Organophotoreceptor with charge transport material with a hydrazone group linked to a heterocyclic group

    公开(公告)号:US07169520B2

    公开(公告)日:2007-01-30

    申请号:US10699364

    申请日:2003-10-31

    IPC分类号: G03G15/06

    CPC分类号: C07D279/22

    摘要: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where n is an integer between 2 and 6, inclusive; R1 and R2 are, independently, H, an alkyl group, an alkaryl group, or an aryl group; X is a linking group having the formula —(CH2)m—, branched or linear, where m is an integer between 0 and 20, inclusive, and one or more of the methylene groups is optionally replaced by O, S, C═O, O═S═O, a heterocyclic group, an aromatic group, urethane, urea, an ester group, a NR3 group, a CHR4 group, or a CR5R6 group where R3, R4, R5, and R6 are, independently, H, hydroxyl group, thiol group, an alkyl group, an alkaryl group, a heterocyclic group, or an aryl group; Y comprises a bond, C, N, O, S, a branched or linear —(CH2)p— group where p is an integer between 0 and 10, an aromatic group, a cycloalkyl group, a heterocyclic group, or a NR7 group where R7 is hydrogen atom, an alkyl group, or aryl group, wherein Y has a multivalent structure selected to form n bonds with the corresponding X groups; and Z comprises a heterocyclic group selected from the group consisting of phenothiazine group, phenoxazine group, phenoxathiin group, dibenzo(1,4)dioxin group, thianthrene group, and phenazine group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.

    Linked dihydrazone-based charge transport compounds
    7.
    发明授权
    Linked dihydrazone-based charge transport compounds 失效
    连接的腙基电荷输送化合物

    公开(公告)号:US06899984B2

    公开(公告)日:2005-05-31

    申请号:US10431135

    申请日:2003-05-07

    摘要: This invention relates to a novel organophotoreceptor that includes: (a) a charge transport compound having the formula where n is an integer from 0 to 1 inclusive; X is an (N,N-disubstituted)arylamine, such as a carbazole group, a julolidine group, or a p-(N,N-disubstituted)arylamine group (which can be a triarylamine, an alkyldiarylamine or a dialkylarylamine); Ar is an aryl group or a heterocyclic group; A is a linking group having the formula —S—(CH2)m—S— where m is an integer from 1 to 15 inclusive and; B is a second linking group with the formula —(CH2)p— which can be branched or linear, where p is an integer from 3 and 20 inclusive and where one or more methylene groups can be optionally replaced by O, S, a carbonyl group, urethane, urea, an ester group, a —NR21 group, a CHR22 group, or a CR23R24 group where R21, R22, R23 and R24 are, independently, H, hydroxyl, thiol, an amine group, an alkyl group, an alkaryl group, an aryl group, or part of a ring; (b) a charge generating compound; and (c) an electrically conductive substrate over which the charge transport compound and the charge generating compound are located.

    摘要翻译: 本发明涉及一种新型有机光感受器,其包括:(a)具有下式的电荷传输化合物,其中n为0至1的整数,包括0和1; X是(N,N-二取代)芳基胺,例如咔唑基,久洛尼碱基或对 - (N,N-二取代)芳基胺基(其可以是三芳基胺,烷基二芳基胺或二烷基芳基胺); Ar是芳基或杂环基; A是具有式-S-(CH 2 CH 2)m -S-的连接基团,其中m是1至15的整数,包括1和15; B是具有式 - (CH 2)2 - 的第二连接基团,其可以是支链或直链的,其中p是3和20的整数,其中一个 或更多个亚甲基可以任选地被O,S,羰基,氨基甲酸酯,脲,酯基,-NR 21基团,CHR 22基团, 或其中R 21,R 22,R 23,R 23,R 23,R 23, >和R 24独立地是H,羟基,硫醇,胺基,烷基,烷芳基,芳基或环的一部分; (b)电荷产生化合物; 和(c)电荷输送化合物和电荷产生化合物所位于的导电基底。