Method of mking nitriles from carboxylic acids
    5.
    发明授权
    Method of mking nitriles from carboxylic acids 失效
    从羧酸中分离硝基的方法

    公开(公告)号:US3607906A

    公开(公告)日:1971-09-21

    申请号:US3607906D

    申请日:1968-11-20

    CPC classification number: C07C253/22 C07C255/04

    Abstract: Nitriles and dinitriles of monocarboxylic and dicarboxylic acids are produced by evaporating the acid in a film-forming evaporating apparatus, which is preferably made of titanium or stainless steel, in the presence of 0.26 to 40 moles of superheated steam per mole of carboxylic acid, the evaporated acid and steam being then mixed with 4 to 60 moles of gaseous ammonia per mole of carboxylic acid and reacted in the gaseous phase at a temperature between 260* to 500* C. in the presence of a dehydrating catalyst.

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