利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

16 条记录 (耗时 0.014 秒)

    Method of manufacturing polyalkyl methacrylate macromonomers, and use of same in the manufacture of comb polymers
    2.
    发明授权
    Method of manufacturing polyalkyl methacrylate macromonomers, and use of same in the manufacture of comb polymers 失效
    制备聚甲基丙烯酸烷基酯大分子单体的方法，以及在制造梳形聚合物中的用途

    公开(公告)号：US5254632A

    公开(公告)日：1993-10-19

    申请号：US907560

    申请日：1992-07-02

    申请人： Volker Kerscher ,  Werner Siol

    发明人： Volker Kerscher ,  Werner Siol

    IPC分类号： C08F8/14 ,  C08F290/00 ,  C08F290/04 ,  C08F299/00 ,  C08F265/04 ,  C08F18/00

    CPC分类号： C08F290/046 ,  C08F8/14

    摘要： A macronomer of Formula I: ##STR1## wherein R.sub.1 is hydrogen or methyl, X is a biradical, R.sub.2 is an alkyl group of 1-40 carbon atoms and n is such that the molecular weight of the macromonomer ranges from 500-100,000 Dalton is prepared by transesterifying a monomeric ester of Formula II ##STR2## where R.sub.3 represents an alkyl group with 1-8 C atoms, with a hydroxyl-group-terminated polyalkyl methacrylate of Formula III ##STR3## where X and R.sub.2 have the same meanings as above, andn'=n;with the elimination of alcohol HOR.sub.3, thereby resulting in formation of the compound of Formula I.

    摘要翻译： 式I的大分子单体：其中R 1是氢或甲基，X是双原子，R 2是1-40个碳原子的烷基，n是这样大分子单体的分子量在500-100,000道尔顿 通过将式II的单体酯（其中R 3表示具有1-8个C原子的烷基）与式III的羟基封端的聚烷基甲基丙烯酸酯III交酯交换而制备，其中X和R 2具有相同 含义如上，n'= n; 消除醇HOR3，从而形成式I化合物。

    PROCESS FOR PREPARING (METH)ACRYLATES
    3.
    发明申请
    PROCESS FOR PREPARING (METH)ACRYLATES 有权
    制备（甲基）丙烯酸酯的方法

    公开(公告)号：US20100280205A1

    公开(公告)日：2010-11-04

    申请号：US12745703

    申请日：2008-09-29

    申请人： Joachim Knebel ,  Ralf Merbach ,  Guido Protzmann ,  Klaus Gottmann ,  John Hirsh ,  Gerold Schmitt ,  Dieter Tessmer ,  Wilhelm Karnbrock ,  Wolfgang Klesse ,  Volker Kerscher

    发明人： Joachim Knebel ,  Ralf Merbach ,  Guido Protzmann ,  Klaus Gottmann ,  John Hirsh ,  Gerold Schmitt ,  Dieter Tessmer ,  Wilhelm Karnbrock ,  Wolfgang Klesse ,  Volker Kerscher

    IPC分类号： C08F120/12 ,  C07C69/54

    CPC分类号： C07C67/03 ,  C08F20/18 ,  C08F120/12 ,  C07C69/54

    摘要： Process for preparing (meth)acrylates of the formula (I) CH2═C(R1)—CO—O—R2   (I) in which R1 is hydrogen or methyl and R2 is a saturated or unsaturated, linear or branched, aliphatic or cyclic alkyl radical having 6 to 22 carbon atoms, or a (C6-C14)-aryl-(C1-C8)-alkyl radical; by reacting a (meth)acrylate of the formula II CH2═C(R1)—CO—OR3   (II) with an alcohol of the formula (III) HO—R2   (III) in the presence of an amount of a suitable catalyst which catalyses the reaction and of an amount of a phenolic polymerization inhibitor or a combination of two or more phenolic polymerization inhibitors which is sufficient to inhibit undesired polymerization; the reaction being undertaken with input or introduction into the reaction mixture resulting from the reaction of an amount of oxygen or of an oxygenous gas mixture sufficient to inhibit undesired polymerization, and the process is characterized in that the specific total oxygen input is less than or equal to 1.0 l/kg, measured in litres of oxygen per kilogram of (meth)acrylate of the formula (I), where the volume of oxygen introduced is calculated at a temperature of 25° C. and a pressure of 101 325 pascal. The resulting (meth)acrylates can surprisingly be processed to particularly high molecular weight emulsion polymers which are, for example, outstandingly suitable for use as flow resistance reducers in mineral oil extraction.

    摘要翻译： 制备式（I）的（甲基）丙烯酸酯的方法，其中R 1是氢或甲基，R 2是饱和或不饱和的，直链或支链的脂族或环状的 具有6至22个碳原子的烷基或（C 6 -C 14） - 芳基 - （C 1 -C 8） - 烷基; 通过使式II CH 2 = C（R 1）-CO-OR 3（II）的（甲基）丙烯酸酯与式（III）的醇HO-R 2（III）在一定量的合适的催化剂存在下反应， 催化反应和一定量的酚聚合抑制剂或两种或多种酚聚合抑制剂的组合，其足以抑制不期望的聚合; 反应是通过输入或引入反应混合物中进行的，所述反应混合物是由一定量的氧气或足够抑制不期望的聚合的氧气混合物的反应而产生的，并且该方法的特征在于特定的总氧气输入量小于或等于 至1.0l / kg，以公斤式（I）的（甲基）丙烯酸酯计，氧气的导入量在25℃，压力为101 325帕斯卡时计算。 所得到的（甲基）丙烯酸酯可以令人惊奇地加工成特别高分子量的乳液聚合物，例如非常适合用作矿物油提取中的阻流剂。

    METHOD OF RECOVERING IMPREGNATING AGENT COMPOSITIONS
    4.
    发明申请
    METHOD OF RECOVERING IMPREGNATING AGENT COMPOSITIONS 审中-公开
    恢复印染剂组合物的方法

    公开(公告)号：US20100252069A1

    公开(公告)日：2010-10-07

    申请号：US12677546

    申请日：2008-08-15

    申请人： Reinhold Martin ,  Volker Kerscher ,  Franziska Draeger

    发明人： Reinhold Martin ,  Volker Kerscher ,  Franziska Draeger

    IPC分类号： C23G1/00

    CPC分类号： B08B3/14 ,  B08B3/08 ,  C11D3/06 ,  C23G1/24 ,  C23G1/36

    摘要： The present invention relates to processes for recovering impregnating compositions, the impregnated metal part being brought into contact with a salt-containing cleaning composition which comprises at least 0.7% by weight of at least one salt.In addition, the present invention describes processes for impregnating metal parts, which have at least one step for recovering impregnating compositions.

    摘要翻译： 本发明涉及用于回收浸渍组合物的方法，所述浸渍的金属部分与包含至少0.7重量％的至少一种盐的含盐清洁组合物接触。 此外，本发明描述了浸渍金属部件的方法，其具有用于回收浸渍组合物的至少一个步骤。

    Monomer-polymer systems with a controllable pot life
    5.
    发明申请
    Monomer-polymer systems with a controllable pot life 审中-公开
    具有可控适用期的单体 - 聚合物体系

    公开(公告)号：US20060293451A1

    公开(公告)日：2006-12-28

    申请号：US10564355

    申请日：2004-05-28

    申请人： Gerold Schmitt ,  Thomas Sufke ,  Volker Kerscher

    发明人： Gerold Schmitt ,  Thomas Sufke ,  Volker Kerscher

    IPC分类号： C08F8/00

    CPC分类号： C09D4/06 ,  C09J4/06

    摘要： The invention relates to a dual component system with a controllable pot life. Said system can be hardened by a redox initiator system and comprises an emulsion polymer or a plurality of emulsion polymers and an ethylenically unsaturated monomer or a monomer mixture made from ethylenically unsaturated monomers. The emulsion polymer as well as the monomer or the monomer mixture can contain one of the components of a redox initiator system. Pot life is controlled by absorption of the redox initiator system on the polymer (A and B).

    摘要翻译： 本发明涉及一种具有可控寿命的双组分系统。 所述系统可以通过氧化还原引发剂体系硬化，并且包括乳液聚合物或多种乳液聚合物和烯属不饱和单体或由烯属不饱和单体制成的单体混合物。 乳液聚合物以及单体或单体混合物可以含有氧化还原引发剂体系的组分之一。 使用寿命由聚合物（A和B）上的氧化还原引发剂体系的吸收控制。

    Highly transparent plastic for optical materials
    6.
    发明授权
    Highly transparent plastic for optical materials 失效
    用于光学材料的高透明塑料

    公开(公告)号：US07144954B2

    公开(公告)日：2006-12-05

    申请号：US10529478

    申请日：2003-09-13

    申请人： Bardo Schmitt ,  Wolfgang Klesse ,  Volker Kerscher ,  Patrik Hartmann

    发明人： Bardo Schmitt ,  Wolfgang Klesse ,  Volker Kerscher ,  Patrik Hartmann

    IPC分类号： C08J3/00 ,  C08K3/20 ,  C08L75/00 ,  C08F18/08 ,  C08G8/30

    CPC分类号： C08G18/8175 ,  C08F222/1006 ,  C08G18/3876 ,  C08G18/73

    摘要： The present invention relates to mixtures containing A) compounds of the formula (I) and (II) where R1 is independently at each instance hydrogen or a methyl radical, R2 is independently at each instance a linear or branched, aliphatic or cycloaliphatic radical or a substituted or unsubstituted aromatic or heteroaromatic radical and m and n are each independently an integer of not less than 0 subject to the proviso that m+n>0, and B) at least one ethylenically unsaturated monomer (A) which is different from the compounds of the formula (I) and (II). The present invention further relates to processes for polymerizing these mixtures, the highly transparent polymers thus obtainable and to their use.

    摘要翻译： 本发明涉及含有A）式（I）和（II）化合物的混合物，其中R 1各自独立地为氢或甲基，R 2， 在每种情况下独立地为直链或支链的脂族或脂环族基团或取代或未取代的芳族或杂芳族基团，m和n各自独立地为不小于0的整数，条件是m + n> 0，B ）与式（I）和（II）的化合物不同的至少一种烯属不饱和单体（A）。 本发明还涉及使这些混合物聚合的方法，由此获得的高度透明的聚合物及其用途。

    High refractive index plastic base on an alkylthiol and an alkylpolythiol ester
    8.
    发明授权
    High refractive index plastic base on an alkylthiol and an alkylpolythiol ester 失效
    基于烷基硫醇和烷基硫醇酯的高折射率塑料

    公开(公告)号：US5422422A

    公开(公告)日：1995-06-06

    申请号：US134736

    申请日：1993-10-12

    申请人： Martina Bader ,  Volker Kerscher

    发明人： Martina Bader ,  Volker Kerscher

    IPC分类号： C08F220/38 ,  C08F20/38 ,  G02B1/04 ,  C08G75/04 ,  C08F228/00

    CPC分类号： C08F20/38

    摘要： The invention relates to a high refractive index plastic produced by reaction of an alkylthiol with a multiply unsaturated monomer, wherein said alkylthiol (A) has at least 2, and up to 20 carbon atoms in the alkyl group, and contains at least 2 thiol groups in the molecule, is reacted with an alkylpolythiol ester (B) having at least 2, and up to 24, preferably up to 12, carbon atoms in the alkyl group, which ester contains at least 2 thiol groups esterified with (meth)acrylic acid in the molecule, said reaction being under conditions of radical polymerization, with the limitation that the numerical ratio of the mercapto groups to the available double bonds is .ltoreq.1, preferably

    摘要翻译： 本发明涉及通过烷基硫醇与多不饱和单体的反应产生的高折射率塑料，其中所述烷基硫醇（A）在烷基中具有至少2个和至多20个碳原子，并且含有至少2个硫醇基 在分子中与烷基中具有至少2个，最多24个，优选至多12个碳原子的烷基多硫醇酯（B）反应，该酯含有至少2个（甲基）丙烯酸酯化的硫醇基 在分子中，所述反应在自由基聚合的条件下，限制在于巯基与可用双键的数值比为1，优选<0.5。

    Process for preparing (meth)acrylates
    9.
    发明授权
    Process for preparing (meth)acrylates 有权
    （甲基）丙烯酸酯的制备方法

    公开(公告)号：US09206270B2

    公开(公告)日：2015-12-08

    申请号：US12745703

    申请日：2008-09-29

    申请人： Joachim Knebel ,  Ralf Merbach ,  Guido Protzmann ,  Klaus Gottmann ,  John Hirsh ,  Gerold Schmitt ,  Dieter Tessmer ,  Wilhelm Karnbrock ,  Wolfgang Klesse ,  Volker Kerscher

    发明人： Joachim Knebel ,  Ralf Merbach ,  Guido Protzmann ,  Klaus Gottmann ,  John Hirsh ,  Gerold Schmitt ,  Dieter Tessmer ,  Wilhelm Karnbrock ,  Wolfgang Klesse ,  Volker Kerscher

    IPC分类号： C08F118/02 ,  C07C69/52 ,  C08F20/18 ,  C07C67/03 ,  C08F120/12

    CPC分类号： C07C67/03 ,  C08F20/18 ,  C08F120/12 ,  C07C69/54

    摘要： Process for preparing (meth)acrylates of the formula (I) CH2═C(R1)—CO—O—R2  (I) in which R1 is hydrogen or methyl and R2 is a saturated or unsaturated, linear or branched, aliphatic or cyclic alkyl radical having 6 to 22 carbon atoms, or a (C6-C14)-aryl-(C1-C8)-alkyl radical; by reacting a (meth)acrylate of the formula II CH2═C(R1)—CO—OR3  (II) with an alcohol of the formula (III) HO—R2  (III) in the presence of an amount of a suitable catalyst which catalyzes the reaction and of an amount of a phenolic polymerization inhibitor or a combination of two or more phenolic polymerization inhibitors which is sufficient to inhibit undesired polymerization; the reaction being undertaken with input or introduction into the reaction mixture resulting from the reaction of an amount of oxygen or of an oxygenous gas mixture sufficient to inhibit undesired polymerization, and the process is characterized in that the specific total oxygen input is less than or equal to 1.0 l/kg, measured in liters of oxygen per kilogram of (meth)acrylate of the formula (I), where the volume of oxygen introduced is calculated at a temperature of 25° C. and a pressure of 101 325 pascal. The resulting (meth)acrylates can surprisingly be processed to particularly high molecular weight emulsion polymers which are, for example, outstandingly suitable for use as flow resistance reducers in mineral oil extraction.

    摘要翻译： 制备式（I）的（甲基）丙烯酸酯的方法，其中R 1是氢或甲基，R 2是饱和或不饱和的，直链或支链的脂族或环状的 具有6-22个碳原子的烷基或（C 6 -C 14） - 芳基 - （C 1 -C 8） - 烷基; 通过使式II CH 2 = C（R 1）-CO-OR 3（II）的（甲基）丙烯酸酯与式（III）的醇HO-R 2（III）在一定量的合适的催化剂存在下反应， 催化反应和一定量的酚聚合抑制剂或两种或多种酚类聚合抑制剂的组合，其足以抑制不期望的聚合; 反应是通过输入或引入反应混合物中进行的，所述反应混合物是由一定量的氧气或足够抑制不期望的聚合的氧气混合物的反应而产生的，并且该方法的特征在于，具体的总氧气输入量小于或等于 至1.0l / kg，以公斤式（I）的（甲基）丙烯酸酯计，氧气的导入量在25℃，压力为101 325帕斯卡时计算。 所得到的（甲基）丙烯酸酯可以令人惊奇地加工成特别高分子量的乳液聚合物，例如非常适合用作矿物油提取中的阻流剂。