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    Polyolefin production with a high performance support for a metallocene catalyst system
    2.
    发明授权
    Polyolefin production with a high performance support for a metallocene catalyst system 有权
    聚烯烃生产具有高性能支持的茂金属催化剂体系

    公开(公告)号：US08436112B2

    公开(公告)日：2013-05-07

    申请号：US12013774

    申请日：2008-01-14

    申请人： Jun Tian ,  William Gauthier ,  David Rauscher ,  Shady Henry

    发明人： Jun Tian ,  William Gauthier ,  David Rauscher ,  Shady Henry

    IPC分类号： C08F4/52 ,  C08F4/64 ,  C08F4/76

    CPC分类号： C08F4/76 ,  C08F4/65912 ,  C08F4/65927 ,  C08F10/00 ,  Y10T428/2982 ,  C08F4/65916 ,  C08F110/06 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24 ,  C08F2500/15

    摘要： The invention is directed to a metallocene catalyst system comprising an inert silica support having pores with a peak pore volume of greater than about 0.115 mL/g at a pore diameter between about 250 Angstroms and about 350 Angstroms, and an alumoxane activator, with the metallocene being bound substantially throughout the support. The activator is grafted to the support in a solvent at a reflux temperature of toluene to obtain an aluminoxane on silica, and a metallocene component is added to make a MCS having a metallocene loading of about 2 wt %. This facilitates the production of metallocene catalyst systems having increased catalytic activity than previously recognized that is at least about 20 percent higher than the catalytic activity for a metallocene loading of about 1 wt % where the activator is grafted to the support at room temperature.

    摘要翻译： 本发明涉及一种茂金属催化剂体系，其包含惰性二氧化硅载体，其具有在孔直径约250埃至约350埃之间具有大于约0.115mL / g的峰孔体积的孔，以及铝氧烷活化剂与茂金属 在整个支撑体上大体上被束缚。 将活化剂在甲苯的回流温度下在溶剂中接枝到载体上，得到二氧化硅上的铝氧烷，并加入金属茂组分以制备茂金属负载量为约2重量％的MCS。 这促进了催化活性增加的茂金属催化剂体系的生产，其催化活性比之前所公认的高约1％（重量），其中活化剂在室温下接枝到载体上的金属茂负载量的催化活性高至少约20％。

    Polyolefin Production with a High Performance Support for a Metallocene Catalyst System
    3.
    发明申请
    Polyolefin Production with a High Performance Support for a Metallocene Catalyst System 有权
    具有高性能支撑金属茂催化剂体系的聚烯烃生产

    公开(公告)号：US20080194399A1

    公开(公告)日：2008-08-14

    申请号：US12013774

    申请日：2008-01-14

    申请人： Jun Tian ,  William Gauthier ,  David Rauscher ,  Shady Henry

    发明人： Jun Tian ,  William Gauthier ,  David Rauscher ,  Shady Henry

    IPC分类号： B01J31/00

    CPC分类号： C08F4/76 ,  C08F4/65912 ,  C08F4/65927 ,  C08F10/00 ,  Y10T428/2982 ,  C08F4/65916 ,  C08F110/06 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24 ,  C08F2500/15

    摘要： The invention is directed to a metallocene catalyst system comprising an inert silica support having pores with a peak pore volume of greater than about 0.115 mL/g at a pore diameter between about 250 Angstroms and about 350 Angstroms, and an alumoxane activator, with the metallocene being bound substantially throughout the support. The activator is grafted to the support in a solvent at a reflux temperature of toluene to obtain an aluminoxane on silica, and a metallocene component is added to make a MCS having a metallocene loading of about 2 wt %. This facilitates the production of metallocene catalyst systems having increased catalytic activity than previously recognized that is at least about 20 percent higher than the catalytic activity for a metallocene loading of about 1 wt % where the activator is grafted to the support at room temperature.

    摘要翻译： 本发明涉及一种茂金属催化剂体系，其包含惰性二氧化硅载体，其具有在孔直径约250埃至约350埃之间具有大于约0.115mL / g的峰孔体积的孔，以及铝氧烷活化剂与茂金属 在整个支撑体上大体上被束缚。 将活化剂在甲苯的回流温度下在溶剂中接枝到载体上，得到二氧化硅上的铝氧烷，并加入金属茂组分以制备茂金属负载量为约2重量％的MCS。 这促进了催化活性增加的茂金属催化剂体系的生产，其催化活性比之前所公认的高约1％（重量），其中活化剂在室温下接枝到载体上的金属茂负载量的催化活性高至少约20％。

    Process for increasing ethylene incorporation into random copolymers
    5.
    发明申请
    Process for increasing ethylene incorporation into random copolymers 审中-公开
    增加乙烯掺入无规共聚物的方法

    公开(公告)号：US20060247394A1

    公开(公告)日：2006-11-02

    申请号：US11117872

    申请日：2005-04-29

    申请人： William Gauthier ,  Jun Tian ,  Shady Henry ,  Nathan Williams

    发明人： William Gauthier ,  Jun Tian ,  Shady Henry ,  Nathan Williams

    IPC分类号： C08F2/00

    CPC分类号： C08F210/16 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F210/06 ,  C08F4/65927 ,  C08F2500/03 ,  C08F2500/20

    摘要： Random copolymers may be prepared using a process that includes polymerizing a mixture of monomers including at least propylene and ethylene monomer, in the presence of a catalyst system including a metallocene catalyst having the general structure: racemic-X(2-R1-4-R2-Ind)2MCl2 wherein M is a Group 4, 5 or 6 transition metal, or a lanthanide or actinide series metal; X is a structural bridge imparting stereorigidity; R1 is hydrogen or an alkyl, aryl or a substitution moiety; R2 is hydrogen, or a C1-C4 alkyl; and Ind is an indenyl group. The copolymers are prepared under reaction conditions suitable to form a copolymer, wherein the copolymer has a higher level of ethylene incorporation than a corresponding polymer formed under otherwise identical reaction conditions except that a different bisindeny metallocene catalyst having a 4-indenyl substitution larger than 4 carbons is used. The copolymers may have a lower melt temperature than the corresponding polymers. The resulting copolymers may be used to prepare articles of manufacture including, but not limited to films, fibers and injection molded articles.

    摘要翻译： 无规共聚物可以使用包括聚合包含至少丙烯和乙烯单体的单体的混合物在内的方法在包括具有以下通式结构的茂金属催化剂的催化剂体系存在下的方法来制备： 线式“end =”lead“？>外消旋-X（2-R 1 - 4-R 2 -Ind）2 MCl 其中M是第4,5或6族过渡金属，或镧系元素或锕系元素系列金属 ; X是赋予立体感的结构桥梁; R1是氢或烷基，芳基或取代部分; R 2是氢或C 1 -C 4烷基; 而Ind是茚基。 共聚物在适于形成共聚物的反应条件下制备，其中共聚物具有比在其他相同反应条件下形成的相应聚合物更高的乙烯掺入水平，不同之处在于使用具有4-茚基取代基大于4个碳原子的不同的双茚基茂金属催化剂 用来。 共聚物可以具有比相应聚合物更低的熔融温度。 所得共聚物可用于制备制品，包括但不限于薄膜，纤维和注模制品。

    POLYAMIDE SUPPORTED METALLOCENE CATALYSTS
    8.
    发明申请
    POLYAMIDE SUPPORTED METALLOCENE CATALYSTS 失效
    聚酰胺支持的金属催化剂

    公开(公告)号：US20050049372A1

    公开(公告)日：2005-03-03

    申请号：US10648716

    申请日：2003-08-26

    申请人： David Rauscher ,  William Gauthier ,  Shady Henry ,  Kai Hortmann

    发明人： David Rauscher ,  William Gauthier ,  Shady Henry ,  Kai Hortmann

    IPC分类号： C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F110/06 ,  C08F4/44

    CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65927 ,  C08F110/06 ,  Y02P20/52 ,  Y10S526/904 ,  Y10S526/943 ,  C08F4/65916 ,  C08F2500/16 ,  C08F2500/15 ,  C08F2500/12 ,  C08F2500/18

    摘要： Supported stereospecific catalysts and processes for the stereotactic propagation of a polymer chain derived from ethylenically unsaturated monomers such as the polymerization of propylene to produce syndiotactic polypropylene or isotactic polypropylene. The supported catalyst comprises a stereospecific metallocene catalyst component and a co-catalyst component comprising an alkylalumoxane. Both the metallocene catalyst component and the co-catalyst component are supported on a particulate polyamide support comprising spheroidical particles of a polyamide having an average diameter with the range of 5-60 microns, and a porosity permitting distribution of a portion of the co-catalyst within the pore volume of the polyamide particles while retaining a substantial portion on the surface of the particles. The polyamide support is characterized by relatively low surface area, specifically a surface area less than 20 square meters per gram. The metallocene component can take the form of a single metallocene two or more co-supported metallocenes.

    摘要翻译： 支持的立体定向催化剂和用于衍生自烯属不饱和单体的聚合物链的立体定向扩散的方法，例如丙烯聚合以产生间同立构聚丙烯或全同立构聚丙烯。 载体催化剂包括立体特异性茂金属催化剂组分和包含烷基铝氧烷的助催化剂组分。 金属茂催化剂组分和助催化剂组分均负载在包含平均直径为5-60微米范围的聚酰胺球形颗粒的颗粒聚酰胺载体上，孔隙率允许一部分助催化剂分配 在聚酰胺颗粒的孔体积内，同时保留颗粒表面上的实质部分。 聚酰胺载体的特征在于相对较低的表面积，特别是小于20平方米/克的表面积。 茂金属组分可以采用单一茂金属两种或多种共支撑金属茂的形式。

    Transition Metal Catalyst Systems and Formation Thereof
    9.
    发明申请
    Transition Metal Catalyst Systems and Formation Thereof 有权
    过渡金属催化剂体系及其形成

    公开(公告)号：US20100099834A1

    公开(公告)日：2010-04-22

    申请号：US12642896

    申请日：2009-12-21

    申请人： Jun Tian ,  William Gauthier ,  Joseph Thorman ,  Shady Henry

    发明人： Jun Tian ,  William Gauthier ,  Joseph Thorman ,  Shady Henry

    IPC分类号： C08F4/52 ,  C08F4/76

    CPC分类号： C08F10/00 ,  C08F4/65927 ,  C08F110/06 ,  Y10S526/943 ,  C08F4/65912 ,  C08F4/65916 ,  C08F2500/18 ,  C08F2500/03

    摘要： Catalyst systems and methods of forming the catalyst systems are described herein. The methods generally include contacting a support material with an activator to form a support composition, contacting a component with at least a portion of an aluminum containing compound including TIBAl, wherein the component is selected from the support composition, the transition metal catalyst compound and combinations thereof and contacting the support composition with a transition metal catalyst compound to form a supported catalyst system.

    摘要翻译： 本文描述了形成催化剂体系的催化剂体系和方法。 所述方法通常包括使支撑材料与活化剂接触以形成载体组合物，使组分与包含TIBAl的含铝化合物的至少一部分接触，其中所述组分选自载体组合物，过渡金属催化剂化合物和组合 并使载体组合物与过渡金属催化剂化合物接触以形成负载型催化剂体系。

    Transition metal catalyst and formation thereof
    10.
    发明授权
    Transition metal catalyst and formation thereof 有权
    过渡金属催化剂及其形成

    公开(公告)号：US07683002B2

    公开(公告)日：2010-03-23

    申请号：US11492351

    申请日：2006-07-25

    申请人： Jun Tian ,  William Gauthier ,  Joseph Thorman ,  Shady Henry

    发明人： Jun Tian ,  William Gauthier ,  Joseph Thorman ,  Shady Henry

    IPC分类号： C08F4/642 ,  C08F4/6592 ,  B01J31/14 ,  B01J31/22

    CPC分类号： C08F10/00 ,  C08F4/65927 ,  C08F110/06 ,  Y10S526/943 ,  C08F4/65912 ,  C08F4/65916 ,  C08F2500/18 ,  C08F2500/03

    摘要： Catalyst systems and methods of forming the catalyst systems are described herein. The methods generally include contacting a support material with an activator to form a support composition, contacting a component with at least a portion of an aluminum containing compound including TIBAl, wherein the component is selected from the support composition, the transition metal catalyst compound and combinations thereof and contacting the support composition with a transition metal catalyst compound to form a supported catalyst system.

    摘要翻译： 本文描述了形成催化剂体系的催化剂体系和方法。 所述方法通常包括使支撑材料与活化剂接触以形成载体组合物，使组分与包含TIBAl的含铝化合物的至少一部分接触，其中所述组分选自载体组合物，过渡金属催化剂化合物和组合 并使载体组合物与过渡金属催化剂化合物接触以形成负载型催化剂体系。