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    Method for continuously polymerizing in mass quantities and taylor reactor for carrying out this method
    1.
    发明申请
    Method for continuously polymerizing in mass quantities and taylor reactor for carrying out this method 失效
    用于实施该方法的用于连续聚合的方法和泰勒反应器

    公开(公告)号：US20050159565A1

    公开(公告)日：2005-07-21

    申请号：US10486893

    申请日：2002-10-02

    申请人： Werner-Alfons Jung ,  Heinz-Peter Rink ,  Heinrich Meinecke ,  Josef Krull

    发明人： Werner-Alfons Jung ,  Heinz-Peter Rink ,  Heinrich Meinecke ,  Josef Krull

    IPC分类号： B01F7/00 ,  B01F7/28 ,  B01F15/00 ,  B01J19/18 ,  C08F2/01 ,  C08F2/02 ,  C08F2/00

    CPC分类号： B01J19/1806 ,  B01F7/00908 ,  B01F7/28 ,  B01F15/00688 ,  B01J2219/00094 ,  B01J2219/182 ,  B01J2219/185 ,  B01J2219/187 ,  B01J2219/194 ,  C08F2/01

    摘要： A Taylor reactor (1) according to FIG. 1, comprising 1. an annular reaction volume (2) which widens in the flow direction and is defined by an outer reactor wall (3), a rotor (4) which is mounted rotatably at the end (4.1) in the reactor floor (5) and at its other end (4.2) is unmounted, and a reactor floor (5) having a seal (6) for the drive shaft (7), 2. an inlet region (8) above the reactor floor (5), having at least one side feed (8.1) and/or at least one feed (8.1) through the reactor floor (5) for the reactants and/or the process media, 3. an outlet region (9) which is disposed above the annular reaction volume (2), widens further beyond the annular reaction volume (2) in the flow direction, and subsequently tapers toward a product offtake (10), 4. a product offtake (10) which at its greatest diameter opens toward the outlet region (9) and tapers in the other direction, and 5. a pressure maintenance valve (11); and its use for continuous bulk polymerization.

    摘要翻译： 图1的泰勒反应器（1）。 包括1.在流动方向上变宽并由外部反应器壁（3）限定的环形反应体积（2），可旋转地安装在端部（4.1）处的转子（4） 反应器底板（5）和其另一端（4.2）被卸下，并且具有用于驱动轴（7）的密封件（6）的反应器底板（5），2.在反应器底板上方的入口区域（8） （5），具有用于反应物和/或处理介质的至少一个侧进料（8.1）和/或至少一个进料（8.1），3.反应器底板（5）的出口区域（9） 设置在环形反应体积（2）上方，在流动方向上进一步扩展到环形反应体积（2）之外，并且随后朝向产品出口（10），4逐渐变细。在其最大直径打开的产品（10） 朝向出口区域（9）并沿另一方向逐渐变细，以及5.压力维持阀（11）。 并用于连续本体聚合。

    Method for continuously polymerizing in mass quantities and taylor reactor for carrying out this method
    2.
    发明授权
    Method for continuously polymerizing in mass quantities and taylor reactor for carrying out this method 失效
    用于实施该方法的用于连续聚合的方法和泰勒反应器

    公开(公告)号：US07651670B2

    公开(公告)日：2010-01-26

    申请号：US10486893

    申请日：2002-10-02

    申请人： Werner-Alfons Jung ,  Heinz-Peter Rink ,  Heinrich Meinecke ,  Josef Krull

    发明人： Werner-Alfons Jung ,  Heinz-Peter Rink ,  Heinrich Meinecke ,  Josef Krull

    IPC分类号： B01J8/08 ,  B01J8/02 ,  B01J19/00 ,  B01J19/18 ,  B01D19/00 ,  C08G85/00 ,  C08F4/00 ,  C08F210/00

    CPC分类号： B01J19/1806 ,  B01F7/00908 ,  B01F7/28 ,  B01F15/00688 ,  B01J2219/00094 ,  B01J2219/182 ,  B01J2219/185 ,  B01J2219/187 ,  B01J2219/194 ,  C08F2/01

    摘要： A Taylor reactor (1) according to FIG. 1, comprising 1. an annular reaction volume (2) which widens in the flow direction and is defined by an outer reactor wall (3), a rotor (4) which is mounted rotatably at the end (4.1) in the reactor floor (5) and at its other end (4.2) is unmounted, and a reactor floor (5) having a seal (6) for the drive shaft (7), 2. an inlet region (8) above the reactor floor (5), having at least one side feed (8.1) and/or at least one feed (8.1) through the reactor floor (5) for the reactants and/or the process media, 3. an outlet region (9) which is disposed above the annular reaction volume (2), widens further beyond the annular reaction volume (2) in the flow direction, and subsequently tapers toward a product offtake (10), 4. a product offtake (10) which at its greatest diameter opens toward the outlet region (9) and tapers in the other direction, and 5. a pressure maintenance valve (11); and its use for continuous bulk polymerization.

    摘要翻译： 根据图1的泰勒反应器（1） 1，包括1.环形反应体积（2），其在流动方向上变宽并由外反应器壁（3）限定;转子（4），其可旋转地安装在反应器底板（4.1）的端部（4.1） 并且在其另一端（4.2）上未安装，并且具有用于驱动轴（7）的密封件（6）的反应器底板（5），2.在反应器底板（5）上方的入口区域（8） 具有通过用于反应物和/或处理介质的反应器底板（5）的至少一个侧进料（8.1）和/或至少一个进料（8.1），3.出口区域（9），其设置在环形 反应体积（2）在流动方向上进一步扩展到环形反应体积（2）之外，并且随后朝着产品出口（10）逐渐变细。4.产品出口（10），其最大直径朝向出口区域打开 （9）并沿另一个方向逐渐变细; 5。压力维持阀（11）; 并用于连续本体聚合。

    Coating agent based on a branched hydroxyl group-containing polyester-modified polyacrylate resin and use thereof
    3.
    发明授权
    Coating agent based on a branched hydroxyl group-containing polyester-modified polyacrylate resin and use thereof 失效
    基于含支链羟基的聚酯改性聚丙烯酸酯树脂的涂料及其用途

    公开(公告)号：US6120851A

    公开(公告)日：2000-09-19

    申请号：US230532

    申请日：1999-01-25

    申请人： Harald Borgholte ,  Heinz-Peter Rink ,  Werner-Alfons Jung ,  Michael Brunnemann

    发明人： Harald Borgholte ,  Heinz-Peter Rink ,  Werner-Alfons Jung ,  Michael Brunnemann

    IPC分类号： C08G18/40 ,  C08G18/63 ,  C09D133/04 ,  C09D151/08 ,  C09D167/00 ,  C08L67/00

    CPC分类号： C09D151/08 ,  C08G18/4063 ,  C08G18/631 ,  C09D167/00

    摘要： The present invention relates to a coating composition comprising(A) at least one hydroxyl-containing component which [lacuna] of(A1) from 5 to 60% by weight of at least one polyester and(A2) from 40 to 95% by weight of at least one polyacrylate resin which has been prepared at least partially in the presence of component (A1) and(B) at least one crosslinking agent, characterized in that component (A2) is obtainable from the monomer units:(a) a cycloaliphatic ester of (meth)acrylic acid,(b) a hydroxyl-containing alkyl ester of (meth)acrylic acid,(c) a monomer which is different from (a) and (b) and has at least two polymerizable, olefinically unsaturated double bonds,(d) optionally a further hydroxyl-containing, ethylenically unsaturated monomer which is different from (a), (b) and (c),(e) an aliphatic ester of (meth)acrylic acid which is different from (a), (b), (c) and (d),(f) a vinyl-aromatic hydrocarbon which is different from (a), (b), (c), (d) and (e), and(g) a further ethylenically unsaturated monomer which is different from (a), (b), (c), (d), (e) and (f).

    摘要翻译： PCT No.PCT / EP97 / 03661 Sec。 371日期1999年1月25日 102（e）1999年1月25日PCT PCT 1997年7月10日PCT公布。 公开号WO98 / 03598 日本公开日1998年1月29日本发明涉及一种涂料组合物，其包含（A）至少一种含羟基成分，其中（A1）为5至60重量％的至少一种聚酯和（A2）40 至少一种在组分（A1）和（B）存在下至少部分制备的至少一种交联剂的至少一种聚丙烯酸酯树脂，其特征在于组分（A2）可从单体单元获得： （a）（甲基）丙烯酸的脂环族酯，（b）（甲基）丙烯酸的含羟基烷基酯，（c）不同于（a）和（b）的单体，并具有至少两个 可聚合的烯属不饱和双键，（d）任选的另外的含羟基的烯属不饱和单体，其不同于（a），（b）和（c），（e）（甲基）丙烯酸的脂族酯， 与（a），（b），（c），（d）和（e）不同的（a），（b），（c）和（d） 和（g）不同于（a），（b），（c），（d），（e）和（f）的另外的烯属不饱和单体。

    POWDER COATING SUSPENSIONS (POWDER SLURRIES) AND POWDER COATING MATERIALS, THEIR PREPARATION AND USE
    4.
    发明申请
    POWDER COATING SUSPENSIONS (POWDER SLURRIES) AND POWDER COATING MATERIALS, THEIR PREPARATION AND USE 审中-公开
    粉末涂料悬浮液（粉末状态）和粉末涂料，其制备和使用

    公开(公告)号：US20100240824A1

    公开(公告)日：2010-09-23

    申请号：US12160389

    申请日：2007-01-10

    申请人： Christina Alpert ,  Heinz-Peter Rink ,  Werner-Alfons Jung ,  Elisabeth Wessling ,  Markus Oberhoff ,  Thomas Danner ,  Andreas Bauder

    发明人： Christina Alpert ,  Heinz-Peter Rink ,  Werner-Alfons Jung ,  Elisabeth Wessling ,  Markus Oberhoff ,  Thomas Danner ,  Andreas Bauder

    IPC分类号： C08L39/04

    CPC分类号： C09D5/027 ,  C09D5/033 ,  C09D7/45

    摘要： Disclosed herein is a powder coating suspension prepared in the presence of an emulsifier (A) by emulsifying a liquid component (B) in an aqueous medium (C) to give an aqueous emulsion of liquid particles (D); and cooling the emulsion of liquid particles (D); wherein the emulsifier (A) has a hydroxyl number of 50 to 250 mg KOH/g and is a copolymer prepared by copolymerizing in an aqueous medium (a1) a hydroxyl-containing, olefinically unsaturated monomer; and (a2) an olefinically unsaturated monomer selected from the group consisting of (a21) a monomer of the general formula R1R2C═CR3R4, wherein R1, R2, R3, and R4 are independently hydrogen atoms or substituted or unsubstituted alkyl, cycloalkyl, alkylcycloalkyl, cycloalkylalkyl, aryl, alkylaryl, cycloalkylaryl, arylalkyl or arylcycloalkyl radicals, with the proviso that at least two of R1, R2, R3, and R4 are aryl, arylalkyl or arylcycloalkyl radicals; (a22) an olefinically unsaturated terpene hydrocarbon; and (a23) a dimeric alpha-alkylvinylaromatic.

    摘要翻译： 本文公开了通过在水性介质（C）中乳化液体组分（B）而在乳化剂（A）存在下制备的粉末涂料悬浮液，得到液体颗粒（D）的水性乳液; 并冷却液体颗粒（D）的乳液; 其中所述乳化剂（A）的羟值为50-250mgKOH / g，并且是通过在水性介质（a1）中共聚含羟基的烯属不饱和单体制备的共聚物; 和（a2）选自（a21）通式为R 1 R 2 C = CR 3 R 4的单体的烯属不饱和单体，其中R 1，R 2，R 3和R 4独立地为氢原子或取代或未取代的烷基，环烷基，烷基环烷基， 环烷基烷基，芳基，烷基芳基，环烷基芳基，芳基烷基或芳基环烷基，条件是R 1，R 2，R 3和R 4中的至少两个是芳基，芳基烷基或芳基环烷基; （a22）烯属不饱和萜烯烃; 和（a23）二聚α-烷基乙烯基芳族化合物。

    OLIGOMERIC URETHANE ACRYLATES, THEIR PREPARATION AND USE
    6.
    发明申请
    OLIGOMERIC URETHANE ACRYLATES, THEIR PREPARATION AND USE 审中-公开
    低聚脲丙烯酸酯，其制备和使用

    公开(公告)号：US20090306422A1

    公开(公告)日：2009-12-10

    申请号：US12162513

    申请日：2007-02-09

    申请人： Maxime Allard ,  Heinz-Peter Rink ,  Werner-Alfons Jung ,  Jennifer Moebius

    发明人： Maxime Allard ,  Heinz-Peter Rink ,  Werner-Alfons Jung ,  Jennifer Moebius

    IPC分类号： C07C271/06

    CPC分类号： C08G18/8175 ,  C09D175/16

    摘要： An oligomeric urethane acrylate composition is disclosed. The composition comprises, on average per molecule, at least two structural units of the general formula I: R{—X—CH2—CH(—CH2—O—(O)—CR1═CH2)[—O—C(O)—NH—]}n (I), where n is a number from 1 to 6, R is a monovalent to hexavalent organic radical, X is oxygen atom or —C(O)—O— radical linked by the carbon atom to the radical R, and R1 is hydrogen atom, halogen atom, nitrile group, substituted or unsubstituted alkyl group having 1 to 6 carbon atoms, substituted or unsubstituted cycloalkyl group having 3 to 6 carbon atoms, or substituted or unsubstituted aryl group having 6 to 10 carbon atoms. Also disclosed are processes for preparing and using the compositions.

    摘要翻译： 公开了低聚氨基甲酸酯丙烯酸酯组合物。 该组合物平均每分子包含至少两个通式I的结构单元：R（-X-CH 2 -CH（-CH 2 -O-（O）-CR 1 -CH 2）] - [（O）-NH - ]} n（I），其中n是1至6的数，R是一价至六价有机基团，X是氧原子或被碳原子连接到基团R的-C（O）-O-基团 R 1为氢原子，卤原子，腈基，取代或未取代的碳原子数为1〜6的烷基，取代或未取代的碳原子数为3〜6的环烷基，取代或未取代的碳数为6〜10的芳基。 还公开了制备和使用组合物的方法。

    Continuous method for the production of powder paint suspensions (powder slurries) and powder paints
    7.
    发明授权
    Continuous method for the production of powder paint suspensions (powder slurries) and powder paints 失效
    用于生产粉末涂料悬浮液（粉末浆料）和粉末涂料的连续方法

    公开(公告)号：US07064156B2

    公开(公告)日：2006-06-20

    申请号：US10474859

    申请日：2002-05-24

    申请人： Heinz-Peter Rink ,  Werner-Alfons Jung ,  Michael Stang ,  Heik Wolf

    发明人： Heinz-Peter Rink ,  Werner-Alfons Jung ,  Michael Stang ,  Heik Wolf

    IPC分类号： C08J3/05

    CPC分类号： B82Y30/00 ,  C08J3/16 ,  C09D5/02 ,  C09D5/03

    摘要： Powder coating materials prepared by (1) mixing at least two liquid components comprising in each case at least one liquid starting product in a static mixer, to give a molecularly disperse and/or finely dispersed liquid mixture, (2) emulsifying the liquid mixture (1) in an aqueous medium in a dispersing unit, to give an aqueous emulsion of liquid particals, (3) cooling the emulsion (2) so that a suspension of dimensionally stable particles is formed, (4) isolating the dimensionally stable particles from the suspension (3) or alternatively (3) isolating the dimensionally stable particles directly from the emulsion (2); and also processes for preparing them and their use as coating materials, adhesives, and sealing compounds or to prepare such compositions.

    摘要翻译： 粉末涂料通过（1）混合至少两种液体组分，每种液体组分在每种情况下在静态混合器中至少包含一种液体起始物，得到分子分散和/或细分散的液体混合物，（2）乳化液体混合物 1）在分散单元的水性介质中，得到液体部分的水性乳液，（3）冷却乳液（2），使得形成尺寸稳定的颗粒的悬浮液，（4）将尺寸稳定的颗粒从 悬浮液（3）或（3）直接从乳液（2）分离尺寸稳定的颗粒; 以及它们的制备方法及其作为涂料，粘合剂和密封化合物的用途，或制备这种组合物。