摘要:
Toluene-soluble, sulphur-modified polychloroprene is obtained by emulsion copolymerization of chloroprene, sulphur and optionally further monomers which are copolymerizable with chloroprene and sulphur using a peroxy activator and subsequent working-up by stabilizing, stopping, degassing and isolating without separate peptization, in that polymerization is carried out in the presence of dithiocarbamates and/or xanthogenates and the activator is metered in continuously or batch-wise during the course of polymerization.
摘要:
An improved process for the preparation of polychloroprene by the emulsion (co)polymerization of chloroprene and optionally other monomers capable of copolymerization with chloroprene, using a peroxo activator, and subsequent working up of the product by stopping the reaction, stabilizing, degassing and isolating the product, characterized in that polymerization is carried out in the presence of dithiocarbamates and/or xanthates and 0 to 0.5% by weight of sodium .beta.-anthraquinone sulphonate.
摘要:
An elastomeric mass of polychloroprene sol and polychloroprene gel in proportions in the range of 95:5 to 25:75% by weight in which the polychloroprene sol is free from sulphur and the polychloroprene gel used is a sulphur-containing gel with xanthate or carbamate functions has better processing characteristics than the pure sol component without the expected deterioration in the mechanical properties of the vulcanisates prepared from the mass.
摘要:
The invention relates to a polychloroprene rubber which shows advantages over the prior art in the sum total of its performance properties, namely vulcanization rate, tensile strength, elongation at break, modulus, tear propagation resistance and thermal stability of the vulcanizate.
摘要:
Vulcanizable, mercaptan- and/or xanthogen-disulfide-regulated polychloroprene rubber are produced by emulsion polymerization of chloroprene and, based on polymerizable monomer used, 0 to 30 parts by weight ethylenically unsaturated, other monomers copolymerizable with chloroprene in an alkaline medium by a process in which(1) 0.1 to 10 parts by weight of a tricyclic diterpene carboxylic acid containing at least two conjugated C.dbd.C double bonds per molecule, based on the polymerizable monomer used, and optionally(2) 0.1 to 5 parts by weight, based on polymerizable monomer used, fatty acid estersare used for their production.The polychloroprene produced in accordance with the invention may be used for the production of vulcanized rubber articles. The polychloroprene rubbers produced by the process according to the invention have a minimal tendency to foul metal molds. The pollution of wastewaters by the process according to the invention is minimal. The well-known favorable properties of polychloroprene remain unaffected.
摘要:
The combination of unmodified resinic acids and direct peptization in the production of sulfur-modified polychloroprene leads to a favorable ratio of elasticity to viscosity.
摘要:
Solid polychloroprene mixtures consisting of sol and gel polymer, wherein the sol component consists of a copolymer of chloroprene and from 0.75 to 0.32% by weight of sulphur, based on the total quantity of unsaturated compounds of the sol polychloroprene, and the gel component consists of a copolymer of chloroprene, from 0.4 to 1.0% by weight of sulphur, based on the total quantity of unsaturated compounds of the gel polychloroprene and from 7.5.times.10.sup.-3 to 3.0.times.10.sup.-2 mols, based on 100 g of the total quantity of monomer of the gel polychloroprene, of a compound corresponding to the general formula ##STR1## wherein R.sub.1 and R.sub.2 each represents a hydrogen atom or C.sub.1 -C.sub.4 alkyl group, and X represents a C.sub.2 -C.sub.10 alkylene group,are suitable for the production by extrusion and by calandering of rubber articles which may be subjected to high strains.
摘要:
Vulcanizable, elastomeric chloroprene/sulfur copolymers having viscosities of from 60 to 35 ME, strengths of greater than 20 MPa and sulfur contents of from about 0.3 to 0.45% by weight are obtained by polymerizing chloroprene in the presence of from 0.05 to 0.40% by weight of sulfur to form a latex I, polymerizing chloroprene in the presence of from 0.5 to 1.5% by weight of sulfur to form a latex II, mixing latices I and II, optionally together with other sulfur-modified polychloroprene latices, in a ratio of from 4:1 to 1:4 (based in each case on solids) and peptizing the mixture, followed by working up to form the solid rubber, the percentages quoted being based on the quantity of monomer.
摘要:
Vulcanisable, elastomeric chloroprene-sulphur copolymers having viscosities of from 60 to 35 MU, strengths of >20 MPa and sulphur contents of from about 0.5 to 0.7%, by weight, in the batch are obtained by polymerising chloroprene in the presence of from 0.10 to 0.35%, by weight, of sulphur to form a latex I, polymerising chloroprene in the presence of from 0.50 to 1.00% by weight, of sulphur to form a latex II, mixing latices I and II in a ratio of from 4:1 to 1:4 (based in each case on solids), optionally together with other sulphur-modified polychloroprene latices, the mixture is peptised and worked-up to form the solid rubber, the percentages quoted being based on the quantity of monomer.
摘要:
This invention relates to mixtures of polychloroprene elastomers which are distinguished by their good processibility and excellent cold resistance.