)日:2010-06-10

    申请号:US12445254

    申请日:2007-10-02

    摘要: The invention relates to the production and use of novel bioactive devices and metallic coatings for example for sterilizing, disinfecting, and decontaminating water or aqueous solutions. The known oligodynamic effect of silver for reducing the amount of germs is thereby improved and increased by combining silver with ruthenium and a vitamin or derivative thereof. The novel properties of these bioactive metal surfaces lead to faster and more efficient killing of microorganisms. Simultaneously, these novel bioactive metal surfaces prevent infestation by microorganisms and attachment or permanent deposition of problematic biomolecules such as for example DNA, RNA, or proteins. A self-cleaning surface is thus obtained, which very quickly and efficiently and over extended periods of time sterilizes water and aqueous solutions when they come in contact with said surface.

    摘要翻译: 本发明涉及新型生物活性装置和金属涂层的生产和使用,例如用于消毒,消毒和净化水或水溶液。 因此,通过将银与钌及其维生素或其衍生物结合来改善和增加银的用于减少细菌量的已知的小动力学效应。 这些生物活性金属表面的新特性导致更快更有效地杀死微生物。 同时,这些新的生物活性金属表面防止微生物的侵袭和附着或永久沉积有问题的生物分子,例如DNA,RNA或蛋白质。 因此,获得了自清洁表面,当它们与所述表面接触时,其非常快速且有效地并且延长的时间段使水和水溶液消毒。

    Electrolytic process for obtaining high purity platinum from
contaminated platinum
    5.
    发明授权
    Electrolytic process for obtaining high purity platinum from contaminated platinum 失效
    从受污染的铂获得高纯度铂的电解过程

    公开(公告)号:US5393389A

    公开(公告)日:1995-02-28

    申请号:US170422

    申请日:1993-12-20

    CPC分类号: C25C1/20

    摘要: The electrolytic process for obtaining platinum of high purity from a concentrated hydrochloric acid solution of contaminated platinum containing base and noble metal impurities includes electrolyzing the hydrochloric acid solution containing the contaminated platinum in an electrolysis cell subdivided by a cation exchanger membrane under potentiostatic or voltage-controlled conditions with a voltage of 2.5 V to 8 V applied across the anode and cathode under a current density of 0.3 to 12.5 A/dm.sup.2 so as to form a refined platinum-containing solution and a platinum alloy metal deposit. The concentrated hydrochloric acid solutions used in the process can have a contaminated platinum content of 50 to 700 g/l and total metal impurities of .ltoreq.5000 ppm. In contrast to the known prior art processes, the process according to the invention operates with minimal requirements in terms of safety technology and equipment, causes a minimal environmental burden and is far less time-consuming and more economical.

    摘要翻译: 从被污染的含铂基质和贵金属杂质的浓盐酸溶液中获得高纯度的铂的电解方法包括在恒电位或电压控制下在阳离子交换膜细分的电解槽中电解含有污染的铂的盐酸溶液 在0.3至12.5A / dm 2的电流密度下在阳极和阴极上施加2.5V至8V的电压的条件,以形成精炼的含铂溶液和铂合金金属沉积物。 在该方法中使用的浓盐酸溶液可以具有污染的铂含量为50至700g / l,总金属杂质为

    Electrolytic process for extracting high purity platinum from platinum
alloys
    7.
    发明授权
    Electrolytic process for extracting high purity platinum from platinum alloys 失效
    从铂合金中提取高纯度铂的电解工艺

    公开(公告)号:US5393388A

    公开(公告)日:1995-02-28

    申请号:US170421

    申请日:1993-12-20

    CPC分类号: C25C1/20

    摘要: The electrolytic process for obtaining platinum of high purity from concentrated hydrochloric acid solutions of a platinum alloy containing Rh, Ir and/or Pd proceeds with simultaneous depletion of noble and base metal impurities from the solution. This electrolysis process takes place in an electrolysis cell having an anode and cathode and subdivided by a teflon cation exchanger membrane under potentiostatic or, voltage-controlled conditions with a potential applied across the anode and cathode of 8 V to 16 V, preferably 11.5 to 12 V, at a current density of 12.5 to 37.5 A/dm.sup.2, preferably 22.5 to 35 A/dm.sup.2, to form a purified platinum-containing solution from which the high purity platinum can be obtained and also platinum alloy metal component deposits on the anode and cathode. The concentrated hydrochloric acid solution of the platinum alloy can have a platinum alloy content of 50 to 700 g/l and total metal impurities of not greater than 5000 ppm.

    摘要翻译: 从含有Rh,Ir和/或Pd的铂合金的浓盐酸溶液中获得高纯度铂的电解方法进行同时从溶液中消耗贵金属和碱金属杂质。 这种电解过程在具有阳极和阴极的电解池中进行,并且在恒电位或电压控制条件下用聚四氟乙烯阳离子交换膜细分,其中施加在阳极和阴极上的电压为8V至16V,优选为11.5至12 V,电流密度为12.5〜37.5A / dm 2,优选为22.5〜35A / dm 2,形成纯化的含铂溶液,由此可获得高纯度的铂,并且铂合金金属成分沉积在阳极上, 阴极。 铂合金的浓盐酸溶液可以具有50至700g / l的铂合金含量和不大于5000ppm的总金属杂质。