公开(公告)号：US06923949B1

公开(公告)日：2005-08-02

申请号：US10795108

申请日：2004-03-05

申请人： Wenyih F. Lai ,  Richard B. Saunders ,  Machteld M. Mertens ,  Johannes P. Verduijn

发明人： Wenyih F. Lai ,  Richard B. Saunders ,  Machteld M. Mertens ,  Johannes P. Verduijn

IPC分类号： C01B33/36 ,  C01B39/00 ,  C01B39/48 ,  C01F7/00

CPC分类号： C01B39/48

摘要： Pure phase, high activity ZSM-48 crystals having a SiO2/Al2O3 ratio of less than about 150/1, substantially free from ZSM-50 and Kenyaite, and fibrous morphology crystals. The crystals may further have a specific cross morphology. A method for making such crystals using heterostructural, zeolite seeds, other than ZSM-48 and ZSM-50 seeds.

摘要翻译： 具有小于约150/1的纯相，高活性的ZSM-48晶体，其基本上为无定形的，优选的是SiO 2 / 来自ZSM-50和肯尼亚，以及纤维形态晶体。 晶体还可以具有特定的交叉形态。 使用除ZSM-48和ZSM-50种子以外的异质结构沸石种子制造这种晶体的方法。

公开(公告)号：US20110118520A1

公开(公告)日：2011-05-19

申请号：US12590952

申请日：2009-11-17

申请人： Frank Lai ,  Richard B. Saunders ,  Kathy Saunders

发明人： Frank Lai ,  Richard B. Saunders ,  Kathy Saunders

IPC分类号： C07C15/08 ,  B01J29/06

CPC分类号： C01B39/42 ,  B01J29/7034 ,  C07C6/126 ,  Y02P20/52 ,  Y10S423/33 ,  C07C15/08

摘要： A porous, crystalline material is described having the framework structure of ZSM-12 and a composition involving the molar relationship: X2O3:(n)YO2 wherein X is a trivalent element, Y is a tetravalent element and n is less than about 45, e.g., less than about 40, wherein the average crystal size of the material is less than about 0.1 micron, which material is substantially free of impurities. The material is made by: (a) preparing a mixture capable of forming said material, said mixture comprising sources of alkali or alkaline earth metal (M), an oxide of trivalent element (X), an oxide of tetravalent element (Y), hydroxyl (OH−) ions, water, and an organic monoquaternary ammonium cation directing agent (R) and an organic diquaternary ammonium structure blocking agent (R′); (b) maintaining the mixture under sufficient conditions until crystals of said material are formed; and (c) recovering the crystalline material from step (ii). The material can be used as a hydrocarbon conversion process catalyst.

摘要翻译： 描述了具有ZSM-12的骨架结构和涉及摩尔关系的组成的多孔结晶材料：X 2 O 3：（n）YO 2其中X是三价元素，Y是四价元素，n小于约45，例如 小于约40，其中材料的平均晶体尺寸小于约0.1微米，该材料基本上不含杂质。 该材料通过以下制备：（a）制备能够形成所述材料的混合物，所述混合物包含碱金属或碱土金属（M），三价元素（X）的氧化物，四价元素（Y）的氧化物， 羟基（OH-）离子，水和有机单季铵阳离子导向剂（R）和有机二季铵结构封闭剂（R'）; （b）将混合物保持在足够的条件下，直到形成所述材料的晶体; 和（c）从步骤（ii）中回收结晶物质。 该材料可用作烃转化工艺催化剂。

公开(公告)号：US08202506B2

公开(公告)日：2012-06-19

申请号：US12590952

申请日：2009-11-17

申请人： Frank Lai ,  Richard B. Saunders ,  Kathy Saunders, legal representative

发明人： Frank Lai ,  Richard B. Saunders

IPC分类号： C01B39/04

CPC分类号： C01B39/42 ,  B01J29/7034 ,  C07C6/126 ,  Y02P20/52 ,  Y10S423/33 ,  C07C15/08

摘要： A porous, crystalline material is described having the framework structure of ZSM-12 and a composition involving the molar relationship: X2O3:(n)YO2 wherein X is a trivalent element, Y is a tetravalent element and n is less than about 45, e.g., less than about 40, wherein the average crystal size of the material is less than about 0.1 micron, which material is substantially free of impurities. The material is made by: (a) preparing a mixture capable of forming said material, said mixture comprising sources of alkali or alkaline earth metal (M), an oxide of trivalent element (X), an oxide of tetravalent element (Y), hydroxyl (OH−) ions, water, and an organic monoquaternary ammonium cation directing agent (R) and an organic diquaternary ammonium structure blocking agent (R′); (b) maintaining the mixture under sufficient conditions until crystals of said material are formed; and (c) recovering the crystalline material from step (ii). The material can be used as a hydrocarbon conversion process catalyst.

摘要翻译： 描述了具有ZSM-12的骨架结构和涉及摩尔关系的组成的多孔结晶材料：X 2 O 3：（n）YO 2其中X是三价元素，Y是四价元素，n小于约45，例如 小于约40，其中材料的平均晶体尺寸小于约0.1微米，该材料基本上不含杂质。 该材料通过以下制备：（a）制备能够形成所述材料的混合物，所述混合物包含碱金属或碱土金属（M），三价元素（X）的氧化物，四价元素（Y）的氧化物， 羟基（OH-）离子，水和有机单季铵阳离子导向剂（R）和有机二季铵结构封闭剂（R'）; （b）将混合物保持在足够的条件下，直到形成所述材料的晶体; 和（c）从步骤（ii）中回收结晶物质。 该材料可用作烃转化工艺催化剂。