Toluene diisocyanate residue-based compositions having reduced acid
values
    1.
    发明授权
    Toluene diisocyanate residue-based compositions having reduced acid values 失效
    基于甲苯二异氰酸酯残基的组合物具有降低的酸值

    公开(公告)号:US5837794A

    公开(公告)日:1998-11-17

    申请号:US958282

    申请日:1997-10-27

    摘要: TDI residue-based urethane-filled isocyanate compositions are produced by reacting a TDI residue satisfying specified criteria with a monofunctional alcohol in amounts such that the equivalent ratio of isocyanate groups to hydroxyl groups is from about 0.9:1 to about 1:0.9. This reaction product is then dissolved in a diisocyanate or polyisocyanate before, during or after reaction of that product with an epoxide having an epoxide equivalent weight of from about 44 to about 400 at a temperature of up to 120.degree. C. These TDI residue-based urethane-filled isocyanate compositions are particularly useful in the production of polyurethanes.

    摘要翻译: 通过使满足特定标准的TDI残基与单官能醇反应,使得异氰酸酯基与羟基的当量比为约0.9:1至约1:0.9来制备TDI残余物聚氨酯填充的异氰酸酯组合物。 然后在高达120℃的温度下,该反应产物在该产物与环氧当量为约44至约400的环氧化物反应之前,期间或之后溶解在二异氰酸酯或多异氰酸酯中。这些基于TDI残基 聚氨酯填充的异氰酸酯组合物特别可用于生产聚氨酯。

    Liquification of diphenylmethane diisocyanate by partially reacting the
isocyanate groups with blocking agents
    2.
    发明授权
    Liquification of diphenylmethane diisocyanate by partially reacting the isocyanate groups with blocking agents 失效
    通过使异氰酸酯基团与封端剂部分反应来二苯基甲烷二异氰酸酯的液化

    公开(公告)号:US5288899A

    公开(公告)日:1994-02-22

    申请号:US085235

    申请日:1993-06-30

    摘要: The present invention relates to a liquid, storage-stable isocyanate having a viscosity of less than 100,000 mPa.s at 25.degree. C. and an isocyanate content of from about 10 to 29% by weight, and is prepared by reacting a solid or semi-solid diphenylmethane diisocyanate with a blocking agent. More generally, the liquid isocyanate is prepared by reacting the solid or semi-solid diphenylmethane diisocyanate with the blocking agent in quantities such that from 7 to 55% of the isocyanate groups are blocked. Preferred blocking agents are the ketoximes, and mixtures thereof.

    摘要翻译: 本发明涉及一种液体储存稳定的异氰酸酯,其在25℃下的粘度小于100,000mPa.s,异氰酸酯含量为约10至29重量%,并且通过使固体或半 固体二苯基甲烷二异氰酸酯与封闭剂。 更一般地,液体异氰酸酯通过固体或半固体二苯基甲烷二异氰酸酯与封闭剂反应制备,使得7至55%的异氰酸酯基团被封闭。 优选的封闭剂是酮肟及其混合物。

    Azeotropic compositions of 1,3-dioxolane and hydrocarbons having 5 or 6 carbon atoms and the use thereof in the production of foams
    5.
    发明授权
    Azeotropic compositions of 1,3-dioxolane and hydrocarbons having 5 or 6 carbon atoms and the use thereof in the production of foams 失效
    具有5或6个碳原子的1,3-二氧戊环和烃的共沸组合物及其在泡沫体生产中的用途

    公开(公告)号:US06358908B1

    公开(公告)日:2002-03-19

    申请号:US08410177

    申请日:1995-03-24

    IPC分类号: C11D726

    CPC分类号: C08J9/149 C08J2375/04

    摘要: Azeotropic compositions made up of (a) from about 4 to about 50% by weight 1,3-dioxolane and (b) one compound selected from (1) about 75 to about 96% by weight cyclopentane, (2) about 60 to about 79% by weight 2-methyl pentane, (3) about 59 to about 77% by weight 3-methyl pentane, and (4) about 50 to about 69% by weight n-hexane in which the sum of the weight percent of (a) plus weight percent of (b) is approximately 100 percent are used as blowing agents in the production of polyurethane/polyurea foams.

    摘要翻译: 由(a)约4至约50重量%的1,3-二氧戊环组成的共沸组合物和(b)选自(1)约75至约96重量%的环戊烷的化合物,(2)约60至约 79重量%的2-甲基戊烷,(3)约59-约77重量%的3-甲基戊烷,和(4)约50-约69重量%的正己烷,其中( a)加上(b)的重量百分比约为100%用作生产聚氨酯/聚脲泡沫体中的发泡剂。