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公开(公告)号：US5786431A
公开(公告)日：1998-07-28
申请号：US478126
申请日：1995-06-07
IPC分类号： C07C2/32 , C08F4/69 , C08F10/00 , C08F110/02
CPC分类号： C08F10/00 , C07C2/32 , C07C2531/22 , C08F110/02
摘要： Novel chromium-containing compounds are prepared by forming a mixture of a chromium salt, a metal amide, and an ether. These novel chromium-containing, or chromium pyrrolide, compounds, with a metal alkyl and an unsaturated hydrocarbon, can be used as a cocatalyst system in the presence of an olefin polymerization catalyst system to produce a comonomer in-situ. The resultant polymer, although produced from predominately one monomer, has characteristics of a copolymer.
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公开(公告)号：US5451645A
公开(公告)日：1995-09-19
申请号：US109855
申请日：1993-08-20
IPC分类号： C07C2/32 , C08F4/69 , C08F10/00 , C08F110/02
CPC分类号： C08F10/00 , C07C2/32 , C07C2531/22 , C08F110/02
摘要： Novel chromium-containing compounds are prepared by forming a mixture of a chromium salt, a metal amide, and an ether. These novel chromium-containing, or chromium pyrrolide, compounds, with a metal alkyl and an unsaturated hydrocarbon, can be used as a cocatalyst system in the presence of an olefin polymerization catalyst system to produce a comonomer in-situ. The resultant polymer, although produced from predominately one monomer, has characteristics of a copolymer.
摘要翻译： 通过形成铬盐，金属酰胺和醚的混合物制备新的含铬化合物。 这些具有金属烷基和不饱和烃的新颖的含铬或铬吡咯化合物可以在烯烃聚合催化剂体系的存在下用作助催化剂体系，以原位产生共聚单体。 所得到的聚合物虽然主要由一种单体制成，但具有共聚物的特性。
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公开(公告)号：US5814575A
公开(公告)日：1998-09-29
申请号：US485344
申请日：1995-06-07
IPC分类号： B01J23/26 , B01J31/14 , B01J31/16 , B01J31/18 , B01J31/22 , B01J37/02 , C07C2/32 , C07F11/00 , C08F4/69 , C08F4/78 , C08F10/00
CPC分类号： B01J31/2208 , B01J23/26 , B01J31/1616 , B01J31/181 , B01J31/2213 , B01J37/0203 , C07C2/32 , C07F11/005 , C08F10/00 , B01J2231/20 , B01J2531/0205 , B01J2531/62 , B01J31/143 , B01J31/2234 , C07C2531/12 , C07C2531/22 , Y02P20/588
摘要： Novel chromium-containing compounds, such as, for example, chromium pyrrolides, are prepared by forming a mixture of a chromium salt, a metal amide, and an electron pair donor solvent, such as, for example, an ether. These novel chromium-containing, or chromium pyrrolide, compounds can be used either unsupported or supported on an inorganic oxide support, with a metal alkyl and an unsaturated hydrocarbon, to trimerize, oligomerize, and/or polymerize olefins.
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公开(公告)号：US5763723A
公开(公告)日：1998-06-09
申请号：US485544
申请日：1995-06-07
IPC分类号： B01J23/26 , B01J31/14 , B01J31/16 , B01J31/18 , B01J31/22 , B01J37/02 , C07C2/32 , C07F11/00 , C08F4/69 , C08F4/78 , C08F10/00
CPC分类号： B01J31/2208 , B01J23/26 , B01J31/1616 , B01J31/181 , B01J31/2213 , B01J37/0203 , C07C2/32 , C07F11/005 , C08F10/00 , B01J2231/20 , B01J2531/0205 , B01J2531/62 , B01J31/143 , B01J31/2234 , C07C2531/12 , C07C2531/22 , Y02P20/588
摘要： Novel chromium-containing compounds, such as, for example, chromium pyrrolides, are prepared by forming a mixture of a chromium salt, a metal amide, and an electron pair donor solvent, such as, for example, an ether. These novel chromium-containing, or chromium pyrrolide, compounds can be used either unsupported or supported on an inorganic oxide support, with a metal alkyl and an unsaturated hydrocarbon, to trimerize, oligomerize, and/or polymerize olefins.
摘要翻译： 通过形成铬盐，金属酰胺和电子对供体溶剂（例如醚）的混合物来制备新的含铬化合物，例如吡咯化铬。 这些新颖的含铬或铬吡咯化合物可以无支撑或负载在无机氧化物载体上，与金属烷基和不饱和烃一起使用以使烯烃三聚，低聚和/或聚合。
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5.发明授权
公开(公告)号：US5523507A
公开(公告)日：1996-06-04
申请号：US290048
申请日：1994-07-29
IPC分类号： B01J23/26 , B01J31/14 , B01J31/16 , B01J31/18 , B01J31/22 , B01J37/02 , C07C2/32 , C07F11/00 , C08F4/69 , C08F4/78 , C08F10/00 , C07C2/30
CPC分类号： B01J31/2208 , B01J23/26 , B01J31/1616 , B01J31/181 , B01J31/2213 , B01J37/0203 , C07C2/32 , C07F11/005 , C08F10/00 , B01J2231/20 , B01J2531/0205 , B01J2531/62 , B01J31/143 , B01J31/2234 , C07C2531/12 , C07C2531/22 , Y02P20/588
摘要： Novel chromium-containing compounds, such as, for example, chromium pyrrolides, are prepared by forming a mixture of a chromium salt, a metal amide, and an electron pair donor solvent, such as, for example, an ether. These novel chromium-containing, or chromium pyrrolide, compounds can be used either unsupported or supported on an inorganic oxide support, with a metal alkyl and an unsaturated hydrocarbon, to trimerize, oligomerize, and/or polymerize olefins.
摘要翻译： 通过形成铬盐，金属酰胺和电子对供体溶剂（例如醚）的混合物来制备新的含铬化合物，例如吡咯化铬。 这些新颖的含铬或铬吡咯化合物可以无支撑或负载在无机氧化物载体上，与金属烷基和不饱和烃一起使用以使烯烃三聚，低聚和/或聚合。
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公开(公告)号：US5376612A
公开(公告)日：1994-12-27
申请号：US109858
申请日：1993-08-20
IPC分类号： B01J23/26 , B01J31/14 , B01J31/16 , B01J31/18 , B01J31/22 , B01J37/02 , C07C2/32 , C07F11/00 , C08F4/69 , C08F4/78 , C08F10/00
CPC分类号： B01J31/2208 , B01J23/26 , B01J31/1616 , B01J31/181 , B01J31/2213 , B01J37/0203 , C07C2/32 , C07F11/005 , C08F10/00 , B01J2231/20 , B01J2531/0205 , B01J2531/62 , B01J31/143 , B01J31/2234 , C07C2531/12 , C07C2531/22 , Y02P20/588
摘要： Novel chromium-containing compounds, such as, for example, chromium pyrrolides, are prepared by forming a mixture of a chromium salt, a metal amide, and an electron pair donor solvent, such as, for example, an ether. These novel chromium-containing, or chromium pyrrolide, compounds can be used either unsupported or supported on an inorganic oxide support, with a metal alkyl and an unsaturated hydrocarbon, to trimerize, oligomerize, and/or polymerize olefins.
摘要翻译： 通过形成铬盐，金属酰胺和电子对供体溶剂（例如醚）的混合物来制备新的含铬化合物，例如吡咯化铬。 这些新颖的含铬或铬吡咯化合物可以无支撑或负载在无机氧化物载体上，与金属烷基和不饱和烃一起使用以使烯烃三聚，低聚和/或聚合。
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公开(公告)号：US5393719A
公开(公告)日：1995-02-28
申请号：US194606
申请日：1994-02-10
IPC分类号： C08F10/00 , C08F110/02 , C08F4/24 , B01J31/00
CPC分类号： C08F10/00 , C08F110/02
摘要： Olefins can be polymerized in the presence of a catalyst system composition comprising chromium oxides supported on a inorganic oxide support, a pyrrole-containing compound and a non-hydrolyzed metal alkyl. The use of this type of polymerization catalyst in a polymerization process can produce an olefin comonomer in-situ, resulting in polymers having decreased density and increased branching.
摘要翻译： 烯烃可以在包含负载在无机氧化物载体上的铬氧化物，含吡咯化合物和非水解金属烷基的催化剂体系组合物存在下聚合。 在聚合过程中使用这种类型的聚合催化剂可以原位产生烯烃共聚单体，导致聚合物具有降低的密度和增加的支化。
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公开(公告)号：US5331070A
公开(公告)日：1994-07-19
申请号：US976124
申请日：1992-11-13
IPC分类号： C08F10/00 , C08F110/02 , C08F4/24
CPC分类号： C08F10/00 , C08F110/02
摘要： Olefins can be polymerized in the presence of a catalyst system composition comprising chromium supported on an inorganic oxide support, a pyrrole-containing compounds, and a metal alkyl. The use of this type of polymerization process can produce an olefin comonomer in-situ, resulting in polymers having decreased density and increased branching.
摘要翻译： 烯烃可以在包含负载在无机氧化物载体上的铬的催化剂体系组合物，含吡咯的化合物和金属烷基的存在下聚合。 使用这种类型的聚合方法可以原位产生烯烃共聚单体，导致聚合物具有降低的密度和增加的支化。
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公开(公告)号：US5340785A
公开(公告)日：1994-08-23
申请号：US23746
申请日：1993-02-26
CPC分类号： C08F10/00
摘要： Supported olefin polymerization catalyst systems can be produced using waste chromium compounds. Olefin polymers can be prepared using a catalyst system composition comprising a waste chromium compound and an alkyl aluminum compound, both supported on an inorganic oxide support, wherein at least a portion of the waste chromium compound is in a hexavalent state.
摘要翻译： 支持的烯烃聚合催化剂体系可以使用废铬化合物生产。 烯烃聚合物可以使用包含负载在无机氧化物载体上的废铬化合物和烷基铝化合物的催化剂体系组合物制备，其中至少一部分废铬化合物处于六价态。
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公开(公告)号：US5399539A
公开(公告)日：1995-03-21
申请号：US265572
申请日：1994-06-24
CPC分类号： C08F10/00
摘要： Supported olefin polymerization catalyst systems can be produced using waste chromium compounds. Olefin polymers can be prepared using a catalyst system composition comprising a waste chromium compound and an alkyl aluminum compound, both supported on an inorganic oxide support, wherein at least a portion of the waste chromium compound is in a hexavalent state.
摘要翻译： 支持的烯烃聚合催化剂体系可以使用废铬化合物生产。 烯烃聚合物可以使用包含负载在无机氧化物载体上的废铬化合物和烷基铝化合物的催化剂体系组合物制备，其中至少一部分废铬化合物处于六价态。
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