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1.发明授权公开(公告)号：US06982514B1
公开(公告)日：2006-01-03
申请号：US09863808
申请日：2001-05-22
CPC分类号： F03G7/005 , H01B1/127 , H01B1/128 , H02N11/006 , Y10S310/80
摘要： The present invention includes the preparation of highly conducting conjugated polymers and their use as electrochemical actuators, A typical electrochemical actuator comprises a highly conducting, conjugated polymer for the anode or the cathode, or for both the anode and the cathode; suitable conjugate polymers have a conductivity ≧100 S/cm. The material may have any form, including films and fibers. A preferred shape is a strip or a fiber, where the fiber can be solid or hollow, although any shape may be used. Before use, the material may be treated, for example, by immersion in an acid, in order to dope/protonate the material or to introduce anions or to exchange the anion in the polymer for another anion. Other materials may be incorporated in the polyaniline to increase its conductivity or to provide other benefits, such as increased strength. Useful conducting polymers include monomers of anilines, pyrroles, thiophenes, phenylene vinylenes, and derivatives thereof.
摘要翻译： 本发明包括制备高导电性共轭聚合物及其作为电化学致动器的用途。典型的电化学致动器包括用于阳极或阴极或阳极和阴极的高导电共轭聚合物; 合适的共轭聚合物的导电率> 100S / cm。 该材料可以具有任何形式，包括膜和纤维。 优选的形状是条或纤维，其中纤维可以是固体或中空的，尽管可以使用任何形状。 在使用之前，可以例如通过浸入酸中来处理材料，以便掺杂或质子化材料或引入阴离子或交换聚合物中的阴离子用于另一种阴离子。 可以将其它材料引入聚苯胺中以增加其导电性或提供其它益处，例如增加的强度。 有用的导电聚合物包括苯胺，吡咯，噻吩，亚苯基乙烯基单体及其衍生物。
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公开(公告)号：US07288871B1
公开(公告)日：2007-10-30
申请号：US10886001
申请日：2004-07-06
CPC分类号： H02N11/006 , Y10T428/2929 , Y10T428/2933 , Y10T428/2965
摘要： A linear electrochemical actuator is described where at least one electrically conductive (between 400 and 1000 S/cm), doped polyaniline solid fiber or a yarn produced from such fibers is disposed in an electrolyte inside of a electrically conductive polyaniline hollow fiber, thereby allowing 2-electrode operation without a metal backing. This is an example of the electrochemical devices of the present invention having a solid-in-hollow polymer fiber configuration. In a propylene carbonate electrolyte, the electrochemical and actuation behavior of the fibers was found to be influenced by the solubility and size of the polymer dopants. That is, solubility of the dopant in the electrolyte resulted in high electroactivity and strain in the fibers. Actuation of fibers was also affected by electrolyte anions, small anions resulting in anion-exchange dominated actuation, while large anions resulted in cation-exchange dominated actuation. Isotonic strains of 0.9% and isometric stresses of 0.9 MPa were realized for the solid-in-hollow polyaniline fiber actuators.
摘要翻译： 描述了线性电化学致动器，其中至少一种导电（在400和1000S / cm）掺杂的聚苯胺固体纤维或由这种纤维产生的纱线设置在导电聚苯胺中空纤维内部的电解质中，从而允许2 - 没有金属背衬的电极操作。 这是具有中空聚合物纤维结构的本发明的电化学装置的实例。 在碳酸亚丙酯电解质中，发现纤维的电化学和致动性受聚合物掺杂剂的溶解度和尺寸的影响。 也就是说，掺杂剂在电解质中的溶解度导致纤维中的高电活性和应变。 纤维的致动也受到电解质阴离子的影响，小的阴离子导致阴离子交换主导致动，而大的阴离子导致阳离子交换主导致动。 对于固体中空聚苯胺纤维致动器，实现了0.9％的等渗应变和0.9MPa的等长应力。
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3.发明申请公开(公告)号：US20060169954A1
公开(公告)日：2006-08-03
申请号：US11208024
申请日：2005-08-19
申请人： Elisabeth Smela , Benjamin Mattes , Philip Adams , Guido Zuccarello , Wen Lu
发明人： Elisabeth Smela , Benjamin Mattes , Philip Adams , Guido Zuccarello , Wen Lu
IPC分类号： H01B1/12
CPC分类号： F03G7/005 , H01B1/127 , H01B1/128 , H02N11/006 , Y10S310/80
摘要： The present invention includes the preparation of highly conducting conjugated polymers and their use as electrochemical actuators. A typical electrochemical actuator comprises a highly conducting, conjugated polymer for the anode or the cathode, or for both the anode and the cathode; suitable conjugate polymers have a conductivity ≧100 S/cm. The material may have any form, including films and fibers. A preferred shape is a strip or a fiber, where the fiber can be solid or hollow, although any shape may be used. Before use, the material may be treated, for example, by immersion in an acid, in order to dope/protonate the material or to introduce anions or to exchange the anion in the polymer for another anion. Other materials may be incorporated in the polyaniline to increase its conductivity or to provide other benefits, such as increased strength. Useful conducting polymers include monomers of anilines, pyrroles, thiophenes, phenylene vinylenes, and derivatives thereof.
摘要翻译： 本发明包括制备高导电共轭聚合物及其作为电化学致动器的用途。 典型的电化学致动器包括用于阳极或阴极或用于阳极和阴极的高导电共轭聚合物; 合适的共轭聚合物的导电率> 100S / cm。 该材料可以具有任何形式，包括膜和纤维。 优选的形状是条或纤维，其中纤维可以是固体或中空的，尽管可以使用任何形状。 在使用之前，可以例如通过浸入酸中来处理材料，以便掺杂或质子化材料或引入阴离子或交换聚合物中的阴离子用于另一种阴离子。 可以将其它材料引入聚苯胺中以增加其导电性或提供其它益处，例如增加的强度。 有用的导电聚合物包括苯胺，吡咯，噻吩，亚苯基乙烯基单体及其衍生物。
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公开(公告)号：US20070249803A1
公开(公告)日：2007-10-25
申请号：US11568507
申请日：2004-04-28
IPC分类号： C08G73/00
CPC分类号： C08G73/0266
摘要： Methods are described for preparing substantially defect-free, adjustable molecular-weight, aniline-based polymers at sub-freezing temperatures in the absence of salts effective for lowering the freezing point of the reacting solutions, and in the absence of inorganic acids containing chlorine atoms.
摘要翻译： 描述了在不存在有效降低反应溶液的凝固点的盐的情况下以及在不存在含有氯原子的无机酸的情况下，在亚冰点温度下制备基本上无缺陷的，可调节分子量的苯胺基聚合物的方法 。
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