公开(公告)号：US5773635A

公开(公告)日：1998-06-30

申请号：US498840

申请日：1995-07-06

申请人： Walter Dobler ,  Wolfgang Krause ,  Joachim Paust ,  Otto Worz ,  Udo Rheude ,  Wolfram Burst ,  Gunter Dauwel ,  Armin Bertram ,  Bernhard Schulz ,  Gunter Wegner ,  Peter Munster ,  Hansgeorg Ernst ,  Arno Kochner ,  Heinz Etzrodt

发明人： Walter Dobler ,  Wolfgang Krause ,  Joachim Paust ,  Otto Worz ,  Udo Rheude ,  Wolfram Burst ,  Gunter Dauwel ,  Armin Bertram ,  Bernhard Schulz ,  Gunter Wegner ,  Peter Munster ,  Hansgeorg Ernst ,  Arno Kochner ,  Heinz Etzrodt

IPC分类号： C07C51/16 ,  C07C403/00 ,  C07C403/20

CPC分类号： C07C403/20 ,  C07C403/16 ,  C07B2200/09 ,  C07C2101/16

摘要： A process for preparing polyenecarbonyl compounds having a high all-E content and their acetals or ketals by aldol condensation or Horner-Emmons reaction comprises carrying out the reaction, for the purposes of the preferred formation of a double bond of E configuration and in order to maintain the E configuration of the double bonds in the stating compounds as completely as possible, in the presence of oxygen or an oxygen-inert gas mixture or nitric oxide or a nitric oxide-inert gas mixture and/or in the presence of specific stable radicals and/or in the presence of quinones or quinone derivatives.

摘要翻译： 通过醛醇缩合或霍纳 - 埃蒙斯反应制备具有高全E含量的多元羰基化合物及其缩醛或缩酮的方法包括进行反应，为了优选形成E构型的双键，为了 在氧气或氧惰性气体混合物或一氧化氮或一氧化氮惰性气体混合物的存在下和/或在特定的稳定基团的存在下，尽可能地完全地保持化合物中双键的E构型 和/或在醌或醌衍生物的存在下。

公开(公告)号：US6013843A

公开(公告)日：2000-01-11

申请号：US85836

申请日：1998-05-28

申请人： Werner Aquila ,  Hartwig Fuchs ,  Otto Worz ,  Wilhelm Ruppel ,  Klaus Halbritter

发明人： Werner Aquila ,  Hartwig Fuchs ,  Otto Worz ,  Wilhelm Ruppel ,  Klaus Halbritter

IPC分类号： B01J23/52 ,  B01J8/02 ,  B01J8/08 ,  C07B61/00 ,  C07C45/38 ,  C07C45/67 ,  C07C47/21 ,  C07C47/22 ,  C07C45/00

CPC分类号： C07C45/38 ,  B01J8/0242 ,  B01J8/087 ,  C07C45/67 ,  B01J2208/00212

摘要： A process for continuous industrial production of unsaturated aliphatic aldehydes having a boiling range from 95 to 136.degree. C. by oxidative dehydrogenation of the corresponding alcohols with an oxygen-comprising gas over a supported catalyst consisting of copper, silver and/or gold on an inert support in a tube bundle reactor, rapid cooling of the reaction gases and removal of the aldehydes from the resulting condensate with recycling of the unconverted alcohols comprisesa) vaporizing the alcohol,b) admixing the alcohol vapor with an oxygen-comprising gas,c) initially passing the resulting oxygen-comprising alcohol vapor at above the dew point of the alcohol but below the commencement temperature of the reaction through a layer of one of the abovementioned supported catalysts which is at least 0.5 cm in thickness and only thend) reacting the oxygen-comprising alcohol vapor at from 300 to 600.degree. C. in a sufficient number, for the desired capacity, of parallel reaction tubes surrounded by a fluidic heat transfer medium, packed with the supported catalyst and having an internal diameter D of from about 0.5 to 3 cm and a length of at least 5 cm, to form the corresponding aldehyde.

摘要翻译： 通过相对应的醇与含氧气体在由铜，银和/或金组成的负载型催化剂上惰性惰性的连续工业生产不饱和脂族醛的方法，其沸程为95至136℃ 在管束反应器中的支撑，反应气体的快速冷却以及未转化的醇的再循环从所得冷凝物中除去醛包括a）蒸发醇，b）将醇蒸气与含氧气体混合，c） 首先将所得的含氧醇醇蒸气在醇的露点以上但低于反应开始温度的上述负载型催化剂层中的至少0.5cm厚度，然后d）使 含氧的醇蒸气在300-600℃下以足够的数量容纳所需的并联反应管 由流体传热介质引入，填充有负载的催化剂并且具有约0.5至3cm的内径D和至少5cm的长度以形成相应的醛。