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1.发明授权Synthesis of ZSM-48 crystals with heterostructural, non ZSM-48, seeding 有权合成具有异质结构，非ZSM-48的ZSM-48晶体，接种公开(公告)号：US06923949B1
公开(公告)日：2005-08-02
申请号：US10795108
申请日：2004-03-05
CPC分类号： C01B39/48
摘要： Pure phase, high activity ZSM-48 crystals having a SiO2/Al2O3 ratio of less than about 150/1, substantially free from ZSM-50 and Kenyaite, and fibrous morphology crystals. The crystals may further have a specific cross morphology. A method for making such crystals using heterostructural, zeolite seeds, other than ZSM-48 and ZSM-50 seeds.
摘要翻译： 具有小于约150/1的纯相，高活性的ZSM-48晶体，其基本上为无定形的，优选的是SiO 2 / 来自ZSM-50和肯尼亚，以及纤维形态晶体。 晶体还可以具有特定的交叉形态。 使用除ZSM-48和ZSM-50种子以外的异质结构沸石种子制造这种晶体的方法。
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公开(公告)号：US08617383B2
公开(公告)日：2013-12-31
申请号：US13169616
申请日：2011-06-27
申请人： Krista Marie Prentice , Michel Daage , Ajit Bhaskar Dandekar , Christopher Gordon Oliveri , Rohit Vijay , Stephen J. McCarthy , Wenyih F. Lai , Bradley R. Fingland
发明人： Krista Marie Prentice , Michel Daage , Ajit Bhaskar Dandekar , Christopher Gordon Oliveri , Rohit Vijay , Stephen J. McCarthy , Wenyih F. Lai , Bradley R. Fingland
CPC分类号： C10G65/043 , C10G45/06 , C10G45/08 , C10G45/44 , C10G45/52 , C10G45/58 , C10G45/62 , C10G45/64 , C10G47/16 , C10G47/18 , C10G65/046 , C10G65/12 , C10G69/02 , C10G2300/202 , C10G2300/302 , C10G2300/4018 , C10G2300/4081 , C10G2400/02 , C10G2400/04 , C10G2400/10
摘要： An integrated process for producing naphtha fuel, diesel fuel and/or lubricant base oils from feedstocks under sour conditions is provided. The ability to process feedstocks under higher sulfur and/or nitrogen conditions allows for reduced cost processing and increases the flexibility in selecting a suitable feedstock. The sour feed can be delivered to a catalytic dewaxing step without any separation of sulfur and nitrogen contaminants, or with only a high pressure separation so that the dewaxing still occurs under sour conditions. Various combinations of hydrotreating, catalytic dewaxing, hydrocracking, and hydrofinishing can be used to produce fuel products and lubricant base oil products.
摘要翻译： 提供了一种在酸性条件下从原料生产石脑油燃料，柴油和/或润滑油基础油的综合方法。 在更高硫和/或氮条件下处理原料的能力允许降低成本处理并增加选择合适原料的灵活性。 酸进料可以被输送到催化脱蜡步骤，而没有硫和氮污染物的任何分离，或者只有高压分离，使得在酸性条件下仍然发生脱蜡。 可以使用加氢处理，催化脱蜡，加氢裂化和加氢精加工的各种组合来生产燃料产品和润滑油基础油产品。
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公开(公告)号：US08500991B2
公开(公告)日：2013-08-06
申请号：US12653038
申请日：2009-12-08
申请人： Wenyih F. Lai , Christine N. Elia
发明人： Wenyih F. Lai , Christine N. Elia
CPC分类号： C10G45/64 , B01J29/70 , B01J29/74 , B01J37/0009 , B01J2229/20 , B01J2229/42 , C01B39/065 , C01B39/48
摘要： A process is described of producing an MTT framework type molecular sieve by crystallizing a mixture capable of forming said molecular sieve, wherein the mixture comprises sources of alkali or alkaline earth metal (M), an oxide of trivalent element (X), an oxide of tetravalent element (Y), water and a directing agent (R) of the formula (CH3)3N+CH2CH2CH2N+(CH3)2CH2CH2CH2N+(CH3)3, and has a composition, in terms of mole ratios, within the following ranges. YO2/X2O3less than 45 H2O/YO25 to 100 OH−/YO20.05 to 0.5 M/YO20.05 to 0.5 and R/YO2>0 to
摘要翻译： 描述了通过使能够形成所述分子筛的混合物结晶来生产MTT框架型分子筛的方法，其中所述混合物包含碱金属或碱土金属（M）的源，三价元素（X）的氧化物， 四价元素（Y），水和式（CH 3）3 N + CH 2 CH 2 CH 2 N +（CH 3）2 CH 2 CH 2 CH 2 N +（CH 3）3的定向剂（R），并且以摩尔比计含有以下范围内的组成。 YO2 / X2O3小于45H2O / YO2 5至100 OH- / YO2 0.05至0.5M / YO2 0.05至0.5，R / YO2> 0至<0.5。
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4.发明授权Noble metal-containing catalyst containing a specific ratio of silica to aluminum in the framework 有权在框架中含有特定比例的二氧化硅与铝的贵金属催化剂公开(公告)号：US07538065B2
公开(公告)日：2009-05-26
申请号：US11205604
申请日：2005-08-17
CPC分类号： B01J29/0325 , B01J29/043 , B01J37/0009 , B01J2229/20 , B01J2229/42 , C10G49/08
摘要： An improved noble metal-containing catalyst containing a specific ratio of silica to aluminum in the framework suitable for use in the hydroprocessing of hydrocarbonaceous feeds, which is directed at a catalyst comprising a hydrogenation-dehydrogenation component selected from the Group VIII noble metals and mixtures thereof on a mesoporous support having aluminum incorporated into its framework and an average pore diameter of about 15 to less than about 40 Å.
摘要翻译： 在适用于烃类进料的加氢处理的框架中，含有二氧化硅与铝的特定比例的改进的含贵金属的催化剂，其包含选自第VIII族贵金属的氢化脱氢组分及其混合物 在具有结合到其骨架中的铝并且平均孔径为约15至小于约的介孔载体上。
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公开(公告)号：US20110192766A1
公开(公告)日：2011-08-11
申请号：US13021835
申请日：2011-02-07
IPC分类号： C10G11/05 , B01J29/06 , B01J29/40 , B01J29/068
CPC分类号： B01J35/002 , B01J21/063 , B01J29/40 , B01J29/65 , B01J29/70 , B01J29/7023 , B01J29/703 , B01J29/7038 , B01J29/7046 , B01J29/7461 , B01J35/023 , B01J35/026 , B01J35/1019 , B01J35/1061 , B01J37/0009 , B01J37/04 , B01J2229/42 , C10G45/62 , C10G45/64 , C10G2300/4018
摘要： A supported catalyst comprises a zeolite having a silica to alumina molar ratio of 500 or less, a first metal oxide binder having a crystallite size greater than 200 Å and a second metal oxide binder having a crystallite size less than 100 Å, wherein the second metal oxide binder is present in an amount less than 15 wt % of the total weight of the catalyst.
摘要翻译： 载体催化剂包括二氧化硅与氧化铝的摩尔比为500以下的沸石，微晶尺寸大于的第一金属氧化物粘合剂和微晶尺寸小于的第二金属氧化物粘合剂，其中第二金属 氧化物粘合剂的存在量小于催化剂总重量的15重量％。
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公开(公告)号：US20100187156A1
公开(公告)日：2010-07-29
申请号：US12655120
申请日：2009-12-23
申请人： Krista Marie Prentice , Gary Paul Schleicher , Lei Zhang , Timothy Lee Hilbert , Michel A. Daage , Sylvain Hantzer , Wenyih F. Lai , David Mentzer , William Francis Heaney , Christine Nicole Elia , Shifang Luo , Stephen J. McCarthy , Mohan Kalyanaraman
发明人： Krista Marie Prentice , Gary Paul Schleicher , Lei Zhang , Timothy Lee Hilbert , Michel A. Daage , Sylvain Hantzer , Wenyih F. Lai , David Mentzer , William Francis Heaney , Christine Nicole Elia , Shifang Luo , Stephen J. McCarthy , Mohan Kalyanaraman
IPC分类号： C10G69/02
CPC分类号： C10G45/62 , C10G2300/202 , C10G2300/207 , C10G2400/10
摘要： An integrated process for producing lubricant base oils from feedstocks under sour conditions is provided. The ability to process feedstocks under higher sulfur conditions allows for reduced cost processing and increases the flexibility in selecting a suitable feedstock. The sour feed can be delivered to a catalytic dewaxing step without any separation of sulfur and nitrogen contaminants, or a high pressure separation can be used to partially eliminate contaminants.
摘要翻译： 提供了一种在酸性条件下从原料生产润滑剂基础油的综合方法。 在较高硫条件下处理原料的能力允许降低成本处理并增加选择合适原料的灵活性。 可以将酸性进料输送到催化脱蜡步骤，而不会分离硫和氮污染物，或者可以使用高压分离来部分地消除污染物。
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公开(公告)号：US20100147741A1
公开(公告)日：2010-06-17
申请号：US12653038
申请日：2009-12-08
申请人： Wenyih F. Lai , Christine N. Elia
发明人： Wenyih F. Lai , Christine N. Elia
CPC分类号： C10G45/64 , B01J29/70 , B01J29/74 , B01J37/0009 , B01J2229/20 , B01J2229/42 , C01B39/065 , C01B39/48
摘要： A process is described of producing an MTT framework type molecular sieve by crystallizing a mixture capable of forming said molecular sieve, wherein the mixture comprises sources of alkali or alkaline earth metal (M), an oxide of trivalent element (X), an oxide of tetravalent element (Y), water and a directing agent (R) of the formula (CH3)3N+CH2CH2CH2N+(CH3)2CH2CH2CH2N+(CH3)3, and has a composition, in terms of mole ratios, within the following ranges. YO2/X2O3 less than 45 H2O/YO2 5 to 100 OH−/YO2 0.05 to 0.5 M/YO2 0.05 to 0.5 and R/YO2>0 to
摘要翻译： 描述了通过使能够形成所述分子筛的混合物结晶来生产MTT框架型分子筛的方法，其中所述混合物包含碱金属或碱土金属（M）的源，三价元素（X）的氧化物， 四价元素（Y），水和式（CH 3）3 N + CH 2 CH 2 CH 2 N +（CH 3）2 CH 2 CH 2 CH 2 N +（CH 3）3的定向剂（R），并且以摩尔比计含有以下范围内的组成。 YO2 / X2O3小于45H2O / YO2 5至100 OH- / YO2 0.05至0.5M / YO2 0.05至0.5，R / YO2> 0至<0.5。
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公开(公告)号：US10016747B2
公开(公告)日：2018-07-10
申请号：US14887492
申请日：2015-10-20
CPC分类号： B01J29/703 , B01J29/74 , C10G45/62 , C10G45/64 , C10G65/043 , C10G65/12 , C10G2300/302 , C10G2300/304 , C10G2400/10 , C10M101/02
摘要： Methods are provided for using a dewaxing catalyst formed using at least two structure directing agents for production of a lubricant base stock. For example, ZSM-48 crystals formed using multiple directing agents (and/or formulated catalysts made using such crystals) can have an increased activity and/or can provide an improved yield during catalytic production of lubricant base stocks. Additionally or alternately, ZSM-48 crystals formed using multiple directing agents (and/or formulated catalysts made using such crystals) can provide improved aromatic saturation during processing of a feed for lubricant base stock production.
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公开(公告)号：US20160121315A1
公开(公告)日：2016-05-05
申请号：US14887492
申请日：2015-10-20
IPC分类号： B01J29/70 , C10G65/04 , C10G65/12 , C10M101/02 , C10G45/64
CPC分类号： B01J29/703 , B01J29/74 , C10G45/64 , C10G65/043 , C10G65/12 , C10M101/02
摘要： Methods are provided for using a dewaxing catalyst formed using at least two structure directing agents for production of a lubricant base stock. For example, ZSM-48 crystals formed using multiple directing agents (and/or formulated catalysts made using such crystals) can have an increased activity and/or can provide an improved yield during catalytic production of lubricant base stocks. Additionally or alternately, ZSM-48 crystals formed using multiple directing agents (and/or formulated catalysts made using such crystals) can provide improved aromatic saturation during processing of a feed for lubricant base stock production.
摘要翻译： 提供了使用至少两种用于生产润滑剂基础原料的结构导向剂形成的脱蜡催化剂的方法。 例如，使用多个引导剂（和/或使用这种晶体制备的配制的催化剂）形成的ZSM-48晶体可以具有增加的活性和/或可以在催化生产润滑剂基础油料时提供改善的产率。 另外或替代地，使用多个引导剂（和/或使用这种晶体制备的配制的催化剂）形成的ZSM-48晶体可以在用于润滑剂原料生产的进料的加工期间提供改善的芳族饱和度。
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公开(公告)号：US08992764B2
公开(公告)日：2015-03-31
申请号：US13169409
申请日：2011-06-27
申请人： Krista Marie Prentice , Michel Daage , Ajit Bhaskar Dandekar , Christopher Gordon Oliveri , Rohit Vijay , Stephen J. McCarthy , Wenyih F. Lai , Bradley R. Fingland
发明人： Krista Marie Prentice , Michel Daage , Ajit Bhaskar Dandekar , Christopher Gordon Oliveri , Rohit Vijay , Stephen J. McCarthy , Wenyih F. Lai , Bradley R. Fingland
IPC分类号： C10G73/38 , C10G73/44 , C10G45/02 , C10G45/64 , C10G47/16 , C10G7/00 , C10G49/22 , C10G65/12 , C10G65/04 , B01J29/74 , B01J35/02
CPC分类号： C10G67/02 , B01J29/7461 , B01J35/026 , B01J2229/36 , B01J2229/42 , C10G45/64 , C10G65/043 , C10G65/12 , C10G2300/202 , C10G2300/302 , C10G2300/4018 , C10G2300/4081 , C10G2400/02 , C10G2400/04 , C10G2400/10 , C10L1/08 , C10L2200/0446 , C10L2270/026 , C10L2290/543 , C10M101/02
摘要： An integrated process for producing naphtha fuel, diesel fuel and/or lubricant base oils from feedstocks under sour conditions is provided. The ability to process feedstocks under higher sulfur and/or nitrogen conditions allows for reduced cost processing and increases the flexibility in selecting a suitable feedstock. The sour feed can be delivered to a catalytic dewaxing step without any separation of sulfur and nitrogen contaminants. The integrated process includes an initial dewaxing of a feed under sour conditions, optional hydrocracking of the dewaxed feed, and a separation to form a first diesel product and a bottoms fraction. The bottoms fraction is then exposed to additional hydrocracking and dewaxing to form a second diesel product and optionally a lubricant base oil product. Alternatively, a feedstock can be hydrotreated, fractionated, dewaxed, and then hydrocracked to form a diesel fuel and a dewaxed, hydrocracked bottoms fraction that is optionally suitable for use as a lubricant base oil.
摘要翻译： 提供了一种在酸性条件下从原料生产石脑油燃料，柴油和/或润滑油基础油的综合方法。 在更高硫和/或氮条件下处理原料的能力允许降低成本处理并增加选择合适原料的灵活性。 酸性饲料可以输送到催化脱蜡步骤，而不会分离硫和氮污染物。 一体化方法包括在酸性条件下进料的初始脱蜡，脱蜡进料的任选加氢裂化和分离以形成第一柴油产物和塔底馏分。 然后将底部馏分暴露于额外的加氢裂化和脱蜡以形成第二柴油产品和任选的润滑剂基础油产品。 或者，可以将原料加氢处理，分馏，脱蜡，然后进行加氢裂化，以形成任选适合用作润滑剂基础油的柴油燃料和脱蜡加氢裂化塔底馏分。
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