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公开(公告)号：US20110166376A1
公开(公告)日：2011-07-07
申请号：US12999336
申请日：2009-06-05
申请人： Sergio Mastroianni
发明人： Sergio Mastroianni
IPC分类号： C07C253/10
CPC分类号： C07C253/10 , B01J31/185 , B01J31/2404 , B01J2231/32 , B01J2531/847 , C07C255/04
摘要： A process for the hydrocyanation of a hydrocarbon-based compound having at least one site of ethylenic unsaturation into a nitrile compound includes reaction thereof, in a liquid medium, with hydrogen cyanide in the presence of a catalyst containing a metal element selected from among the transition metals and an organophosphorus ligand, wherein the organophosphorus ligand is a mixture of at least one monodentate organophosphite compound and at least one monodentate organophosphine compound; the subject process is especially useful for the synthesis of adiponitrile from butadiene.
摘要翻译： 将具有至少一个烯属不饱和位点的烃类化合物氢氰化为腈化合物的方法包括在液体介质中与氰化氢反应，在含有选自过渡金属的金属元素的催化剂存在下， 金属和有机磷配体，其中有机磷配体是至少一种单齿有机亚磷酸酯化合物和至少一种单齿有机膦化合物的混合物; 本发明方法对于从丁二烯合成己二腈是特别有用的。
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公开(公告)号：US07863213B2
公开(公告)日：2011-01-04
申请号：US11800773
申请日：2007-05-07
IPC分类号： C08F4/6592 , B01J31/22 , B01J31/14
CPC分类号： C08F10/02 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F110/02 , C08F210/16 , C08F2410/02 , Y10S526/943 , C08F4/65908 , C08F210/14 , C08F2500/03
摘要： A supported catalyst for olefin polymerization comprises a selected ionic activator, a selected organometallic catalyst and a support material. The selected activator must contain an active hydrogen moeity. The organometallic catalyst is characterized by having a phosphinimine ligand and a substituted cyclopentadienyl ligand (which contains from 7 to 30 carbon atoms). The supported catalyst exhibits excellent activity in gas phase olefin polymerizations and may be used under substantially “non-fouling” polymerization conditions.
摘要翻译： 用于烯烃聚合的负载催化剂包括选择的离子活化剂，选择的有机金属催化剂和载体材料。 选择的活化剂必须含有活性氢气。 有机金属催化剂的特征在于具有膦亚胺配体和取代的环戊二烯基配体（其含有7至30个碳原子）。 载体催化剂在气相烯烃聚合中表现出优异的活性，并且可以在基本上“非污染”的聚合条件下使用。
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公开(公告)号：US20090131613A1
公开(公告)日：2009-05-21
申请号：US11921268
申请日：2006-06-01
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/6592 , C08F210/16 , C08F2420/02 , C08F4/65908 , C08F4/65916 , C08F210/14 , C08F2500/03
摘要： A method for the preparation of a supported polymerisation catalyst system, comprises: (1) contacting together in a suitable solvent (a) a transition metal polymerisation talyst and (b) a cocatalyst, (2) contacting the mixture from step (1) with a porous support material, and (3) removing the solvent is characterised in that the molar ratio of cocatalyst to transition metal catalyst is
摘要翻译： 一种制备负载型聚合催化剂体系的方法，包括：（1）在合适的溶剂（a）过渡金属聚合保护剂和（b）助催化剂中，（2）使步骤（1）的混合物与 多孔载体材料，（3）除去溶剂的特征在于助催化剂与过渡金属催化剂的摩尔比为10:1。 优选的聚合催化剂是过渡金属化合物，特别是茂金属络合物。 在添加到载体之前将催化剂组分预混合导致某些优点，特别是更容易的制备方法而没有任何活性损失。
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公开(公告)号：US07528090B2
公开(公告)日：2009-05-05
申请号：US10568822
申请日：2004-08-04
IPC分类号： C08F4/02 , C08F4/6592 , B01J31/22
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65916 , C08F4/6592 , C08F2420/02 , C08F4/65912 , C08F210/14
摘要： A supported polymerisation catalyst system comprises a porous support, a polymerisation catalyst and a cocatalyst wherein the support has been treated with an inert material such as polyisobutene. The support is preferably silica and is preferably treated with the inert material prior to contact with the other components. Preferably the polymerisation catalyst is a metallocene and the polymerisation catalyst system reduces the initial peak isotherm allowing for a smoother activity increase in particular for polymerisations carried out in the gas phase.
摘要翻译： 负载型聚合催化剂体系包括多孔载体，聚合催化剂和助催化剂，其中载体已用惰性材料如聚异丁烯处理。 载体优选为二氧化硅，并且优选在与其它组分接触之前用惰性材料处理。 优选地，聚合催化剂是茂金属，并且聚合催化剂体系降低了初始峰值等温线，从而允许更平滑的活性增加，特别是对于在气相中进行的聚合反应。
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公开(公告)号：US07476715B2
公开(公告)日：2009-01-13
申请号：US11800590
申请日：2007-05-07
IPC分类号： C08F2/34
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65916 , C08F4/6592 , C08F10/02 , C08F210/16 , C08F2410/02 , Y10S526/901 , Y10S526/943 , C08F4/025 , C08F2/002 , C08F4/65912 , C08F210/14
摘要： The use of high activity “Single Site” polymerization catalysts often causes the fouling of polymerization reactors. The problem is particularly acute with gas phase polymerizations. While not wishing to be bound by theory it is believed that the fouling is initiated by the buildup of static charges in the reactor. The use of anti-static agents mitigates this problem, but typical antistatic agents contain polar species, which can deactivate the polymerization catalyst. We have now discovered that the use of a porous metal oxide support allows large levels of a selected antistatic agent to be used in a manner that reduces static/fouling problems in highly active polymerization catalysts.
摘要翻译： 使用高活性“单点”聚合催化剂通常会导致聚合反应器的结垢。 气相聚合问题尤其严重。 虽然不希望被理论束缚，但据信污垢是由反应器中静电荷的累积引起的。 使用抗静电剂减轻了这个问题，但是典型的抗静电剂含有极性物质，这可以使聚合催化剂失活。 我们现在已经发现，使用多孔金属氧化物载体允许以降低高活性聚合催化剂中静电/结垢问题的方式使用大量选定的抗静电剂。
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公开(公告)号：US20070135296A1
公开(公告)日：2007-06-14
申请号：US10568822
申请日：2004-08-04
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65916 , C08F4/6592 , C08F2420/02 , C08F4/65912 , C08F210/14
摘要： A supported polymerisation catalyst system comprises a porous support, a polymerisation catalyst and a cocatalyst wherein the support has been treated with an inert material such as polyisobutene. The support is preferably silica and is preferably treated with the inert material prior to contact with the other components. Preferably the polymerisation catalyst is a metallocene and the polymerisation catalyst system reduces the initial peak isotherm allowing for a smoother activity increase in particular for polymerisations carried out in the gas phase.
摘要翻译： 负载型聚合催化剂体系包括多孔载体，聚合催化剂和助催化剂，其中载体已用惰性材料如聚异丁烯处理。 载体优选为二氧化硅，并且优选在与其它组分接触之前用惰性材料处理。 优选地，聚合催化剂是茂金属，并且聚合催化剂体系降低了初始峰值等温线，从而允许更平滑的活性增加，特别是对于在气相中进行的聚合反应。
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公开(公告)号：US08846975B2
公开(公告)日：2014-09-30
申请号：US13697189
申请日：2011-05-09
CPC分类号： C07C51/316 , C07C55/14 , C07C55/02
摘要： A process for preparing dicarboxylic acids is described. More particularly a process is described for preparing adipic acid (1,6-hexanedioic acid), by the action of nitric acid, starting from cyclic ketones or alcohols which are the corresponding compounds from the standpoint of the number of carbon atoms, in the presence of one or more oxides of nitrogen at a molar concentration in the reaction mixture of greater than 2.5 mmol per kg of reaction mixture.
摘要翻译： 描述了制备二羧酸的方法。 更具体地描述了一种通过硝酸的作用制备己二酸（1,6-己二酸）的方法，该方法是在存在碳原子数的情况下，从作为相应化合物的环状酮或醇开始 的一种或多种氮氧化物，其反应混合物中摩尔浓度大于2.5mmol / kg反应混合物。
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公开(公告)号：US08697902B2
公开(公告)日：2014-04-15
申请号：US12999350
申请日：2009-06-05
申请人： Sergio Mastroianni
发明人： Sergio Mastroianni
IPC分类号： C07C253/00 , C07F9/02
CPC分类号： C07C253/10 , B01J31/2404 , B01J2231/32 , B01J2531/847 , C07C255/04
摘要： A process for the hydrocyanation of a hydrocarbon-based compound having at least one site of ethylenic unsaturation into a nitrile compound includes reaction thereof, in a liquid medium, with hydrogen cyanide in the presence of a catalyst containing a metal element selected from among the transition metals and an organophosphorus ligand, wherein the organophosphorus ligand is a compound of formula (I): The subject process is particularly useful for the synthesis of adiponitrile from butadiene.
摘要翻译： 将具有至少一个烯属不饱和位点的烃类化合物氢氰化为腈化合物的方法包括在液体介质中与氰化氢反应，在含有选自过渡金属的金属元素的催化剂存在下， 金属和有机磷配体，其中有机磷配体是式（I）的化合物：本发明方法特别可用于从丁二烯合成己二腈。
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公开(公告)号：US08536081B2
公开(公告)日：2013-09-17
申请号：US11667466
申请日：2005-11-10
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F210/16 , C08F2420/02 , C08F2420/04 , Y02P20/52 , C08F4/6592 , C08F210/14 , C08F2500/12 , C08F2500/09
摘要： Supported catalyst system for the polymerization of olefins, having at least two different monocyclopentadienyl transition metal compounds, one or more activators including an ionic compound having (i) a cation and (ii) an anion having up to 100 non-hydrogen atoms and the anion containing at least one substituent comprising a moiety having an active hydrogen, and one or more support materials. The supported “mixed or dual site” catalyst systems having different monocyclopentadienyl catalysts when activated by specific ionic activators lead to catalyst systems showing an improved balance of properties which may be used to prepare LLDPE polymers having broad melt flow ratios.
摘要翻译： 用于烯烃聚合的负载催化剂体系，其具有至少两种不同的单环戊二烯基过渡金属化合物，一种或多种活化剂，其包括具有（i）阳离子和（ii）具有至多100个非氢原子的阴离子的离子化合物和阴离子 含有至少一个包含具有活性氢的部分的取代基和一种或多种载体材料。 当由特定的离子活化剂活化时，具有不同单环戊二烯基催化剂的“混合或双位点”催化剂体系导致催化剂体系显示改进的性能平衡，其可用于制备具有宽熔体流动比的LLDPE聚合物。
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公开(公告)号：US08338551B2
公开(公告)日：2012-12-25
申请号：US12225098
申请日：2007-03-06
申请人： Grant Berent Jacobsen , Claudine Viviane Lalanne-Magne , Sergio Mastroianni , Melanie Muron , Eric Nicolas Vincent Osmont
发明人： Grant Berent Jacobsen , Claudine Viviane Lalanne-Magne , Sergio Mastroianni , Melanie Muron , Eric Nicolas Vincent Osmont
IPC分类号： C08F4/64 , C08F4/76 , C08F4/52 , C08F210/02 , C08F210/16
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/6592 , C08F210/16 , C08J5/18 , C08J2323/08 , Y10T428/268 , C08F4/65916 , C08F210/14 , C08F2500/12 , C08F2500/24 , C08F2500/26
摘要： Method for the preparation of a blown film containing 300-600 gels/m2 of size in the range 100-2000 μm as measured by an optical control system, in which the film is derived by extrusion from an ethylene-α-olefin copolymer. The method is carried out by preparing the copolymer in a particle forming polymerization process in the presence of a single site catalyst system containing a single site catalyst, a cocatalyst, and a support material.
摘要翻译： 制备通过光学控制系统测量的100-2000μm范围内的300-600凝胶/ m2尺寸的吹塑薄膜的方法，其中通过乙烯-α-烯烃共聚物的挤出得到薄膜。 该方法通过在含有单中心催化剂，助催化剂和载体材料的单中心催化剂体系的存在下，在颗粒形成聚合方法中制备共聚物来进行。
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