摘要:
The invention features organic photoreceptors that include a charge transport compound having the formula: where X is an N-alkyl-substituted carbazole, an N-aryl-substituted carbazole, or a p-(N,N-disubstituted)arylamine; Ar is a group having the formula: R1 is a hydrogen, halogen, or alkyl group; R is a hydrogen, halogen, OH, CN, OR2, or OCOR3 group; R2 is an alkyl, aryl, or alkaryl group; R3 is a hydrogen, alkyl, aryl, or haloalkyl group; n is 0 or 1; A is a group having the formula: Z is O or S; Q is O, S, or CH2; and m is 0 or 1.
摘要:
An improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material comprising a polymer having the formula where X1 and X2 are, each independently, a bond or a linking group; Y comprises a bond or an arylamine group; Z comprises a bond, O, S, or NR4; R1 and R4 comprise, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, or a heterocyclic group; R2 and R3 comprise, each independently, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, or a heterocyclic group; and n is a distribution of integers between 1 and 100,000 with an average value of greater than one; and (b) a charge generating compound. Corresponding electrophotographic apparatuses, imaging methods, and methods of forming the charge transport material are described.
摘要翻译:改进的有机光感受器包括在导电基底上的导电基底和光电导元件,光导元件包括:(a)电荷输送材料,其包含具有下式的聚合物:其中X 1和X 2 > 2 SUB>各自独立地为键或连接基团; Y包含键或芳基胺基; Z包括键,O,S或NR 4; R 1和R 4各自独立地包含H,烷基,烯基,炔基,芳族基团或杂环基团; R 2和R 3各自独立地包括烷基,烯基,炔基,芳族基团或杂环基团; 并且n是整数在1和100,000之间的平均值大于1的分布; 和(b)电荷产生化合物。 描述了相应的电子照相设备,成像方法和形成电荷传输材料的方法。
摘要:
Charge transport compounds are described that have a multiple number of hydrazone-bridged heterocyclic groups (especially julolidine groups, carbazole groups, triarylamine groups and (N,N-disubstituted)arylamine groups such as dialkarylamine groups (e.g. dimethylphenylamine; methylethylphenylamine, dipropylphenylamine, ethylepropylphenylamine, ethylbutylnaphthylamine, etc.), alkyldiarylamine groups (e.g. methyldiphenylamino, ethyldiphenylamino, etc), and triarylamino groups (e.g., triphenyl amino, trinaphthylamino, etc)) connected by a central bridging group. An example of charge transport compounds are those having the following generic formula: (R—Q)n−Y Formula I wherein R is selected from the group consisting of julolidine ring groups, carbazole ring groups, and and (N,N-disubstituted)arylamine groups; Q comprises an aromatic hydrazone linking group, such as Y comprises a bridging group between R—Q— groups, such as a bond, carbon atom, nitrogen atom, oxygen atom, sulfur atom, a methylene group; Z is an aryl group, preferably a phenyl group or naphthyl group; X is a linking group, preferably a methylene group, and for example having the formula —(CH2)m— (branched or linear), where m is an integer between 0 and 20, inclusive, and one or more of the methylene groups is optionally replaced by an oxygen atom, a carbonyl group, urethane, urea, an ester group, a —NR6 group, a CHR7 group, or a CR8R9 group where R6, R7, R8, and R9 are, independently, H, an alkyl group, or aryl group; and n is an integer between 2 and 6, inclusive. An organic photoreceptor includes that compound and (b) a charge generating compound; and (c) an electrically conductive substrate.
摘要:
Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where R1 and R2 are, independently, H, an alkyl group, an alkaryl group, or an aryl group; X is a linking group having the formula —(CH2)m—, branched or linear, where m is an integer between 1 and 20, inclusive, and one or more of the methylene groups is optionally replaced by O, S, C═O, O═S═O, a heterocyclic group, an aromatic group, urethane, urea, an ester group, a NR3 group, a CHR4 group, or a CR5R6 group where R3, R4, R5, and R6 are, independently, H, hydroxyl group, thiol group, an alkyl group, an alkyl group, a heterocyclic group, or an aryl group; V comprises a vinyl ether group; and Z comprises an (N,N-disubstituted)arylamine group, such as a carbazole group, a julolidine group, or a p-(N,N-disubstituted)arylamine group; and (b) a charge generating compound.
摘要:
Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where R1 and R2 are, independently, H, an alkyl group, an alkaryl group, or an aryl group; X is a linking group having the formula —(CH2)m—, branched or linear, where m is an integer between 1 and 20, inclusive, and one or more of the methylene groups is optionally replaced by O, S, C═O, O═S═O, a heterocyclic group, an aromatic group, urethane, urea, an ester group, a NR3 group, a CHR4 group, or a CR5R6 group where R3, R4, R5, and R6 are, independently, H, hydroxyl group, thiol group, an alkyl group, an alkyl group, a heterocyclic group, or an aryl group; V comprises a vinyl ether group; and Z comprises an (N,N-disubstituted)arylamine group, such as a carbazole group, a julolidine group, or a p-(N,N-disubstituted)arylamine group; and (b) a charge generating compound.
摘要:
Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where R1, R2, R3, and R4 are, independently, an alkyl group, an alkaryl group, or an acyl group; Y is an alkyl group, alkaryl group, or aryl group; X is a linking group having the formula —(CH2)m—, branched or linear, where in is an integer between 1 and 20, inclusive, and one or more of the methylene groups is optionally replaced by O, S, C═O, O═S═O, a heterocyclic group, an aromatic group, urethane, urea, an ester group, a NR3 group, a CHR4 group, or a CR5R6 group where R3, R4, R,5 and R6 are, independently, H, hydroxyl group, thiol group, an alkyl group, an alkaryl group, a heterocyclic group, or an aryl group; and E is an epoxy group; and (b) a charge generating compound.
摘要:
Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where R1, R2, R3, and R4 are, independently, an alkyl group, an alkaryl group, or an acyl group; Y is an alkyl group, alkaryl group, or aryl group; X is a linking group having the formula —(CH2)m—, branched or linear, where in is an integer between 1 and 20, inclusive, and one or more of the methylene groups is optionally replaced by O, S, C═O, O═S═O, a heterocyclic group, an aromatic group, urethane, urea, an ester group, a NR3 group, a CHR4 group, or a CR5R6 group where R3, R4, R,5 and R6 are, independently, H, hydroxyl group, thiol group, an alkyl group, an alkaryl group, a heterocyclic group, or an aryl group; and E is an epoxy group; and (b) a charge generating compound.
摘要:
Improved organophotoreceptor comprises a photoconductive element comprising: (a) a charge transport material having the formula where Y1 and Y2 are, each independently, a bond, —CR1═N—NR2—, or —CR3═N—N═CR4— where R1, R2, R3, and R4 comprise, each independently, H, an alkyl group, an alkenyl group, a heterocyclic group, or an aromatic group; X1 and X2 are, each independently, a linking group; T1 and T2 are, each independently, a thiiranyl group, H, an alkyl group, an alkenyl group, or an aromatic group with the proviso that at least one of T1 and T2 is a thiiranyl group; and Ar comprises an aromatic group with the proviso that when both Y1 and Y2 are a bond and one of T1 and T2 is not a thiiranyl group, Ar comprises a bis[(N,N-disubstituted)amino]aromatic group or a bicarbazole group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.
摘要翻译:改进的有机光感受器包括光电导元件,其包含:(a)具有下式的电荷传输材料,其中Y 1和Y 2 2各自独立地为键,-CR 1 -N-NR 2 - 或-CR 3 -NN-CR 4 - 其中R 1 R 2,R 3和R 4各自独立地包括H,烷基,烯基, 杂环基或芳基; X 1和X 2各自独立地为连接基团; T 1和T 2各自独立地为硫杂芳基,H,烷基,烯基或芳族基团,条件是至少一个 T 1和T 2是硫杂芳基; 并且Ar包含芳族基团,条件是当Y 1和Y 2都是键并且T 1和T 2中的一个 > 2不是噻吩基,Ar包含双[(N,N-二取代)氨基]芳基或二咔唑基; 和(b)电荷产生化合物。 描述相应的电子照相设备和成像方法。
摘要:
Improved organophotoreceptor comprises a photoconductive element comprising: (a) a charge transport material having the formula where Y1 and Y2 are, each independently, a bond, —CR1═N—NR2—, or —CR3═N—N═CR4— where R1, R2, R3, and R4 comprise, each independently, H, an alkyl group, an alkenyl group, a heterocyclic group, or an aromatic group; X1 and X2 are, each independently, a linking group; T1 and T2 are, each independently, a thiiranyl group, H, an alkyl group, an alkenyl group, or an aromatic group with the proviso that at least one of T1 and T2 is a thiiranyl group; and Ar comprises an aromatic group with the proviso that when both Y1 and Y2 are a bond and one of T1 and T2 is not a thiiranyl group, Ar comprises a bis[(N,N-disubstituted)amino]aromatic group or a bicarbazole group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.
摘要翻译:改进的有机光感受器包括光电导元件,其包含:(a)具有下式的电荷传输材料,其中Y 1和Y 2 2各自独立地为键,-CR 1 -N-NR 2 - 或-CR 3 -NN-CR 4 - 其中R 1 R 2,R 3和R 4各自独立地包括H,烷基,烯基, 杂环基或芳基; X 1和X 2各自独立地为连接基团; T 1和T 2各自独立地为硫杂芳基,H,烷基,烯基或芳族基团,条件是至少一个 T 1和T 2是硫杂芳基; 并且Ar包含芳族基团,条件是当Y 1和Y 2都是键并且T 1和T 2中的一个 > 2不是噻吩基,Ar包含双[(N,N-二取代)氨基]芳基或二咔唑基; 和(b)电荷产生化合物。 描述相应的电子照相设备和成像方法。
摘要:
Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Z1 and Z2 comprise, each independently, a bond, a vinyl group, a —CR1═N—NR2— group, or a —CR3═N—N═CR4— group; Y1 and Y2 comprise, each independently, an aromatic group; X1 and X2 are, each independently, a linking group; W1 and W2 are, each independently, a —(CH2)n— group or a —(CH2)n-1—C(═O)— group, where n is an integer between 1 and 10, inclusive; Q1 and Q2 are, each independently, O, S, or NR; and R1, R2, R3, R4, R, R′, and R″ comprise, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an acyl group, a heterocyclic group, or an aromatic group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.