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    Polymerization catalyst
    2.
    发明授权
    Polymerization catalyst 失效
    聚合催化剂

    公开(公告)号：US06828398B2

    公开(公告)日：2004-12-07

    申请号：US10181802

    申请日：2002-11-15

    申请人： Vernon Charles Gibson ,  Olivier Hoarau ,  Brian Stephen Kimberley ,  Peter James Maddox

    发明人： Vernon Charles Gibson ,  Olivier Hoarau ,  Brian Stephen Kimberley ,  Peter James Maddox

    IPC分类号： C08F444

    CPC分类号： C07F15/045 ,  C07F7/003 ,  C07F9/005 ,  C07F13/005 ,  C07F15/004 ,  C07F15/0053 ,  C07F15/008 ,  C07F15/025 ,  C08F10/00 ,  C08F110/02 ,  C08F2410/04 ,  C08F4/7042

    摘要： A complex suitable for use as a catalyst in the polymerisation of olefins is disclosed, having the Formula (I) wherein M is a transition metal; X represents an atom or group covalently or ionically bonded to M; T is the oxidation state of M; b is the valency of the atom or group X; A1 to A3 are each independently N or P or CR, with the proviso that at least one but no more than two of them are independently CR; Y1 and Y2 are each independently CR′ or PR′R″; Z is oxygen or NR5, R5 and R7 and each R, each R′ and each R″ are independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl, substituted heterohydrocarbyl or SiR303 where each R30 is independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl; but excluding those complexes having the formulae (1) and (2) where in both cases R4 and R6 are Me, R5 and R7 are 2, 4, 6-trimethylphenyl, M is Fe, T is II, X is Cl and b is 1

    摘要翻译： 公开了一种适合用作烯烃聚合中催化剂的络合物，其具有式（I），其中M是过渡金属; X表示与M共价或离子键合的原子或基团; T是M的氧化态; b是原子或基团X的化合价; A 1至A 3各自独立地为N或P或CR，条件是其中至少一个但不多于两个独立地为CR; Y 1和Y 2各自独立地为CR'或PR'R“; Z是氧或NR 5，R 5和R 7，每个R，每个R'和每个R“独立地选自氢，卤素，烃基，取代的烃基，杂烃基，取代的杂烃基或SiR 30> 3，其中每个R 30独立地选自氢，卤素，烃基，取代的烃基，杂烃基和取代的杂烃基; 但不包括具有式（1）和（2）的那些络合物，其中在两种情况下，R 4和R 6均为Me，R 5和R 7为2,4,6-三甲基苯基，M为 Fe，T为II，X为Cl且b为1

    Supported polymerisation catalysts
    3.
    发明授权
    Supported polymerisation catalysts 失效
    负载型聚合催化剂

    公开(公告)号：US07528090B2

    公开(公告)日：2009-05-05

    申请号：US10568822

    申请日：2004-08-04

    申请人： Grant Berent Jacobsen ,  Brian Stephen Kimberley ,  Sergio Mastroianni

    发明人： Grant Berent Jacobsen ,  Brian Stephen Kimberley ,  Sergio Mastroianni

    IPC分类号： C08F4/02 ,  C08F4/6592 ,  B01J31/22

    CPC分类号： C08F210/16 ,  C08F4/65908 ,  C08F4/65916 ,  C08F4/6592 ,  C08F2420/02 ,  C08F4/65912 ,  C08F210/14

    摘要： A supported polymerisation catalyst system comprises a porous support, a polymerisation catalyst and a cocatalyst wherein the support has been treated with an inert material such as polyisobutene. The support is preferably silica and is preferably treated with the inert material prior to contact with the other components. Preferably the polymerisation catalyst is a metallocene and the polymerisation catalyst system reduces the initial peak isotherm allowing for a smoother activity increase in particular for polymerisations carried out in the gas phase.

    摘要翻译： 负载型聚合催化剂体系包括多孔载体，聚合催化剂和助催化剂，其中载体已用惰性材料如聚异丁烯处理。 载体优选为二氧化硅，并且优选在与其它组分接触之前用惰性材料处理。 优选地，聚合催化剂是茂金属，并且聚合催化剂体系降低了初始峰值等温线，从而允许更平滑的活性增加，特别是对于在气相中进行的聚合反应。

    Catalysts for olefin polymerization
    5.
    发明授权
    Catalysts for olefin polymerization 失效
    用于烯烃聚合的催化剂

    公开(公告)号：US06333292B1

    公开(公告)日：2001-12-25

    申请号：US09301074

    申请日：1999-04-28

    申请人： Vernon Charles Gibson ,  Brian Stephen Kimberley

    发明人： Vernon Charles Gibson ,  Brian Stephen Kimberley

    IPC分类号： B01J3118

    CPC分类号： C08F10/00 ,  C07F7/003 ,  C08F2410/03 ,  C08F4/64075 ,  C08F4/64013

    摘要： Novel compounds are disclosed comprising the skeletal unit depicted in Formula (I) wherein O is oxygen; N is nitrogen; R1 is hydrogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl; R3, R4, R5 and R6 are hydrogen or hydrocarbyl or heterohydrocarbyl groups containing 1 to 10 carbon atoms and the R12 groups are independently selected from hydrogen, hydrocarbyl, substituted hydrocarbyl, heterocarbyl and substituted heterocarbyl; A is carbon or silicon; and r is 1 or more; M is scandium, yttrium, or a Group IV or Group V metal or a lanthanide or actinide; T is the oxidation state of M and is II or greater; X represents a monodentate atom or group covalently or ionically bonded to M; L is a mono- or bidentate molecule datively bound to M, and n is from 0 to 5.

    摘要翻译： 公开了包含式（I）中所示的骨架单元的新型化合物，其中O是氧; N是氮; R 1是氢，烃基，取代的烃基，杂烃基或取代的杂烃基; R 3，R 4，R 5和R 6是氢或含有1至10个碳原子的烃基或杂烃基，R 12基团独立地选自氢，烃基，取代的烃基，杂碳原子和取代的杂碳原子; A是碳或硅; r为1以上; M是钪，钇或IV族或Ⅴ族金属或镧系元素或锕系元素; T为M的氧化态，为II以上; X表示与M共价或离子键合的单齿原子或基团; L是与M直接结合的单齿或双齿分子，n为0至5。

    Polymerization catalysts
    8.
    发明授权
    Polymerization catalysts 失效
    聚合催化剂

    公开(公告)号：US06683141B1

    公开(公告)日：2004-01-27

    申请号：US09702745

    申请日：2000-11-01

    申请人： Vernon Charles Gibson ,  Brian Stephen Kimberley ,  Gregory Adam Solan

    发明人： Vernon Charles Gibson ,  Brian Stephen Kimberley ,  Gregory Adam Solan

    IPC分类号： C08F444

    CPC分类号： C08F10/00 ,  C07F7/003 ,  C07F9/005 ,  C07F11/005 ,  C07F15/025 ,  C07F15/065 ,  C08F110/02 ,  C08F4/68284 ,  C08F4/025 ,  C08F4/69224 ,  C08F4/64089 ,  C08F2500/04 ,  C08F4/7042 ,  C08F4/7054 ,  C08F4/7044

    摘要： A complex suitable for the polymerization of l-olefins is disclosed, having the Formula A wherein M is a transition metal, lanthanide or actinide; X represents an atom or group covalently or ionically bonded to the transition metal M; b is the valency of the atom or group X; Z1 is N or P; Z2 is N, P, N−, P−or NR5; Z3 is one of N, P, O, S, NHR3, NR3R4, OH, OR3, SH, SR3, PHR3, PR3R4, (NR3)−, O−, S−, (PR3)−, P(R3R4)O, NR3 or PR3 to the proviso that one of Z2 and Z3 is anionic; T is the oxidation state of the transition metal M when both Z2 or Z3 are neutral, and is one less than the oxidation state of M when one of Z2 or Z3 is anionic; A and B are independently hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl, and may together with Z2 form part of a heterocyclic substituent; B may be joined to Z3 by either a single or a double bond; R1 to R5 are each independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl, and any two or more of R1 to R5 when hydrocarbyl may be joined together to form a ring; L is a solvate molecule, and n is from 0 to 5. The complex is useful as a polymerization catalyst in a process for the polymerization and copolymerization of olefins.

    摘要翻译： 公开了适用于1-烯烃聚合的络合物，其具有式A，其中M是过渡金属，镧系元素或锕系元素; X表示与过渡金属M共价或离子键合的原子或基团; b是原子或基团X的化合价; Z 1是N或P; Z 2是N，P，N，P或NR 5; Z 3是N，P，O，S，NHR 3，NR 3 R 4，OH，OR 3，SH，SR 3，PHR 3，PR < （R 3）R 3，（NR 3） - ，O - ，S - ，（PR 3） - ，P（R 3 R 4） NR 3或PR 3，条件是Z 2和Z 3中的一个为阴离子; 当Z 2或Z 3均为中性时，T是过渡金属M的氧化态，当Z 2或Z 3中的一个为阴离子时，其摩尔比小于M的氧化态; A和B独立地是烃基，取代的烃基，杂烃基或取代的杂烃基，并且可以与Z 2一起形成杂环取代基的一部分; B可以通过单键或双键与Z 3连接; R 1至R 5各自独立地选自氢，卤素，烃基，取代的烃基，杂烃基或取代的杂烃基，当烃基可以连接在一起时，R 1至R 5中的任何两个或多个 形成戒指 L是溶剂化物分子，n为0至5.该络合物可用作烯烃聚合和共聚方法中的聚合催化剂。

    Supported olefin polymerization catalyst
    9.
    发明授权
    Supported olefin polymerization catalyst 有权
    负载型烯烃聚合催化剂

    公开(公告)号：US07811956B2

    公开(公告)日：2010-10-12

    申请号：US12216323

    申请日：2008-07-02

    申请人： Grant Berent Jacobsen ,  Brian Stephen Kimberley ,  Sergio Mastroianni

    发明人： Grant Berent Jacobsen ,  Brian Stephen Kimberley ,  Sergio Mastroianni

    IPC分类号： C08F4/02 ,  C08F4/602 ,  C08F4/642

    CPC分类号： C08F210/16 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65916 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/04

    摘要： A supported catalyst system comprises (a) a dehydrated support material, (b) a transition metal compound, and (c) an activator and is characterised in that the support material has been pretreated with at least two different organoaluminum compounds prior to content with either or both the transition metal-compound or the activator. The prefer transition metal compound is a metallocene and the supported catalyst systems are suitable for the preparation of polymers having broad molecular weight distributions and improved melt strength.

    摘要翻译： 负载催化剂体系包括（a）脱水的载体材料，（b）过渡金属化合物和（c）活化剂，其特征在于，所述载体材料在含量之前用至少两种不同的有机铝化合物预处理 或过渡金属化合物或活化剂两者。 优选的过渡金属化合物是茂金属，并且负载型催化剂体系适用于制备具有宽分子量分布和改进的熔体强度的聚合物。

    Polymerization process
    10.
    发明授权
    Polymerization process 有权
    聚合过程

    公开(公告)号：US07335710B2

    公开(公告)日：2008-02-26

    申请号：US11347237

    申请日：2006-02-06

    申请人： Choon Kooi Chai ,  Brian Stephen Kimberley ,  Sergio Mastroianni

    发明人： Choon Kooi Chai ,  Brian Stephen Kimberley ,  Sergio Mastroianni

    IPC分类号： C08F4/6392 ,  C08F4/6592

    CPC分类号： C08F210/16 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65908 ,  C08F2/34

    摘要： A process for the polymerisation of olefins is described involving the use of a catalyst system comprising a supported transition metal compound and an activator based on an organoborane and an aluminoxane. Preferably the transition metal compound is a metallocene complex. The support is pretreated with an organoaluminium compound and the process is particularly suitable for the gas phase preparation of copolymers of ethylene and alpha-olefins having a molecular weight distribution in the range 2.5-7.0 and a melt strength in the range 3-12 cN.

    摘要翻译： 描述了用于烯烃聚合的方法，涉及使用包含负载的过渡金属化合物和基于有机硼烷和铝氧烷的活化剂的催化剂体系。 优选地，过渡金属化合物是茂金属络合物。 该载体用有机铝化合物预处理，该方法特别适用于分子量分布范围为2.5-7.0，熔体强度在3-12cN范围内的乙烯和α-烯烃共聚物的气相制备。