公开(公告)号：US06218048B1

公开(公告)日：2001-04-17

申请号：US09286969

申请日：1999-04-06

申请人： Vesselin Manev ,  Titus Faulkner ,  D. Wayne Barnette ,  John Francis Engel

发明人： Vesselin Manev ,  Titus Faulkner ,  D. Wayne Barnette ,  John Francis Engel

IPC分类号： H01M450

CPC分类号： H01M4/131 ,  H01M2/1673 ,  H01M4/04 ,  H01M4/0402 ,  H01M4/0442 ,  H01M4/1391 ,  H01M4/485 ,  H01M4/505 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/42 ,  H01M2004/028 ,  Y10T29/49108 ,  Y10T29/49115

摘要： The present invention includes a method of preparing secondary lithium and lithium-ion batteries with improved coulombic efficiency, improved cycling and storage performance at elevated temperatures, and lower rates of transition metal dissolution. In accordance with the present invention, the positive electrode material is thermally treated at a temperature of between 50° C. and 120° C. to produce a passivating film having lithium ion conductivity. The present invention also includes a secondary lithium or lithium-ion cell having positive electrode material covered with a thermally-activated thin passivating film having lithium ion conductivity and a positive electrode material formed of particles of a lithium intercalation compound with a passivating film on the surface of the particles.

摘要翻译： 本发明包括一种制备二次锂和锂离子电池的方法，其具有提高的库仑效率，在升高的温度下改善的循环和储存性能以及较低的过渡金属溶解速率。 根据本发明，在50℃〜120℃的温度下对正极材料进行热处理，得到具有锂离子传导性的钝化膜。 本发明还包括具有由具有锂离子传导性的热活化薄钝化膜和由表面上具有钝化膜的锂嵌入化合物的颗粒形成的正极材料覆盖的正极材料的二次锂或锂离子电池 的颗粒。

公开(公告)号：US06423294B1

公开(公告)日：2002-07-23

申请号：US09842459

申请日：2001-04-26

申请人： Vesselin Manev ,  Titus Faulkner ,  D. Wayne Barnette

发明人： Vesselin Manev ,  Titus Faulkner ,  D. Wayne Barnette

IPC分类号： C01G4502

摘要： The present invention includes lithium manganese oxide spinel compounds having a low porosity, a high tap density and a high pellet density, and methods of preparing these compounds. In particular, the method comprises preparing a lithium manganese oxide with a spinel structure and having the formula: wherein: Li 1 + X ⁢ Mn 2 - Y ⁢ M m 1 1 ⁢ M m 2 2 ⁢ … ⁢   ⁢ M m k k ⁢ O 4 + Z M1, M2, . . . Mk are cations different than lithium or manganese selected from the group consisting of alkaline earth metals, transition metals, B, Al, Si, Ga and Ge; X, Y, m1, m2, . . . mk, each have a value between 0 and 0.2; Z has a value between −0.1 and 0.2; and X, Y, m1, M2. . . mk are selected to satisfy the equation: Y=X+m1+m2+. . . +mk.

公开(公告)号：US06517803B2

公开(公告)日：2003-02-11

申请号：US09842968

申请日：2001-04-26

申请人： Vesselin Manev ,  Titus Faulkner ,  D. Wayne Barnette

发明人： Vesselin Manev ,  Titus Faulkner ,  D. Wayne Barnette

IPC分类号： C01G4502

CPC分类号： H01M4/505 ,  C01G45/02 ,  C01G45/1242 ,  C01G53/54 ,  C01P2002/32 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2004/03 ,  C01P2006/10 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/40

摘要： The present invention includes lithium manganese oxide spinel compounds having a low porosity, a high tap density and a high pellet density, and methods of preparing these compounds. In particular, the method comprises preparing a lithium manganese oxide with a spinel structure and having the formula: wherein: Li1+XMn2−YMm11Mm22 . . . MmkkO4+Z M1, M2, . . . Mk are cations different than lithium or manganese selected from the group consisting of alkaline earth metals, transition metals, B, Al, Si, Ga and Ge; X, Y, m1, m2, . . . , mk, each have a value between 0 and 0.2; Z has a value between −0.1 and 0.2; and X, Y, m1, m2, . . . mk are selected to satisfy the equation: Y=X+m1+m2+ . . . +mk.

摘要翻译： 本发明包括具有低孔隙率，高振实密度和高颗粒密度的锂锰氧化物尖晶石化合物以及这些化合物的制备方法。 特别地，该方法包括制备具有尖晶石结构的锂锰氧化物并具有下式：其中：M1，M2，...。 。 。 Mk是选自碱土金属，过渡金属，B，Al，Si，Ga和Ge中的锂或锰的阳离子; X，Y，m1，m2。 。 。 ，mk各自具有介于0和0.2之间的值; Z具有介于-0.1和0.2之间的值; 和X，Y，m1，m2。 。 。 mk被选择以满足等式：

公开(公告)号：US06267943B1

公开(公告)日：2001-07-31

申请号：US09418352

申请日：1999-10-14

申请人： Vesselin Manev ,  Titus Faulkner ,  D. Wayne Barnette

发明人： Vesselin Manev ,  Titus Faulkner ,  D. Wayne Barnette

IPC分类号： C01G4502

CPC分类号： H01M4/505 ,  C01G45/02 ,  C01G45/1242 ,  C01G53/54 ,  C01P2002/32 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2004/03 ,  C01P2006/10 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/40

摘要： The present invention includes lithium manganese oxide spinel compounds having a low porosity, a high tap density and a high pellet density, and methods of preparing these compounds. In particular, the method comprises preparing a lithium manganese oxide with a spinel structure and having the formula: wherein: Li1+XMn2−YM1m1M2m2 . . . MkmkO4+Z M1, M2, . . . Mk are cations different than lithium or manganese selected from the group consisting of alkaline earth metals, transition metals, B, Al, Si, Ga and Ge; X, Y, m1, m2, . . . , mk, each have a value between 0 and 0.2; Z has a value between −0.1 and 0.2; and X, Y, m1, m2, . . . mk are selected to satisfy the equation: Y=X+m1+m2+ . . . +mk.

摘要翻译： 本发明包括具有低孔隙率，高振实密度和高颗粒密度的锂锰氧化物尖晶石化合物，以及这些化合物的制备方法。 特别地，该方法包括制备具有尖晶石结构的锂锰氧化物并具有下式：其中：M1，M2，...。 。 。 Mk是选自碱土金属，过渡金属，B，Al，Si，Ga和Ge中的锂或锰的阳离子; X，Y，m1，m2。 。 。 ，mk各自具有介于0和0.2之间的值; Z具有介于-0.1和0.2之间的值; 和X，Y，m1，m2。 。 。 mk被选择以满足等式：

公开(公告)号：US6040089A

公开(公告)日：2000-03-21

申请号：US31849

申请日：1998-02-27

申请人： Vesselin Manev ,  Titus Faulkner ,  Wayne Barnette ,  Yuan Gao

发明人： Vesselin Manev ,  Titus Faulkner ,  Wayne Barnette ,  Yuan Gao

IPC分类号： H01M4/131 ,  H01M4/50 ,  H01M4/505 ,  H01M10/052 ,  H01M10/36

CPC分类号： H01M4/505 ,  H01M4/131 ,  H01M10/052

摘要： The present invention provides a positive electrode material for lithium and lithium-ion secondary cells which exhibits good cycleability, reversible specific capacity, and structural stability. The positive electrode material comprises a lithium multi metal oxide having a spinel structure and described by the general formula:Li.sub.1+X Mn.sub.2-Y M.sub.m.sbsb.1.sup.1 M.sub.m.sbsb.2.sup.2 . . . M.sub.m.sbsb.k.sup.k O.sub.4+Zwherein M.sup.1, M.sup.2, . . . M.sup.k are at least two cations different than lithium or manganese, selected from the group consisting of alkaline earth metals, transition metals, B, Al, Si, Ga and Ge;X, Y, m.sub.1,m.sub.2, . . . m.sub.k are numbers between 0 and 0.2;m.sub.1, m.sub.2 and Y are greater than 0;Z is a number between -0.1 and 0.2; andwherein the metals M.sup.1, M.sup.2, . . . M.sup.k and the corresponding values m.sub.1, m.sub.2, . . . m.sub.k satisfy the following equation and inequality: ##EQU1## wherein V.sub.1, V.sub.2, . . . V.sub.k are the corresponding valence states of the cations M.sup.1, M.sup.2, . . . M.sup.k.

摘要翻译： 本发明提供一种锂离子二次电池用正极材料，其具有良好的循环性，可逆的比容量和结构稳定性。 正极材料包括具有尖晶石结构并由通式Li1 + XMn2-YMm11Mm22描述的锂多金属氧化物。 。 。 MmkkO4 + Z其中M1，M2，...。 。 。 Mk是选自碱金属，过渡金属，B，Al，Si，Ga和Ge中的至少两种不同于锂或锰的阳离子; X，Y，m1，m2。 。 。 mk是0到0.2之间的数字; m1，m2和Y大于0; Z是-0.1和0.2之间的数字; 并且其中金属M1，M2，...。 。 。 Mk和相应的值m1，m2。 。 。 mk满足以下等式和不等式：其中V1，V2，...。 。 。 Vk是阳离子M1，M2的相应的价态。 。 。 Mk

公开(公告)号：US5766800A

公开(公告)日：1998-06-16

申请号：US867160

申请日：1997-06-02

申请人： Vesselin Manev ,  Titus Faulkner

发明人： Vesselin Manev ,  Titus Faulkner

IPC分类号： C01B31/02 ,  C01G45/00 ,  H01M4/131 ,  H01M4/50 ,  H01M4/505 ,  H01M10/052 ,  H01M10/36 ,  C01G45/12

CPC分类号： H01M4/505 ,  C01G45/1242 ,  H01M4/131 ,  C01P2002/32 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2006/12 ,  C01P2006/40 ,  H01M10/052

摘要： A novel method of preparing a spinel Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compound with low lattice distortion and a highly ordered and homogeneous structure for 4 V secondary lithium and lithium ion cells is provided. The method of preparing the spinel Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compound comprises providing a spinel Li.sub.1+X Mn.sub.2-X O.sub.4 intercalation compound having a lithium to manganese mole ratio of between about 1.02:2 and 1.1:2 and firing the spinel at different temperature ranges with corresponding gas flow rates to form the spinel Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compounds. The spinel Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compounds have a mean X value of between about 0.01 and 0.05, a mean Y value of between about -0.02 and 0.04 and a full width at half maximum of the x-ray diffraction peaks at a diffraction angle 2.theta. of planes (400) and (440) using CuK.alpha..sub.1 rays of between about 0.08.degree. and 0.13.degree.. The spinel Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compounds may be used in the positive electrodes of secondary lithium and lithium ion cells to provide cells having high specific capacities and long cycling lives.

摘要翻译： 提供了一种制备具有低晶格畸变的尖晶石Li1 + XMn2-XO4 + Y插层化合物和用于4 V二次锂和锂离子电池的高度有序和均匀结构的新方法。 制备尖晶石Li1 + XMn2-XO4 + Y插层化合物的方法包括提供锂/锰摩尔比在约1.02:2至1.1:2之间的尖晶石Li1 + XMn2-XO4插层化合物，并在不同温度下烧制尖晶石 范围与相应的气体流速形成尖晶石Li1 + XMn2-XO4 + Y插层化合物。 尖晶石Li1 + XMn2-XO4 + Y插入化合物的平均X值在约0.01和0.05之间，平均Y值在约-0.02和0.04之间，并且x射线衍射峰的全宽度在 使用约0.08和0.13之间的CuKα1射线的平面（400）和（440）的衍射角2θ。 尖晶石Li1 + XMn2-XO4 + Y插层化合物可用于二次锂离子电池和锂离子电池的正电极，以提供具有高比容量和长循环寿命的电池。

公开(公告)号：US5792442A

公开(公告)日：1998-08-11

申请号：US665396

申请日：1996-06-18

申请人： Vesselin Manev ,  Titus Faulkner

发明人： Vesselin Manev ,  Titus Faulkner

IPC分类号： C01G45/00 ,  H01M4/131 ,  H01M4/50 ,  H01M4/505 ,  H01M4/62 ,  H01M10/052 ,  H01M10/36 ,  C01G45/12

CPC分类号： H01M4/505 ,  C01G45/1242 ,  H01M4/131 ,  H01M4/623 ,  C01P2002/32 ,  C01P2002/72 ,  C01P2002/77 ,  C01P2006/40 ,  H01M10/052 ,  Y02P70/54

摘要： A novel method of preparing a spinel Li.sub.1+X Mn.sub.2-X O.sub.4 intercalation compound with low lattice distortion and a highly ordered and homogeneous structure for 4 V secondary lithium and lithium ion cells is provided. The method of preparing the spinel Li.sub.1+X Mn.sub.2-X O.sub.4 intercalation compound comprises mixing at least one manganese compound with at least one lithium compound and firing the mixture at three different temperature ranges with corresponding gas flow rates to form the spinel Li.sub.1+X Mn.sub.2-X O.sub.4 intercalation compounds. The spinel Li.sub.1+X Mn.sub.2-X O.sub.4 intercalation compounds have a mean X value of between about 0.01 and 0.05 and a full width at half maximum of the x-ray diffraction peaks at a diffraction angle 2.theta. of planes (400) and (440) using CuK.alpha..sub.1 rays of between about 0.10.degree. and 0.15.degree.. The spinel Li.sub.1+X Mn.sub.2-X O.sub.4 intercalation compounds may be used in the positive electrodes of secondary lithium and lithium ion cells to provide cells having high specific capacities and long cycling lives.

摘要翻译： 提供了一种制备具有低晶格畸变的尖晶石Li1 + XMn2-XO4插层化合物和用于4 V二次锂和锂离子电池的高度有序和均匀结构的新方法。 制备尖晶石Li1 + XMn2-XO4插层化合物的方法包括将至少一种锰化合物与至少一种锂化合物混合，并在三种不同的温度范围内以相应的气体流速烧制该混合物以形成尖晶石Li1 + XMn2-XO4插层 化合物。 尖晶石Li1 + XMn2-XO4插层化合物的平均X值在平面（400）和（440）的衍射角2θ处的x射线衍射峰的平均X值为大约0.01和0.05之间的全宽，使用 约0.10°至0.15°之间的CuKα1射线。 尖晶石Li1 + XMn2-XO4插层化合物可用于二次锂离子电池和锂离子电池的正电极，以提供具有高比容量和长循环寿命的电池。

公开(公告)号：US6114064A

公开(公告)日：2000-09-05

申请号：US867190

申请日：1997-06-02

申请人： Vesselin Manev ,  Titus Faulkner

发明人： Vesselin Manev ,  Titus Faulkner

IPC分类号： C01G45/00 ,  H01M4/131 ,  H01M4/50 ,  H01M4/505 ,  H01M4/62 ,  H01M10/052 ,  H01M10/36

CPC分类号： H01M4/505 ,  C01G45/1242 ,  H01M4/131 ,  H01M4/623 ,  C01P2002/32 ,  C01P2002/72 ,  C01P2002/77 ,  C01P2006/40 ,  H01M10/052 ,  Y02P70/54

摘要： A novel method of preparing a spinel Li.sub.1+x Mn.sub.2-x O.sub.4 intercalation compound with low lattice distortion and a highly ordered and homogeneous structure for 4 V secondary lithium and lithium ion cells is provided. The method of preparing the spinel Li.sub.1+x Mn.sub.2-x O.sub.4 intercalation compound comprises mixing at least one manganese compound with at least one lithium compound and firing the mixture at three different temperature ranges with corresponding gas flow rates to form the spinel Li.sub.1+x Mn.sub.2-x O.sub.4 intercalation compounds. The spinel Li.sub.1+x Mn.sub.2-x O.sub.4 intercalation compounds have a mean X value of between about 0.01 and 0.05 and a full width at half maximum of the x-ray diffraction peaks at a diffraction angle 2.theta. of planes (400) and (440) using CuK.alpha..sub.1 rays of between about 0.10.degree. and 0.15.degree.. The spinel Li.sub.1+x Mn.sub.2-x O.sub.4 intercalation compounds may be used in the positive electrodes of secondary lithium and lithium ion cells to provide cells having high specific capacities and long cycling lives.

摘要翻译： 提供了一种制备具有低晶格畸变的尖晶石Li1 + xMn2-xO4插层化合物和用于4V二次锂和锂离子电池的高度有序和均匀结构的新方法。 制备尖晶石Li1 + xMn2-xO4插层化合物的方法包括将至少一种锰化合物与至少一种锂化合物混合，并在三种不同的温度范围内以相应的气体流速烧结该混合物以形成尖晶石Li1 + xMn2-xO4插层 化合物。 尖晶石Li1 + xMn2-xO4插入化合物的平均X值在平面（400）和（440）的衍射角2θ处的X射线衍射峰的平均X值为约0.01和0.05之间的全宽，使用 约0.10°至0.15°之间的CuKα1射线。 尖晶石Li1 + xMn2-xO4插层化合物可用于二次锂离子电池和锂离子电池的正电极，以提供具有高比容量和长循环寿命的电池。

公开(公告)号：US5718877A

公开(公告)日：1998-02-17

申请号：US665408

申请日：1996-06-18

申请人： Vesselin Manev ,  Titus Faulkner

发明人： Vesselin Manev ,  Titus Faulkner

IPC分类号： C01B31/02 ,  C01G45/00 ,  H01M4/131 ,  H01M4/50 ,  H01M4/505 ,  H01M10/052 ,  H01M10/36 ,  C01G45/12

CPC分类号： H01M4/505 ,  C01G45/1242 ,  H01M4/131 ,  C01P2002/32 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2006/12 ,  C01P2006/40 ,  H01M10/052

摘要： A novel method of preparing a spinel Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compound with low lattice distortion and a highly ordered and homogeneous structure for 4 V secondary lithium and lithium ion cells is provided. The method of preparing the spinel Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compound comprises providing a spinel Li.sub.1+X Mn.sub.2-X O.sub.4 intercalation compound having a lithium to manganese mole ratio of between about 1.02:2 and 1.1:2 and firing the spinel at different temperature ranges with corresponding gas flow rates to form the spinel Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compounds. The spinel Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compounds have a mean X value of between about 0.01 and 0.05, a mean Y value of between about -0.02 and 0.04 and a full width at half maximum of the x-ray diffraction peaks at a diffraction angle 2.theta. of planes (400) and (440) using CuK.alpha..sub.1 rays of between about 0.08.degree. and 0.13.degree.. The spinel Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compounds may be used in the positive electrodes of secondary lithium and lithium ion cells to provide cells having high specific capacities and long cycling lives.

摘要翻译： 提供了一种制备具有低晶格畸变的尖晶石Li1 + XMn2-XO4 + Y插层化合物和用于4 V二次锂和锂离子电池的高度有序和均匀结构的新方法。 制备尖晶石Li1 + XMn2-XO4 + Y插层化合物的方法包括提供锂/锰摩尔比在约1.02:2至1.1:2之间的尖晶石Li1 + XMn2-XO4插层化合物，并在不同温度下烧制尖晶石 范围与相应的气体流速形成尖晶石Li1 + XMn2-XO4 + Y插层化合物。 尖晶石Li1 + XMn2-XO4 + Y插入化合物的平均X值在约0.01和0.05之间，平均Y值在约-0.02和0.04之间，并且x射线衍射峰的全宽度在 使用约0.08和0.13之间的CuKα1射线的平面（400）和（440）的衍射角2θ。 尖晶石Li1 + XMn2-XO4 + Y插层化合物可用于二次锂离子电池和锂离子电池的正电极，以提供具有高比容量和长循环寿命的电池。

公开(公告)号：US20060115718A1

公开(公告)日：2006-06-01

申请号：US11000277

申请日：2004-11-30

申请人： Mohammad Parsian ,  Vesselin Manev ,  Yee-Ho Chia

发明人： Mohammad Parsian ,  Vesselin Manev ,  Yee-Ho Chia

IPC分类号： H01M10/04 ,  H01M6/46 ,  H01M2/14

CPC分类号： H01M10/0585 ,  H01M10/0525 ,  H01M10/0565 ,  Y10T29/49112

摘要： A lithium polymer battery or multi-cell and a method of making the multi-cells. The multi-cell comprises a plurality of laminated single cell units, each unit comprising, laminated in sequence, a negative electrode current collector, a negative electrode, a first electrolyte-impregnated separator, a positive electrode, and a positive electrode current collector. These single cell units are stacked one next to another in sequence and a second electrolyte-impregnated separator is positioned between adjacent laminated cell units. The method includes positioning, in sequence, a negative electrode current collector, a negative electrode, a first porous separator, a positive electrode, and a positive electrode current collector to form a single cell unit. A plurality of the single cell units are then positioned adjacent one another in sequence, and a second porous separator is positioned between adjacent single cell units. The method further includes impregnating each of the first and second porous separators with an electrolyte and laminating each single cell unit, but adjacent cell units are not laminated to one another.

摘要翻译： 锂聚合物电池或多电池以及制造多电池的方法。 多单元包括多个层压单电池单元，每个单元包括依次层叠负极集电体，负极，第一电解质浸渍隔板，正极和正极集电体。 这些单电池单元依次堆叠在另一个电池单元之间，并且第二电解质浸渍的隔板位于相邻的层压电池单元之间。 该方法包括依次定位负极集电体，负极，第一多孔隔板，正极和正极集电体，以形成单电池单元。 然后将多个单电池单元依次相邻地定位，并且第二多孔隔板位于相邻的单电池单元之间。 该方法还包括用电解质浸渍第一和第二多孔隔板中的每一个，并层压每个单电池单元，但相邻电池单元彼此不层压。