摘要:
An electroluminescent polymer comprises a main chain and a plurality of side chains, each of the side chains comprising an electroluminescent group and a flexible spacer connecting the electroluminescent group to the main chain, the spacers and the main chain being such that the electroluminescent groups are not conjugated with one another. The nature of the main chain and the spacer groups can be varied to enhance solubility, film-forming ability and other characteristics of the polymer, without significantly changing the electroluminescent properties of the polymer.
摘要:
Electroluminescent devices have, as the active layer, a polymer having a chain comprising a plurality of electroluminescent groupings, adjacent pairs of the electroluminescent groupings being connected via two benzene rings linked by only a single covalent bond, at least one of the benzene rings bearing, at a position ortho to the covalent bond, a substituent of sufficient size that the two benzene rings are essentially not conjugated with each other. Preferred electroluminescent groupings comprise a chain of three or more para-phenylene groups connected to one another by amide, carboxy, ester, urea, urethane or vinyl groups. The polymers have a fixed conjugation length with predictable electroluminescent properties.
摘要:
Electroluminescent devices have, as the active layer, a polymer having a chain comprising a plurality of electroluminescent groupings, adjacent pairs of the electroluminescent groupings being connected via two benzene rings linked to each other only by a single covalent bond, at least one of the benzene rings bearing, at a position ortho to the covalent bond, a substituent of sufficient size that the length of the bond connecting the two benzene rings is not less than 1.495 Angstroms. Preferred electroluminescent groupings comprise a chain of three or more para-phenylene groups connected to one another by amide, carboxy, ester, urea, urethane or vinyl groups. The polymers have a fixed conjugation length with predictable electroluminescent properties.
摘要:
An imaging process uses an imaging medium comprising a polymer having a plurality of first groups. This polymer is imagewise contacted with an imaging reagent comprising a plurality of second groups, thus causing, in the areas of the medium exposed to the imaging reagent, the second groups to react with the first groups and form a colored material, and thereby forming an image on the imaging medium. One of the first and second groups comprises a benzotriazinone or benzothiatriazine-4,4-dioxide benzotriazinone moiety and the other comprises a naphthol or a pyrazalone moiety.
摘要:
Liquid crystal compounds which show a ferroelectric phase and which exhibit high spontaneous polarization values and smectic behavior over a range of temperatures have the formula ##STR1## wherein R.sup.1 is alkyl of from 1 to 16 carbon atoms; alkoxy; haloalkyl; alkoxyalkyl, wherein the alkoxy substituent thereof comprises a chain of carbon atoms including one or more oxygen ether atoms; or alkoxyalkoxy, wherein the alkoxy substituent thereof comprises a chain of carbon atoms including one or more oxygen ether atoms; R.sup.2 is alkyl of from 1 to 4 carbon atoms; each of R.sup.3 and R.sup.4 is alkylene; n is an integer 1 or 2; and W is alkyl of from 1 to 12 carbon atoms or fluoroalkyl of the formula ##STR2## wherein each of X, Y and Z is hydrogen or fluorine, m is zero or an integer from 1 to 6, and at least one of X, Y and Z is fluorine when m is zero.
摘要翻译:显示强电介质相并且在一定温度范围内表现出高自发极化值和近晶行为的液晶化合物具有下式:其中R 1为1至16个碳原子的烷基; 烷氧基 卤代烷基 烷氧基烷基,其中烷氧基取代基包括一个包含一个或多个氧原子的碳原子链; 或烷氧基烷氧基,其中烷氧基取代基包含一个包含一个或多个氧原子的碳原子链; R 2是1至4个碳原子的烷基; R 3和R 4各自为亚烷基; n是整数1或2; W为1〜12个碳原子的烷基或式“IMAGE”的氟代烷基,其中X,Y和Z各自为氢或氟,m为0或1〜6的整数,X, 当m为0时,Y和Z为氟。
摘要:
Disclosed are smetic liquid crystal compounds exhibiting ferroelectric behavior and having the formulaR.sup.1 --OR.sup.2).sub.a O--R.sup.3).sub.b Z--R*wherein R.sup.1 is alkyl or alkoxyalkyl, R.sup.2 and R.sup.3 are each alkylene, a is an integer of at least one, b is zero or one, R* is an optically active group containing an asymmetric center and --Z-- is an organic divalent core radical having parallel or coaxially extending bonds at the terminal ends thereof, the core radical having an axial ratio of at least two and being characterized by an essentially rigid and flat molecular structure. Presence of the ether-interrupted hydrocarbon tail moiety at the terminal end of the compounds provides a lowering in observed temperatures of phase transition.
摘要:
Aromatic polyesters exhibiting melt processability are disclosed. The polyesters comprise repeating units of the formula ##STR1## wherein X is hydrogen, halogen, alkyl or nitro. The polyesters exhibit low-melting properties, melt processability and melt anisotropy. The aromatic polyesters can be melt processed to films and fibers.
摘要:
Ethylenically unsaturated polymerizable acrylic (or methacrylic) monomers having pendant halogenated carbazole moieties, useful for the production of high refractive index polymers, are disclosed. The monomers are useful for the bonding of optical elements in the fabrication of optical devices.
摘要:
A class of polyesters comprising recurring units having certain bis(trifluoromethyl)biphenylene radicals is disclosed. The polyesters exhibit favorable solubility properties in certain organic solvents so as to facilitate the production of the polyesters via polycondensation methods to film- and fiber-forming molecular weights. Monomeric compounds comprising a bis(trifluoromethyl)biphenylene radical and useful for the production of the polyesters are also disclosed.
摘要:
A class of polyesters comprising recurring units having certain bis(trifluoromethyl)biphenylene radicals is disclosed. The polyesters exhibit favorable solubility properties in certain organic solvents so as to facilitate the production of the polyesters via polycondensation methods to film- and fiber-forming molecular weights. Monomeric compounds comprising a bis(trifluoromethyl)biphenylene radical and useful for the production of the polyesters are also disclosed.