公开(公告)号：US06207757B1

公开(公告)日：2001-03-27

申请号：US09365227

申请日：1999-07-30

申请人： Werner Obrecht ,  Thomas Scholl ,  Peter Wendling ,  Michael Well ,  Victor Monroy

发明人： Werner Obrecht ,  Thomas Scholl ,  Peter Wendling ,  Michael Well ,  Victor Monroy

IPC分类号： C08K334

CPC分类号： C08L7/00 ,  B60C1/0016 ,  C08K5/54 ,  C08K5/5415 ,  C08L7/02 ,  C08L19/003 ,  C08L21/00 ,  Y02T10/862 ,  Y10T152/10495 ,  C08L2666/08

摘要： A rubber composition which contains a rubber mixture that can be vulcanized with a vulcanizing agent, which includes at least one rubber component, at least one filler having nucleophilic groups, gel particles comprising a rubber, having a particle size between about 3×10−9 and about 1×10−6 m and a swelling index in toluene of about 1 to about 15 and whose surface has electrophilic centers, and a substance acting as a coupling agent between the filler having nucleophilic groups and the additional filler, the substance acting as a coupling agent having the following structure: X—R1—Si—(R2)3, wherein X is a nucleophilic group, R1 is an alkyl group having up to about 6 carbon atoms or a phenyl group, and R2 may be the same as or different from each other and from R1 and is an alkyl or alkoxy group having up to 6 carbon atoms and at least one of R2 is an alkoxy group. The rubber composition has improved hysteresis behavior in the vulcanized state so that with the use of this rubber composition in tires, the rolling resistance is reduced and the wet slippage behavior is improved in relation to conventional rubber compositions. A method of adding and blending the rubber composition as well as a composition useful for tire treads and vehicle tires containing the composition are disclosed.

摘要翻译： 一种橡胶组合物，其包含可以用硫化剂硫化的橡胶混合物，其包括至少一种橡胶组分，至少一种具有亲核基团的填料，包含橡胶的凝胶颗粒，其具有约3×10 -9和约 1×10 -6 m，甲苯中的溶胀指数为约1至约15，并且其表面具有亲电子中心，以及作为在具有亲核基团的填料和附加填料之间的偶联剂的物质，作为偶联剂的物质具有 以下结构：X-R1-Si-（R2）3，其中X是亲核基团，R1是具有高达约6个碳原子的烷基或苯基，R2可以相同或不同 另一个和R 1是具有至多6个碳原子的烷基或烷氧基，并且至少一个R2是烷氧基。 橡胶组合物在硫化状态下具有改善的滞后性能，因此通过在轮胎中使用该橡胶组合物，相对于常规橡胶组合物，滚动阻力降低，湿滑动性能得到改善。 公开了一种添加和混合橡胶组合物的方法以及用于轮胎胎面的组合物和含有该组合物的车辆轮胎。

公开(公告)号：US6133364A

公开(公告)日：2000-10-17

申请号：US365225

申请日：1999-07-30

申请人： Werner Obrecht ,  Thomas Scholl ,  Peter Wendling ,  Michael Well ,  Victor Monroy

发明人： Werner Obrecht ,  Thomas Scholl ,  Peter Wendling ,  Michael Well ,  Victor Monroy

IPC分类号： B60C1/00 ,  C08K5/17 ,  C08L7/00 ,  C08L9/00 ,  C08L19/00 ,  C08L21/00 ,  C08J5/10 ,  C08K3/04

CPC分类号： C08L7/00 ,  B60C1/0016 ,  C08K5/17 ,  C08L19/003 ,  C08L21/00 ,  C08L19/006 ,  C08L7/02

摘要： A rubber composition, which contains a rubber mixture that can be vulcanized with a vulcanizing agent, which includes at least one rubber component, at least one filler, gel particles comprising a rubber, having a particle size between about 3.times.10.sup.-9 and about 1.times.10.sup.-6 m and a swelling index in toluene of about 1 to about 15 and whose surface has electrophilic centers, and a substance which acts as a coupling agent between the gel particles and which has the structure A--R--A, wherein A is a nucleophilic group, and R is a saturated or unsaturated hydrocarbon group. The rubber composition has improved hysteresis behavior in the vulcanized state so that when this rubber composition is used in tires, the rolling resistance is reduced and the wet slippage behavior is improved in relation to the conventional rubber compositions. A method of formulating the rubber composition as well as a composition useful for tire treads and vehicle tires containing the composition are disclosed.

摘要翻译： 一种橡胶组合物，其含有可以用硫化剂硫化的橡胶混合物，其包含至少一种橡胶组分，至少一种填料，包含橡胶的凝胶颗粒，其粒度为约3×10 -9至约1×10 -9〜 6μm，甲苯中的溶胀指数为约1〜约15，表面具有亲电子中心，以及作为凝胶粒子之间的偶联剂并具有结构ARA的物质，其中A为亲核基团，R为 是饱和或不饱和烃基。 橡胶组合物在硫化状态下具有改善的滞后性能，使得当该橡胶组合物用于轮胎时，相对于常规橡胶组合物，滚动阻力降低，并且湿滑动性能得到改善。 公开了一种配制橡胶组合物的方法以及用于轮胎胎面的组合物和含有该组合物的车辆轮胎。

公开(公告)号：US06242534B1

公开(公告)日：2001-06-05

申请号：US09365226

申请日：1999-07-30

申请人： Werner Obrecht ,  Thomas Scholl ,  Peter Wendling ,  Michael Well ,  Victor Monroy

发明人： Werner Obrecht ,  Thomas Scholl ,  Peter Wendling ,  Michael Well ,  Victor Monroy

IPC分类号： C08F800

CPC分类号： C08L7/02 ,  B60C1/0016 ,  C08L7/00 ,  C08L19/00 ,  C08L21/00 ,  Y02T10/862 ,  Y10T152/10 ,  Y10T152/10495 ,  Y10T152/10855 ,  C08L2666/08

摘要： A rubber mixture containing at least one rubber component, at least one filler, and conventional additives that it contain at least one first gel as a filler, which is essentially comprised of a rubber, has a particle size of 3×10−9 to 1×10−6 m, and has a swelling index in toluene of 1 to 15, and at least the surface of this gel has acid or base groups, where these groups have not been produced by means of reaction with dithiophosphoric acid, and comprises: a) at least one second gel as an additional filler, which is essentially comprised of a rubber, has a particle size of 3×10−9 to 1×10−6 m, and has a swelling index in toluene of 1 to 15, which is in a position to undergo a neutralization reaction with the acid or base groups of the first gel and/or b) contains at least one substance as an additional additive, which is capable of undergoing a neutralization reaction with the acid or base groups of at least one gel. The rubber mixture demonstrates an improved hysteresis behavior in the vulcanized state so that, with the use of this rubber mixture in tires, for example, the rolling resistance is reduced and the wet slippage behavior is improved in relation to the conventional rubber mixture. Methods of formulating such rubber mixtures are also provided.

摘要翻译： 包含至少一种橡胶组分，至少一种填料和常规添加剂的橡胶混合物，其含有至少一种基本上由橡胶组成的填料的第一凝胶具有3×10 -9至1×10 -6 并且在甲苯中的溶胀指数为1至15，并且至少该凝胶的表面具有酸或碱基，其中这些基团未通过与二硫代磷酸反应产生，并且包括：a）至少 基本上由橡胶组成的附加填料的一秒钟凝胶的粒径为3×10 -9〜1×10 -6 m，甲苯中的溶胀指数为1〜15，其处于 与第一凝胶和/ orb的酸或碱基的中和反应）含有至少一种作为另外的添加剂的物质，其能够与至少一种凝胶的酸或碱基进行中和反应。橡胶混合物显示 v。改进的滞后行为 硫化状态使得通过使用轮胎中的这种橡胶混合物，例如，相对于常规的橡胶混合物，滚动阻力降低，并且湿滑滑动性能得到改善。还提供了配制这种橡胶混合物的方法。

公开(公告)号：US20050090383A1

公开(公告)日：2005-04-28

申请号：US10489370

申请日：2002-10-07

申请人： Sven Thiele ,  Victor Monroy ,  Hartmut Stoye ,  David Wilson

发明人： Sven Thiele ,  Victor Monroy ,  Hartmut Stoye ,  David Wilson

IPC分类号： C08F36/00 ,  B01J31/00 ,  C08F4/02 ,  C08F4/54 ,  C08F4/60 ,  C08F4/605 ,  C08F36/04

CPC分类号： C08F36/04 ,  C08F4/545

摘要： This invention relates to metal complex compositions, their preparation and their use as catalysts to produce polymers of conjugate dienes through polymerization of conjugated diene monomers. The used metal complex compositions are transition metal compounds in combination with an activator compound, optionally with a transition metal halide compound and optionally a catalyst modifier and optionally an inorganic or organic support material. The metal complexes comprises metals of group 3 to 10 of the Periodic System of the Elements in combination with activators, and optionally transition metal halide compounds of groups 3 to 10 of the Periodic Table of the Elements including lanthanide metals and actinide metals and optionally, catalyst modifiers, especially Lewis acids and optionally an inorganic or organic support material. More in particular the invention relates metal complex compositions, their preparation and their use as catalysts to produce homopolymers of conjugated dienes, preferably, but not limited to, through polymerization of 1,3-butadiene or isoprene.

摘要翻译： 本发明涉及金属络合物组合物及其制备及其作为通过共轭二烯单体聚合生成共轭二烯聚合物的催化剂的用途。 所使用的金属络合物组合物是与活化剂化合物，任选地与过渡金属卤化物化合物和任选的催化剂改性剂和任选的无机或有机载体材料组合的过渡金属化合物。 金属络合物包括与活化剂组合的元素周期系统3至10族的金属，以及任选的元素周期表第3至10族的过渡金属卤化物化合物，包括镧系金属和锕系金属以及任选的催化剂 改性剂，尤其是路易斯酸和任选的无机或有机载体材料。 更具体地，本发明涉及金属络合物组合物及其制备及其用作催化剂以制备共轭二烯的均聚物，优选但不限于通过1,3-丁二烯或异戊二烯的聚合。