公开(公告)号：US06254663B1

公开(公告)日：2001-07-03

申请号：US09221494

申请日：1998-12-28

申请人： Werner Leopold Kepplinger ,  Felix Wallner ,  Johannes Schenk ,  Il-Ock Lee ,  Yong-Ha Kim ,  Moon Duk Park

发明人： Werner Leopold Kepplinger ,  Felix Wallner ,  Johannes Schenk ,  Il-Ock Lee ,  Yong-Ha Kim ,  Moon Duk Park

IPC分类号： C21B1314

摘要： In the process for the production of liquid pig iron 943) or liquid steel pre-products from charging substances comprising iron ore (5) and fluxes and at least partially containing a portion of fines, the iron ore is directly reduced to sponge iron in at least two reduction stages (1, 2) by the fluidized bed method, the sponge iron is melted in a melt-down gasifying zone (39) under the supply of carbon carriers and an oxygen-containing gas, and a CO- and H2-containing reducing gas is produced which is injected into reduction zones of the reduction stages (1, 2), is reacted there, is withdrawn as a top gas and optionally is supplied to a consumer. To achieve uniform reduction of the iron ore at optimum exploitation of the reducing gas, the iron ore (5) in a first reduction stage (1) by aid of the reducing gas is fractionated into at least two fractions having different grain size distributions each, each fraction is reduced by the reducing gas in a separate fluidized bed (6, 15), wherein the reducing gas maintains a first fluidized bed (6) containing the coarse-grain fraction and separates the fine-grain fraction from the same, and wherein, further, reducing gas is additionally introduced into the further fluidized bed (15) directly reduced iron ore (5) is discharged both from the first and from the further fluidized bed (6, 15) and the fine- and the coarse-grain fraction reduced in the first reduction stage (1) are further reduced in at least one further reduction stage (2) operating in the same manner as the first reduction stage (1) and from the last reduction stage (2) the fine-grain fraction is introduced into the melt-down gasifying zone (39) while being agglomerated by provision of oxygen, and the coarse-grain fraction is fed directly into the melt-down gasifying zone (39) gravitationally (FIG. 1).

公开(公告)号：US06416566B1

公开(公告)日：2002-07-09

申请号：US09221494

申请日：1998-12-28

申请人： Werner Leopold Kepplinger ,  Felix Wallner ,  Johannes Schenk ,  Il-Ock Lee ,  Yong-Ha Kim ,  Moon Duk Park

发明人： Werner Leopold Kepplinger ,  Felix Wallner ,  Johannes Schenk ,  Il-Ock Lee ,  Yong-Ha Kim ,  Moon Duk Park

IPC分类号： C21B1314

CPC分类号： C21B13/14 ,  Y02P10/136

摘要： In the process for the production of liquid pig iron 943) or liquid steel pre-products from charging substances comprising iron ore (5) and fluxes and at least partially containing a portion of fines, the iron ore is directly reduced to sponge iron in at least two reduction stages (1, 2) by the fluidized bed method, the sponge iron is melted in a melt-down gasifying zone (39) under the supply of carbon carriers and an oxygen-containing gas, and a CO- and H2-containing reducing gas is produced which is injected into reduction zones of the reduction stages (1, 2), is reacted there, is withdrawn as a top gas and optionally is supplied to a consumer. To achieve uniform reduction of the iron ore at optimum exploitation of the reducing gas, the iron ore (5) in a first reduction stage (1) by aid of the reducing gas is fractionated into at least two fractions having different grain size distributions each, each fraction is reduced by the reducing gas in a separate fluidized bed (6, 15), wherein the reducing gas maintains a first fluidized bed (6) containing the coarse-grain fraction and separates the fine-grain fraction from the same, and wherein, further, reducing gas is additionally introduced into the further fluidized bed (15) directly reduced iron ore (5) is discharged both from the first and from the further fluidized bed (6, 15) and the fine- and the coarse-grain fraction reduced in the first reduction stage (1) are further reduced in at least one further reduction stage (2) operating in the same manner as the first reduction stage (1) and from the last reduction stage (2) the fine-grain fraction is introduced into the melt-down gasifying zone (39) while being agglomerated by provision of oxygen, and the coarse-grain fraction is fed directly into the melt-down gasifying zone (39) gravitationally (FIG. 1).

摘要翻译： 在生产液体生铁943）或含铁矿石（5）和助熔剂的物料的液态钢产品的过程中，至少部分含有一部分细粉，铁矿石直接还原成海绵铁 通过流化床法将至少两个还原阶段（1,2），海绵铁在碳载体和含氧气体的供应下在熔化气化区（39）中熔化，并且CO-和H 2 - 产生含有还原气体的废气，其被注入到还原段（1,2）的还原区中，在其中反应，作为顶部气体排出并任选地供应给消费者。 为了在最佳利用还原气体的情况下实现铁矿石的均匀还原，通过还原气体将第一还原段（1）中的铁矿石（5）分级成至少两个具有不同粒度分布的级分， 在分离的流化床（6,15）中每个馏分被还原气体还原，其中还原气体保持含有粗晶粒部分的第一流化床（6），并将细晶粒部分与其分离，其中 进一步地，将还原气体另外引入到另外的流化床（15）中，直接还原的铁矿石（5）从第一流化床（6,15）和另外的流化床（6,15）排出，并且精细和粗颗粒馏分 在与第一还原阶段（1）相同的方式和从最后的还原阶段（2）操作的至少一个另外的还原阶段（2）中，第一还原阶段（1）中的还原进一步减少，细晶粒分数为 引入熔化 气化区（39），同时通过提供氧气而聚集，并且粗粒部分重力地直接进入熔化气化区（39）。 1）。

公开(公告)号：US6030432A

公开(公告)日：2000-02-29

申请号：US913505

申请日：1997-11-17

申请人： Werner Leopold Kepplinger ,  Felix Wallner ,  Johannes-Leopold Schnek ,  Udo Gennari ,  Il-Ock Lee ,  Yong-Ha Kim ,  Gyu-Dae Park

发明人： Werner Leopold Kepplinger ,  Felix Wallner ,  Johannes-Leopold Schnek ,  Udo Gennari ,  Il-Ock Lee ,  Yong-Ha Kim ,  Gyu-Dae Park

IPC分类号： F27B15/00 ,  C21B13/00 ,  C22B5/14 ,  C21B11/00 ,  C22B1/10

CPC分类号： C21B13/0033 ,  Y02P10/136

摘要： In a process for the reduction of fine ore by reducing gas in the fluidized bed method, the following characteristic features are realized in order to achieve a uniform and even degree of metallization at optimum utilization of the reducing gas and while minimizing the amount of reducing gas employed, that the fine ore is fractionated by aid of the reducing gas into at least two fractions having different grain size distributions, that each fraction is reduced by the reducing gas in a separate fluidized bed, wherein the reducing gas maintains a first fluidized bed containing the coarse-grain fraction and separates the fine-grain fraction from the same, is accelerated together with the fine-grain fraction, subsequently under pressure release forms a further fluidized bed, into which it is continuously injected in a radially symmetrical manner and from below, and wherein, furthermore, secondary reducing gas additionally is directly injected into the further fluidized bed in a radially symmetrical manner, and that reduced ore is discharged from both the first and the second fluidized beds.

摘要翻译： PCT No.PCT / AT96 / 00045 Sec。 371日期：1997年11月17日 102（e）1997年11月17日PCT PCT 1996年3月11日PCT公布。 公开号WO96 / 29435 日期1996年9月26日在流化床方法中通过还原气体还原细矿石的方法中，实现了以下特征，以便在最佳利用还原气体的同时实现均匀均匀的金属化，同时最小化 所用的还原气体的量，将细矿石通过还原气体分级成至少两个具有不同粒度分布的馏分，每个馏分在单独的流化床中被还原气体还原，其中还原气体保持 含有粗晶粒部分并将细晶粒部分与其分离的第一流化床与细晶粒部分一起加速，随后在压力释放下形成另外的流化床，其中它以径向方式连续注入 另外，二次还原气体另外直接注入到另外的流化床中 d以径向对称的方式，并且还原的矿石从第一和第二流化床排出。

公开(公告)号：US06241801B1

公开(公告)日：2001-06-05

申请号：US09193544

申请日：1998-11-17

申请人： Werner Leopold Kepplinger ,  Felix Wallner ,  Johannes-Leopold Schenk ,  Franz Hauzenberger ,  Il-Ock Lee

发明人： Werner Leopold Kepplinger ,  Felix Wallner ,  Johannes-Leopold Schenk ,  Franz Hauzenberger ,  Il-Ock Lee

IPC分类号： C22B514

CPC分类号： C21B13/002 ,  C21B13/0033 ,  C21B13/14 ,  C21B2100/44 ,  C21B2100/66 ,  C22B5/14 ,  F27B15/00 ,  Y02P10/136

摘要： In a method for treating particulate material in the fluidized bed method, the particulate material is maintained in a fluidized bed by a treating gas flowing from bottom to top and thereby is treated. To minimize the consumption of treating gas and to reduce entrainment of fine particles by the treating gas, a particulate material having a wide grain distribution and a relatively high portion of fines is used for treatment and the treating gas in the fluidized bed is maintained at a superficial velocity less than the velocity required for fluidizing the largest particles of said particulate material.

摘要翻译： 在流化床方法中处理颗粒材料的方法中，颗粒材料通过从底部向上流动的处理气体保持在流化床中，从而被处理。 为了最小化处理气体的消耗并且减少由处理气体引起的细颗粒的夹带，使用具有宽晶粒分布和较高部分细粒的颗粒材料用于处理，并且流化床中的处理气体保持在 表面速度小于使所述颗粒材料的最大颗粒流化所需的速度。

公开(公告)号：US5948139A

公开(公告)日：1999-09-07

申请号：US793875

申请日：1997-04-17

申请人： Werner Leopold Kepplinger ,  Felix Wallner ,  Johannes Schenk

发明人： Werner Leopold Kepplinger ,  Felix Wallner ,  Johannes Schenk

IPC分类号： C21B11/02 ,  C21B11/00 ,  C21B13/00 ,  C21B13/14

CPC分类号： C21B13/002 ,  Y02P10/136

摘要： In a process for the production of molten pig iron or steel pre-products from fine-particulate iron-cintaining material, in a meltdown-gasifying zone of a melter gasifier (1), under the supply of carbon-containing material and oxygen-containing gas at the simultaneous formation of a reducing gas, in a bed formed of sold carbon carriers, the iron-containing material is melted when passing the bed. To be able to employ a charge here up to 100% of which consist of fine ore, while reliably avoiding discharge of the supplied fine ore, a high-temperature combustion and/or gasification xzone is formed by combusting and/or gasifying carbon-containing material under direct supply of oxygen in a killing space (III) formed above the bed, into which high-temperature combustion and/or gasification zone the fine-particulate iron-containing material is directly introduced, wherein at least incipient surface melting of the iron-containing material and agglomeration of the same are carried out by means of the heat released during the reaction of the carbon-containing material.

摘要翻译： PCT No.PCT / AT96 / 00129 Sec。 371日期1997年04月17日 102（e）日期1997年4月17日PCT提交1996年7月18日PCT公布。 出版物WO97 / 04137 日期1997年2月6日在熔炼炉气化炉（1）的熔化气化区中，在含碳含量较高的熔融气化炉（1）的熔化气化区中生产熔融生铁或钢铁预制品的方法 材料和含氧气体在同时形成还原气体时，在由销售的碳载体形成的床中，含铁材料在通过床时熔化。 为了能够在其中使用100％的矿石，在可靠地避免供给的细矿石排放的同时，通过燃烧和/或气化含碳的方法形成高温燃烧和/或气化xzone 在床上形成的杀伤空间（III）中直接供应氧的材料，高温燃烧和/或气化区直接引入细颗粒含铁材料，其中至少初期的铁表面熔化 的含有材料和其附聚物通过在含碳材料的反应期间释放的热量进行。

公开(公告)号：US06264722B1

公开(公告)日：2001-07-24

申请号：US08983529

申请日：1998-01-20

申请人： Werner Leopold Kepplinger ,  Felix Wallner ,  Johannes Schenk

发明人： Werner Leopold Kepplinger ,  Felix Wallner ,  Johannes Schenk

IPC分类号： C21B1314

CPC分类号： C21B13/002 ,  C21B13/14 ,  C21B2100/44 ,  Y02P10/136

摘要： In a process for producing molten pig iron or steel preproducts from fine-particulate iron containing material in a meltdown gasifying zone of a melter gasifier, under the supply of carbon-containing material and oxygen-containing gas at the simultaneous formation of a reducing gas in a bed formed of solid carbon carriers, the iron-containing material is melted when passing the bed. In order to be able to work with a charge consisting of fine ore by up to 100%, yet reliably avoid discharging of the fine ore supplied, a supply duct for fine-particulate coal, such as coal dust and/or other carbon-containing materials including volatile portions, and a duct feeding an oxygen-containing gas enter in the vicinity of the reducing-gas discharge duct of the melter gasifier, the fine-particulate coal and/or other carbon-containing materials including volatile portions are reacted to fine-particulate coke upon introduction into the melter gasifier, the fine-particulate coke is discharged along with the reducing gas carried off the melter gasifier and is separated in a separating means.

摘要翻译： 在熔融气化炉的熔化气化区的含细粒铁的材料生产熔融生铁或钢前产品的方法中，在含碳材料和含氧气体的供应下，同时形成还原气体 由固体碳载体形成的床，当含铁材料通过床时熔化。 为了能够将由细矿石组成的装置加工达100％，可靠地避免排出提供的细矿石，用于细粉煤的供应管道，例如煤粉和/或其他含碳的 包括挥发部分的材料和供给含氧气体的管道进入熔化器气化器的还原气体排放管道附近，包含挥发部分的细颗粒煤和/或其它含碳材料反应至细 颗粒状焦炭在引入熔化炉气化器中时，微粉末焦炭与从气化器气化器输送的还原气体一起排出，并在分离装置中分离。

公开(公告)号：US6149708A

公开(公告)日：2000-11-21

申请号：US101208

申请日：1998-08-04

申请人： Werner Leopold Kepplinger ,  Felix Wallner ,  Udo Gennari

发明人： Werner Leopold Kepplinger ,  Felix Wallner ,  Udo Gennari

IPC分类号： C21B13/00 ,  C21B13/14

CPC分类号： C21B13/002 ,  C21B13/14 ,  Y02P10/136

摘要： A process for producing sponge iron by directly reducing particulate, iron-oxide-containing material, wherein reducing gas that is formed from carbon carriers and an oxygen-containing gas in a melt-down gasifying zone is introduced into a reduction zone that contains the iron-oxide-containing material, characterized by the combination of the following characteristic features: (i) to the reduction zone, a reducing gas is fed which contains between iron-oxide-containing material 20 g and 100 g per Nm.sup.3 of a dust having a carbon content of between 30 mass % and 70 mass %; and (ii) the iron-oxide-containing material is exposed to the reducing gas for a time period that exceeds the period for a complete reduction. The process of the invention renders it possible to produce a sponge iron of elevated carbon content.

摘要翻译： PCT No.PCT / AT97 / 00238 Sec。 371日期：1998年8月4日 102（e）日期1998年8月4日PCT 1997年11月5日PCT公布。 公开号WO98 / 20172 日期1998年5月14日一种通过直接还原颗粒状氧化铁的材料制造海绵铁的方法，其中在熔融气化区中由碳载体和含氧气体形成的还原气体被引入还原区 其含有含铁氧化物的材料，其特征在于结合以下特征：（i）至还原区，进料还原气体，该还原气体含有含铁氧化物的材料20g和100g每Nm 3的 碳含量在30质量％至70质量％之间的粉尘; 和（ii）含氧化铁材料暴露于还原气体超过完全还原期间的时间。 本发明的方法使得可以生产具有高碳含量的海绵铁。

公开(公告)号：US5961690A

公开(公告)日：1999-10-05

申请号：US860241

申请日：1997-06-10

申请人： Werner Leopold Kepplinger ,  Felix Wallner ,  Johannes-Leopold Schenk

发明人： Werner Leopold Kepplinger ,  Felix Wallner ,  Johannes-Leopold Schenk

IPC分类号： C21B11/00 ,  C21B13/00 ,  C21B13/14 ,  C22B5/14

CPC分类号： C21B13/14 ,  C21B13/002 ,  Y02P10/122 ,  Y02P10/126 ,  Y02P10/128 ,  Y02P10/136

摘要： In a process for producing molten pig iron or liquid steel pre-products, from particulate iron-oxide-containing material by fluidization, the iron-oxide-containing material is prereduced in at least one prereduction stage (7) by aid of a reducing gas and subsequently is reduced to sponge iron in a final reduction stage (8), the sponge iron is melted in a meltdown-gasifying zone (11) under the supply of carbon carriers and an oxygen-containing gas, and a CO- and H.sub.2 -containing reducing gas is produced which is introduced into the final reduction stage (8), is reacted there, is drawn off, subsequently is introduced into a prereduction stage (7), is reacted there, is drawn off, subjected to scrubbing and subsequently is carried off as an export gas and wherein at least a portion of the reacted reducing gas is purified from CO.sub.2, is heated and is used as a recycle-reducing gas for the reduction of the iron-oxide-containing material. To ensure reduction while avoiding the occurrence of "sticking", while also minimizing the amount of carbon carriers charged, a portion of the reducing gas flowing from the final reduction stage (8) into the prereduction stage (7) is branched off, washed, purified from CO.sub.2 and heated and subsequently is recycled to the final reduction stage (8) (FIG. 1).

摘要翻译： PCT No.PCT / AT96 / 00191 Sec。 371日期：1997年6月10日 102（e）日期1997年6月10日PCT提交1996年10月8日PCT公布。 公开号WO97 / 13880 PCT 日期1997年04月17日在通过流化从含有氧化锰的物质生产熔融生铁或液钢预制品的方法中，含氧化铁材料在至少一个预还原阶段（7）中被预还原 还原气体的帮助，随后在最终还原阶段（8）中还原成海绵铁，海绵铁在碳载体和含氧气体的供应下在熔化气化区（11）中熔化，并且 产生含有CO和H 2的还原气体，其被引入到最终还原阶段（8）中，在其中反应，被排出，随后被引入预还原阶段（7），在那里被反应，被排出 进行洗涤，随后作为出口气体运送，并且其中至少一部分反应的还原气体从CO 2中净化，被加热并用作还原还原气体以还原含氧化铁的材料。 为了确保减少，同时避免“粘附”的发生，同时最小化装载的碳载体的量，一部分从最终还原段（8）流入预还原阶段（7）的还原气体被分支，洗涤， 从CO 2中纯化并加热，随后再循环至最终还原阶段（8）（图1）。

公开(公告)号：US5858058A

公开(公告)日：1999-01-12

申请号：US765331

申请日：1997-01-15

申请人： Gerald Kern ,  Werner Leopold Kepplinger ,  Johannes Schenk ,  Roy Hubert Whipp, Jr.

发明人： Gerald Kern ,  Werner Leopold Kepplinger ,  Johannes Schenk ,  Roy Hubert Whipp, Jr.

IPC分类号： C21B13/00 ,  F27B15/10 ,  F27D17/00

CPC分类号： C21B13/0073 ,  Y02P10/122 ,  Y02P10/136 ,  Y02P10/143

摘要： A direct reduction process is disclosed for iron-oxide-containing materials. Synthesis gas is mixed with top gas produced during direct reduction of the iron-oxide-containing materials and is used as reduction gas for directly reducing iron-oxide-containing materials. In order to avoid or reduce metal dusting caused by an increased CO content of the reduction gas with a simple technique and equipment, the CO/CO.sub.2 ratio of the reduction gas is set at a predetermined value from 1 to 3.

摘要翻译： PCT No.PCT / AT95 / 00123 Sec。 371日期1997年1月15日 102（e）日期1997年1月15日PCT提交1995年6月20日PCT公布。 出版物WO96 / 00304 PCT 日期1996年1月4日公开了含氧化铁材料的直接还原方法。 将合成气与直接还原含铁氧化物的材料中产生的顶部气体混合，并用作直接还原含氧化铁材料的还原气体。 为了通过简单的技术和设备避免或减少由还原气体的CO含量增加引起的金属粉尘，将还原气体的CO / CO 2比设定在1至3的预定值。

公开(公告)号：US20090217785A1

公开(公告)日：2009-09-03

申请号：US12065354

申请日：2006-08-17

申请人： Werner Leopold Kepplinger ,  Bernd Hollauf ,  Wolfgang Franz Mayer

发明人： Werner Leopold Kepplinger ,  Bernd Hollauf ,  Wolfgang Franz Mayer

IPC分类号： C22B9/00 ,  C22B11/00

CPC分类号： C22B15/0054 ,  C22B5/10 ,  C22B5/16 ,  C22B15/006 ,  Y02P10/214 ,  Y02P10/22

摘要： The invention relates to a method for separating impurities out of slags, dusts, minerals, preparation residues of minerals or of recyclings or remaining substances, subsequently called feed stock. In order to save energy and reduce costs, the inventive method is characterized by the combination of the following features: melting the feed stock containing the impurities; forming a copper melt; bring the feed stock into contact with the copper melt while adding reducing agents, preferably coke and/or coal; vaporizing, if required, existing volatile compounds such as metal chlorides; reducing metals of the feed stock more noble than copper in the copper melt, and; forming a slag with constituents of the feed stock to be purified that is less noble than copper.

摘要翻译： 本发明涉及从炉渣，粉尘，矿物质，矿物的制备残余物或回收物或其余物质中分离杂质的方法，随后称为原料。 为了节省能源并降低成本，本发明的方法的特征在于结合以下特征：熔化含有杂质的原料; 形成铜熔体; 使原料与铜熔体接触，同时加入还原剂，优选焦炭和/或煤; 如果需要，蒸发现有的挥发性化合物如金属氯化物; 在铜熔体中还原金属比铜更贵， 与待纯化的原料的成分形成渣，其比铜更不贵。