摘要:
Acicular ferrimagnetic iron oxides are prepared by a process in which iron (III) oxide hydroxide consisting essentially of lepidocrocite is reduced at from 350.degree. to 600.degree. C. by means of an organic compound which is a synthetic polymer with a molecular weight of from 3,000 to 40,000 to give magnetite, which, if desired, is subsequently partially or completely oxidized with an oxygen-containing gas at from 200.degree. to 450.degree. C.
摘要:
Acicular ferromagnetic metal particles consisting essentially of iron are prepared by a process wherein acicular iron(III) oxide hydroxide provided with a shape-stabilizing surface coating, or iron(III) oxide obtained therefrom by dehydration, is reduced by means of a decomposable organic compound and hydrogen.
摘要:
A process for the manufacture of acicular ferrimagnetic iron oxide by converting acicular iron(III) oxide hydroxide at from 300.degree. to 650.degree. C., by treatment with an organic compound which decomposes in this temperature range in the presence of iron oxide, the iron(III) oxide hydroxide used for the reaction being a lepidocrocite which has been heat-treated at from 300.degree. to 700.degree. C.
摘要:
A process for the preparation of acicular ferrimagnetic iron oxides by reducing gamma-iron(III) oxide hydroxide to magnetite, at from 280.degree. to 620.degree. C., by means of an organic compound which is decomposable at this temperature in the presence of iron oxide, and, optionally, a stream of reducing gas, and, if desired, then oxidizing the magnetite with oxygen-containing gases, at from 150.degree. to 450.degree. C., to acicular ferrimagnetic iron oxide of the formula FeO.sub.x, where x is from above 1.33 to 1.50, wherein the organic compound used for the reduction is a non-polar glycerol ester of a fatty acid which is introduced into the aqueous reaction suspension during the preparation of the gamma-iron(III) oxide hydroxide.
摘要:
A process for the manufacture of acicular ferrimagnetic iron oxide by reducing heat-treated acicular iron(III) oxide hydroxide with an organic compound which decomposes in the presence of iron oxide at from 450.degree. to 650.degree. C., followed by at least partial oxidation with an oxygen-containing gas at from 200.degree. to 500.degree. C., wherein the iron(III) oxide hydroxide employed is heat-treated at from 450.degree. to 700.degree. C. and has a surface area, measured by the BET method, of from 10 to 23 m.sup.2 /g.
摘要:
A process for the manufacture of acicular ferromagnetic iron particles by heating a goethite, provided with a shape-stabilizing surface coating, at 250.degree.-450.degree. C. in an atmosphere containing water vapor at a partial pressure of not less than 30 mbar, to give alpha-iron(III) oxide, and reducing this material with hydrogen at 275.degree.-425.degree. C., and the use of the iron particles thus obtained as magnetic material in the production of magnetic recording media.
摘要:
A process for the manufacture of acicular ferrimagnetic iron oxide by dehydrating acicular iron(III) oxide hydroxides to give acicular iron(III) oxides, then reducing these iron(III) oxides at from 300.degree. to 650.degree. C. by means of an organic compound which decomposes in this temperature range, and oxidizing the reduced product with an oxygen-containing gas at from 200.degree. to 500.degree. C., wherein the acicular iron(III) oxide hydroxides employed consist of a mixture of goethite and lepidocrocite, containing at least 60% of the latter, and the dehydration is carried out at from 250.degree. to 700.degree. C.
摘要:
A process for the manufacture of acicular magnetic iron oxides which consist of a core of gamma-iron(III) oxide and a shell of a magnetite modified with zinc(II) ions and/or manganese(II) ions and which contain, based on the total modified gamma-iron(III) oxide, from 0.1 to 20 percent by weight of iron(II) ions, from 0.1 to 10 percent by weight of zinc(II) ions and/or from 0.1 to 10 percent by weight of manganese(II) ions.
摘要:
Ferromagnetic metal particles, consisting essentially of iron and comprising a core, containing not less than 85% by weight of metallic iron, and an iron oxide plus chromium oxide surface layer surrounding this core, which layer additionally contains one or more elements selected from the group comprising zinc, phosphorus in the form of phosphate, aluminum, calcium, strontium, barium, cadmium, lead, cobalt and nickel in a total amount of not more than 9.5% by weight, based on the total amount of the metal particles, and a process for the production of such particles.
摘要:
A process for the manufacture of acicular ferromagnetic iron particles by reducing an iron(III) oxide which carries a shape-stabilizing surface coating and has been produced by heating acicular iron(III) oxide hydroxide at 250.degree.-390.degree. C. in an atmosphere containing water vapor at a partial pressure of not less than 30 mbar, with hydrogen at 275.degree.-425.degree. C.