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公开(公告)号：US4155948A
公开(公告)日：1979-05-22
申请号：US805344
申请日：1977-06-10
IPC分类号： C08C19/44 , C08F8/30 , C08F293/00 , C08G8/38 , C08G12/46 , C08G18/10 , C08G18/69 , C08G18/83 , C08G81/00 , C08L61/10 , C08L9/06 , C08L61/24
CPC分类号： C08G81/00 , C08C19/44 , C08F293/00 , C08F8/30 , C08G12/46 , C08G18/10 , C08G18/69 , C08G18/832 , C08G8/38 , Y10S525/914
摘要： Polymers of anionically polymerized monomers such as conjugated dienes, vinyl substituted aromatics, olefinic type compounds, and heterocyclic nitrogen containing compounds, are produced and end capped with a polyisocyanate or polyisothiocyanate. Such end capped polymers are then reacted with compounds containing an amide such as lactam to give an imide type end group. The imide type terminated polymer is hydrolyzed to form a stable amine terminated polymer which may be utilized, as a composition of matter or stored for a short period of time to an extended period of time and reacted with other various polymers and monomers, or various combinations of monomers to form various block or graft polymers. That is the amine polymer may be subsequently reacted with any amine reactive compound such as with a polyisocyanate or polyisothiocyanate and a lactam in the presence of a known anionic lactam polymerization catalysts to give a blocked nylon copolymer. Similarly, other block or graft coplymers may be obtained by reacting amine reactive compounds such as various monomers or polymers with the terminated amine polymer and examples of amine reactive polymers include polyepoxy, polyurea-aldehyde, polyphenol-aldehyde, polyamide, polyurea-urethane, polyurethane, polyimide, polyurea and similar polymer segments. Of course, identical or similar polymer forming reagents such as monomers as well as identical or similar prepolymers may also be used.
摘要翻译： 制备阴离子聚合单体如共轭二烯，乙烯基取代芳族化合物，烯烃型化合物和含杂环氮化合物的聚合物，并用多异氰酸酯或多异硫氰酸酯封端。 然后使这样的封端聚合物与含有酰胺如内酰胺的化合物反应，得到酰亚胺型端基。 将酰亚胺型封端的聚合物水解以形成稳定的胺封端的聚合物，其可用作物质组合物或在较短时间内长时间储存并与其它各种聚合物和单体或各种组合反应 的单体以形成各种嵌段或接枝聚合物。 也就是说，胺聚合物随后可以与任何胺反应性化合物如多异氰酸酯或多异硫氰酸酯和内酰胺在已知的阴离子内酰胺聚合催化剂存在下反应，得到封端的尼龙共聚物。 类似地，其它嵌段或接枝共聚物可以通过使胺反应性化合物例如各种单体或聚合物与封端的胺聚合物反应而获得，胺反应性聚合物的实例包括聚环氧，聚脲醛，多酚醛，聚酰胺，聚脲 - 氨基甲酸酯，聚氨酯 ，聚酰亚胺，聚脲和类似的聚合物链段。 当然，也可以使用相同或相似的聚合物形成试剂如单体以及相同或相似的预聚物。
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公开(公告)号：US4070344A
公开(公告)日：1978-01-24
申请号：US574676
申请日：1975-05-05
IPC分类号： C08C19/44 , C08F8/30 , C08F293/00 , C08G8/38 , C08G12/46 , C08G18/10 , C08G81/00 , C08F18/24 , C08G18/04
摘要： Polymers of anionically polymerized monomers such as conjugated dienes, vinyl substituted aromatics, olefinic type compounds, and heterocyclic nitrogen containing compounds, are produced and end capped with a polyisocyanate or polyisothiocyanate. Such end capped polymers are then reacted with compounds containing an amide such as lactam to give an imide type end group. The imide type terminated polymer is hydrolyzed to form a stable amine terminated polymer which may be utilized, as a composition of matter or stored for a short period of time to an extended period of time and reacted with other various polymers and monomers, or various combinations of monomers to form various block or graft polymers. That is, the amine polymer may be subsequently reacted with any amine reactive compound such as with a polyisocyanate or polyisothiocyanate and a lactam in the presence of a known anionic lactam polymerizaton catalyst to give a blocked nylon copolymer. Similarly, other block or graft copolymers may be obtained by reacting amine reactive compounds such as various monomers or polymers with the terminated amine polymer and examples of amine reactive polymers include polyepoxy, polyurea-aldehyde, polyphenolaldehyde, polyamide, polyurea-urethane, polyurethane, polyimide, polyurea and similar polymer segments. Of course, identical or similar polymer forming reagents such as monomers as well as identical or similar prepolymers may also be used.
摘要翻译： 制备阴离子聚合单体如共轭二烯，乙烯基取代芳族化合物，烯烃型化合物和含杂环氮化合物的聚合物，并用多异氰酸酯或多异硫氰酸酯封端。 然后使这样的封端聚合物与含有酰胺如内酰胺的化合物反应，得到酰亚胺型端基。 将酰亚胺型封端的聚合物水解以形成稳定的胺封端的聚合物，其可用作物质组合物或在较短时间内长时间储存并与其它各种聚合物和单体或各种组合反应 的单体以形成各种嵌段或接枝聚合物。 也就是说，胺聚合物随后可以与任何胺反应性化合物如聚异氰酸酯或多异硫氰酸酯和内酰胺在已知的阴离子内酰胺聚合催化剂存在下反应，得到封闭的尼龙共聚物。 类似地，其它嵌段或接枝共聚物可以通过使胺反应性化合物如各种单体或聚合物与封端的胺聚合物反应而获得，胺反应性聚合物的实例包括聚环氧，聚脲醛，多酚醛，聚酰胺，聚脲 - 氨基甲酸酯，聚氨酯，聚酰亚胺 ，聚脲和类似的聚合物链段。 当然，也可以使用相同或相似的聚合物形成试剂如单体以及相同或相似的预聚物。
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公开(公告)号：US4157429A
公开(公告)日：1979-06-05
申请号：US792283
申请日：1977-04-29
IPC分类号： C08C19/30 , C08C19/44 , C08F8/30 , C08F8/34 , C08F293/00 , C08G8/38 , C08G12/46 , C08G18/10 , C08G18/62 , C08G18/69 , C08G81/00 , C08J9/10 , C08L77/06
CPC分类号： C08G81/00 , C08C19/30 , C08C19/44 , C08F293/00 , C08F8/30 , C08F8/34 , C08G12/46 , C08G18/10 , C08G18/6204 , C08G18/69 , C08G8/38
摘要： Polymers of anionically polymerized monomers such as conjugated dienes, vinyl substituted aromatics, olefinic type compounds, and heterocyclic nitrogen containing compounds, are produced and end capped with a polyisocyanate or polyisothiocyanate. Such end capped polymers are then reacted with compounds containing an amide such as lactam to give an imide type end group. The imide type terminated polymer is hydrolyzed to form a stable amine terminated polymer which may be utilized, as a composition of matter or stored for a short period of time to an extended period of time and reacted with other various polymers and monomers, or various combinations of monomers to form various block or graft polymers. That is the amine polymer may be subsequently reacted with any amine reactive compound such as with a polyisocyanate or polyisothiocyanate and a lactam in the presence of a known anionic Iactam polymerization catalysts to give a blocked nylon copolymer. Similarly, other block or graft copolymers may be obtained by reacting amine reactive compounds such as various monomers or polymers with the terminated amine polymer and examples of amine reactive polymers include polyepoxy, polyurea-aldehyde, polyphenol-aldehyde, polyamide, polyurea-urethane, polyurethane polyimide, polyurea and similar polymer segments. Of course, identical or similar polymer forming reagents such as monomers as well as identical or similar prepolymers may also be used.
摘要翻译： 制备阴离子聚合单体如共轭二烯，乙烯基取代芳族化合物，烯烃型化合物和含杂环氮化合物的聚合物，并用多异氰酸酯或多异硫氰酸酯封端。 然后使这样的封端聚合物与含有酰胺如内酰胺的化合物反应，得到酰亚胺型端基。 将酰亚胺型封端的聚合物水解以形成稳定的胺封端的聚合物，其可用作物质组合物或在较短时间内长时间储存并与其它各种聚合物和单体或各种组合反应 的单体以形成各种嵌段或接枝聚合物。 也就是说，胺聚合物随后可以与任何胺反应性化合物如聚异氰酸酯或多异硫氰酸酯和内酰胺在已知的阴离子咪唑聚合催化剂存在下反应，得到封闭的尼龙共聚物。 类似地，其它嵌段或接枝共聚物可以通过使胺反应性化合物如各种单体或聚合物与封端的胺聚合物反应而获得，胺反应性聚合物的实例包括聚环氧，聚脲醛，多酚醛，聚酰胺，聚脲 - 聚氨酯，聚氨酯 聚酰亚胺，聚脲和类似的聚合物链段。 当然，也可以使用相同或相似的聚合物形成试剂如单体以及相同或相似的预聚物。
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公开(公告)号：US4154773A
公开(公告)日：1979-05-15
申请号：US805343
申请日：1977-06-10
IPC分类号： C08C19/44 , C08F8/30 , C08F293/00 , C08G8/38 , C08G12/46 , C08G18/10 , C08G18/69 , C08G18/83 , C08G81/00 , C08L9/06 , C08L61/24
CPC分类号： C08G81/00 , C08C19/44 , C08F293/00 , C08F8/30 , C08G12/46 , C08G18/10 , C08G18/69 , C08G18/832 , C08G8/38 , Y10S525/914
摘要： Polymers of anionically polymerized monomers such as conjugated dienes, vinyl substituted aromatics, olefinic type compounds, and heterocyclic nitrogen containing compounds, are produced and end capped with a polyisocyanate or polyisothiocyanate. Such end capped polymers are then reacted with compounds containing an amide such as lactam to give an imide type end group. The imide type terminated polymer is hydrolyzed to form a stable amine terminated polymer which may be utilized, as a composition of matter or stored for a short period of time to an extended period of time and reacted with other various polymers and monomers, or various combinations of monomers to form various block or graft polymers. That is the amine polymer may be subsequently reacted with any amine reactive compound such as with a polyisocyanate or polyisothiocyanate and a lactam in the presence of a known anionic Iactam polymerization catalysts to give a blocked nylon copolymer. Similarly, other block or graft copolymers may be obtained by reacting amine reactive compounds such as various monomers or polymers with the terminated amine polymer and examples of amine reactive polymers include polyepoxy, polyurea-aldehyde, polyphenolaldehyde, polyamide, polyurea-urethane, polyurethane, polyimide, polyurea and similar polymer segments. Of course, identical or similar polymer forming reagents such as monomers as well as identical or similar prepolymers may also be used.
摘要翻译： 制备阴离子聚合单体如共轭二烯，乙烯基取代芳族化合物，烯烃型化合物和含杂环氮化合物的聚合物，并用多异氰酸酯或多异硫氰酸酯封端。 然后使这样的封端聚合物与含有酰胺如内酰胺的化合物反应，得到酰亚胺型端基。 将酰亚胺型封端的聚合物水解以形成稳定的胺封端的聚合物，其可用作物质组合物或在较短时间内长时间储存并与其它各种聚合物和单体或各种组合反应 的单体以形成各种嵌段或接枝聚合物。 也就是说，胺聚合物随后可以与任何胺反应性化合物如聚异氰酸酯或多异硫氰酸酯和内酰胺在已知的阴离子咪唑聚合催化剂存在下反应，得到封闭的尼龙共聚物。 类似地，其它嵌段或接枝共聚物可以通过使胺反应性化合物如各种单体或聚合物与封端的胺聚合物反应而获得，胺反应性聚合物的实例包括聚环氧，聚脲醛，多酚醛，聚酰胺，聚脲 - 氨基甲酸酯，聚氨酯，聚酰亚胺 ，聚脲和类似的聚合物链段。 当然，也可以使用相同或相似的聚合物形成试剂如单体以及相同或相似的预聚物。
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公开(公告)号：US4299932A
公开(公告)日：1981-11-10
申请号：US017789
申请日：1979-03-05
IPC分类号： C08C19/44 , C08F8/30 , C08G8/38 , C08G12/46 , C08G18/10 , C08G18/69 , C08G18/78 , C08G69/00 , C08G81/02 , C08L75/04 , C08L9/06
CPC分类号： C08G81/028 , C08C19/44 , C08F8/30 , C08G12/46 , C08G18/10 , C08G18/69 , C08G18/78 , C08G69/00 , C08G8/38 , C08G81/02
摘要： Polymers of anionically polymerized monomers such as mono-olefins, conjugated dienes, vinyl substituted aromatics, vinyl substituted pyridine, vinyl substituted quinolines, various aldehydes, various epoxides, various oxetanes, various oxygen-containing compounds, and the like are produced and end capped with a polyisocyanate or polyisothiocyanate having the formula R--N.dbd.C.dbd.X).sub.n wherein R is a hydrocarbon, n is 2 or 3, and X is oxygen or sulfur. Such end capped polymers, of course, contain one reacted or connected isocyanate or isothiocyanate group and at least one free isocyanate or isothiocyanate end group, which free end group(s) reacts with an amide to give an imide end group. The imide terminated polymer is then hydrolyzed to form a stable amine terminated polymer. The reaction of the amide compound with the isocyanate(s) or isothiocyanate(s), followed by hydrolysis, results in the replacement of the free isocyanate or isothiocyanate end group(s) with an amine group(s). Thus, the amine terminated polymer contains the polymer connected to an isocyanate or isothiocyanate group (now an amide group or a thioamide group), which in turn is attached to the hydrocarbon portion, that is, the "R" portion of the polyisocyanate, which in turn is connected to the formed amine group. The amine terminated polymers may be stored extended periods of time and then reacted with various polymers, prepolymers, monomers, or various combinations thereof to form various block or graft copolymers. That is, the amine terminated polymer may be subsequently reacted with any amine reactive compound such as diepoxy monomers or an epoxy prepolymer in the presence of known epoxy catalysts to give a blocked epoxy copolymer. Similarly, the amine terminated polymer may be reacted with urea prepolymers or urea-forming monomers to yield a block urea copolymer. Reaction of the amine terminated polymer with urethane polymers, urethane prepolymers, or urethane-forming momomers will yield a urethane block copolymer. Reaction of the amine terminated polymer with urethane-urea prepolymers of urethane-urea forming monomers will yield a urethane-urea block copolymer. Similarly, various dianhydride and diamine monomers may be utilized to form an imide block copolymer.
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公开(公告)号：US4235979A
公开(公告)日：1980-11-25
申请号：US17674
申请日：1979-03-05
CPC分类号： C08G18/832 , C08G12/46 , C08G18/10 , C08G18/6204 , C08G18/69 , C08G8/38
摘要： Polymers of anionically polymerized monomers such as mono-olefins, conjugated dienes, vinyl substituted aromatics, vinyl substituted pyridine, vinyl substituted quinolines, various aldehydes, various epoxides, various oxetanes, various oxygen-containing compounds, and the like are produced and end capped with a polyisocyanate or polyisothiocyanate having the formula R--N.dbd.C.dbd.X).sub.n wherein R is a hydrocarbon, n is 2 or 3, and X is oxygen or sulfur. Such end capped polymers, of course, contain one reacted or connected isocyanate or isothiocyanate group and at least one free isocyanate or isothiocyanate end group, which free end group(s) reacts with an amide to give an imide end group. The imide terminated polymer is then hydrolyzed to form a stable amine terminated polymer. The reaction of the amide compound with the isocyanate(s) or isothiocyanate(s), followed by hydrolysis, results in the replacement of the free isocyanate or isothiocyanate end group(s) with an amine group(s). Thus, the amine terminated polymer contains the polymer connected to an isocyanate or isothiocyanate group (now an amide group or a thioamide group), which in turn is attached to the hydrocarbon portion, that is, the "R" portion of the polyisocyanate, which in turn is connected to the formed amine group. The amine terminated polymers may be stored extended periods of time and then reacted with various polymers, prepolymers, monomers, or various combinations thereof to form various block or graft copolymers. That is, the amine terminated polymer may be subsequently reacted with any amine reactive compound such as diepoxy monomers or an epoxy prepolymer in the presence of known epoxy catalysts to give a blocked epoxy copolymer. Similarly, the amine terminated polymer may be reacted with urea prepolymers or urea-forming monomers to yield a block urea copolymer. Reaction of the amine terminated polymer with urethane polymers, urethane prepolymers, or urethane-forming monomers will yield urethane block copolymer. Reaction of the amine terminated polymer with urethane-urea prepolymers or urethane-urea forming monomers will yield a urethane-urea block copolymer. Similarly, various dianhydride and diamine monomers may be utilized to form an imide block copolymer.
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公开(公告)号：US4157430A
公开(公告)日：1979-06-05
申请号：US792284
申请日：1977-04-29
IPC分类号： C08C19/30 , C08C19/44 , C08F8/30 , C08F293/00 , C08G8/38 , C08G12/46 , C08G18/10 , C08G18/62 , C08G18/69 , C08G81/00 , C08J9/10 , C08L77/06
CPC分类号： C08G81/00 , C08C19/30 , C08C19/44 , C08F293/00 , C08F8/30 , C08G12/46 , C08G18/10 , C08G18/6204 , C08G18/69 , C08G8/38
摘要： Polymers of anionically polymerized monomers such as conjugated dienes, vinyl substituted aromatics, olefinic type compounds, and heterocyclic nitrogen containing compounds, are produced and end capped with a polyisocyanate or polyisothiocyanate. Such end capped polymers are then reacted with compounds containing an amide such as lactam to give an imide type end group. The imide type terminated polymer is hydrolyzed to form a stable amine terminated polymer which may be utilized, as a composition of matter or stored for a short period of time to an extended period of time and reacted with other various polymers and monomers, or various combinations of monomers to form various block or graft polymers. That is the amine polymer may be subsequently reacted with any amine reactive compound such as with a polyisocyanate or polyisothiocyanate and a lactam in the presence of a known anionic Iactam polymerization catalysts to give a blocked nylon copolymer. Similarly, other block or graft copolymers may be obtained by reacting amine reactive compounds such as various monomers or polymers with the terminated amine polymer and examples of amine reactive polymers include polyepoxy, polyurea-aldehyde, polyphenol-aldehyde, polyamide, polyurea-urethane, polyurethane, polyimide, polyurea and similar polymer segments. Of course, identical or similar polymer forming reagents such as monomers as well as identical or similar prepolymers may also be used.
摘要翻译： 制备阴离子聚合单体如共轭二烯，乙烯基取代芳族化合物，烯烃型化合物和含杂环氮化合物的聚合物，并用多异氰酸酯或多异硫氰酸酯封端。 然后使这样的封端聚合物与含有酰胺如内酰胺的化合物反应，得到酰亚胺型端基。 将酰亚胺型封端的聚合物水解以形成稳定的胺封端的聚合物，其可用作物质组合物或在较短时间内长时间储存并与其它各种聚合物和单体或各种组合反应 的单体以形成各种嵌段或接枝聚合物。 也就是说，胺聚合物随后可以与任何胺反应性化合物如聚异氰酸酯或多异硫氰酸酯和内酰胺在已知的阴离子咪唑聚合催化剂存在下反应，得到封闭的尼龙共聚物。 类似地，其它嵌段或接枝共聚物可以通过使胺反应性化合物如各种单体或聚合物与封端的胺聚合物反应而获得，胺反应性聚合物的实例包括聚环氧，聚脲醛，多酚醛，聚酰胺，聚脲 - 聚氨酯，聚氨酯 ，聚酰亚胺，聚脲和类似的聚合物链段。 当然，也可以使用相同或相似的聚合物形成试剂如单体以及相同或相似的预聚物。
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公开(公告)号：US4154913A
公开(公告)日：1979-05-15
申请号：US805435
申请日：1977-06-10
IPC分类号： C08C19/44 , C08F8/30 , C08F293/00 , C08G8/38 , C08G12/46 , C08G18/10 , C08G18/62 , C08G81/00 , C08G18/04
CPC分类号： C08G81/00 , C08C19/44 , C08F293/00 , C08F8/30 , C08G12/46 , C08G18/10 , C08G18/6204 , C08G8/38
摘要： Polymers of anionically polymerized monomers such as conjugated dienes, vinyl substituted aromatics, olefinic type compounds, and heterocyclic nitrogen containing compounds, are produced and end capped with a polyisocyanate or polyisothiocyanate. Such end capped polymers are then reacted with compounds containing an amide such as lactam to give an imide type end group. The imide type terminated polymer is hydrolyzed to form a stable amine terminated polymer which may be utilized, as a composition of matter or stored for a short period of time to an extended period of time and reacted with other various polymers and monomers, or various combinations of monomers to form various block or graft polymers. That is the amine polymer may be subsequently reacted with any amine reactive compound such as with a polyisocyanate or polyisothiocyanate and a lactam in the presence of a known anionic lactam polymerization catalysts to give a blocked nylon copolymer. Similarly, other block or graft copolymers may be obtained by reacting amine reactive compounds such as various monomers or polymers with the terminated amine polymer and examples of amine reactive polymers include polyepoxy, polyurea-aldehyde, polyphenolaldehyde, polyamide, polyurea-urethane, polyurethane, polyimide, polyurea and similar polymer segments. Of course, identical or similar polymer forming reagents such as monomers as well as identical or similar prepolymers may also be used.
摘要翻译： 制备阴离子聚合单体如共轭二烯，乙烯基取代芳族化合物，烯烃型化合物和含杂环氮化合物的聚合物，并用多异氰酸酯或多异硫氰酸酯封端。 然后使这样的封端聚合物与含有酰胺如内酰胺的化合物反应，得到酰亚胺型端基。 将酰亚胺型封端的聚合物水解以形成稳定的胺封端的聚合物，其可用作物质组合物或在较短时间内长时间储存并与其它各种聚合物和单体或各种组合反应 的单体以形成各种嵌段或接枝聚合物。 也就是说，胺聚合物随后可以与任何胺反应性化合物如多异氰酸酯或多异硫氰酸酯和内酰胺在已知的阴离子内酰胺聚合催化剂存在下反应，得到封端的尼龙共聚物。 类似地，其它嵌段或接枝共聚物可以通过使胺反应性化合物如各种单体或聚合物与封端的胺聚合物反应而获得，胺反应性聚合物的实例包括聚环氧，聚脲醛，多酚醛，聚酰胺，聚脲 - 氨基甲酸酯，聚氨酯，聚酰亚胺 ，聚脲和类似的聚合物链段。 当然，也可以使用相同或相似的聚合物形成试剂如单体以及相同或相似的预聚物。
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公开(公告)号：US4154772A
公开(公告)日：1979-05-15
申请号：US805440
申请日：1977-06-10
IPC分类号： C08C19/44 , C08F8/30 , C08F293/00 , C08G8/38 , C08G12/46 , C08G18/10 , C08G18/69 , C08G18/83 , C08G81/00 , C08L61/10 , C08L9/06
CPC分类号： C08G81/00 , C08C19/44 , C08F293/00 , C08F8/30 , C08G12/46 , C08G18/10 , C08G18/69 , C08G18/832 , C08G8/38 , Y10S525/914
摘要： Polymers of anionically polymerized monomers such as conjugated dienes, vinyl substituted aromatics, olefinic type compounds, and heterocyclic nitrogen containing compounds, are produced and end capped with a polyisocyanate or polyisothiocyanate. Such end capped polymers are then reacted with compounds containing an amide such as lactam to give an imide type end group. The imide type terminated polymer is hydrolyzed to form a stable amine terminated polymer which may be utilized, as a composition of matter or stored for a short period of time to an extended period of time and reacted with other various polymers and monomers, or various combinations of monomers to form various block or graft polymers. That is the amine polymer may be subsequently reacted with any amine reactive compound such as with a polyisocyanate or polyisothiocyanate and a lactam in the presence of a known anionic Iactam polymerization catalysts to give a blocked nylon copolymer. Similarly, other block or graft copolymers may be obtained by reacting amine reactive compounds such as various monomers or polymers with the terminated amine polymer and examples of amine reactive polymers include polyepoxy, polyurea-aldehyde, polyphenolaldehyde, polyamide, polyurea-urethane, polyurethane, polyimide, polyurea and similar polymer segments. Of course, identical or similar polymer forming reagents such as monomers as well as identical or similar prepolymers may also be used.
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公开(公告)号：US4151222A
公开(公告)日：1979-04-24
申请号：US848962
申请日：1977-11-07
IPC分类号： C08C19/44 , C08F8/30 , C08F293/00 , C08G8/38 , C08G12/46 , C08G18/10 , C08G18/69 , C08G69/00 , C08G81/02 , C08L79/08
CPC分类号： C08G81/028 , C08C19/44 , C08F293/00 , C08F8/30 , C08G12/46 , C08G18/10 , C08G18/69 , C08G69/00 , C08G8/38 , C08G81/02 , Y10S525/914
摘要： Polymers of anionically polymerized monomers such as mono-olefins, conjugated dienes, vinyl substituted aromatics, vinyl substituted pyridine, vinyl substituted quinolines, various aldehydes, various epoxides, various oxetanes, various oxygen-containing compounds, and the like are produced and end capped with a polyisocyanate or polyisothiocyanate having the formula R--(N.dbd.C.dbd.X).sub.n wherein R is a hydrocarbon, n is 2 or 3, and X is oxygen or sulfur. Such end capped polymers, of course, contain one reacted or connected isocyanate or isothiocyanate group and at least one free isocyanate or isothiocyanate end group, which free end group(s) reacts with an amide to give an imide end group. The imide terminated polymer is then hydrolyzed to form a stable amine terminated polymer. The reaction of the amide compound with the isocyanate(s) or isothiocyanate(s), followed by hydrolysis, results in the replacement of the free isocyanate or isothiocyanate end group(s) with an amine group(s). Thus, the amine terminated polymer contains the polymer connected to an isocyanate or isothiocyanate group (now an amide group or a thioamide group), which in turn is attached to the hydrocarbon portion, that is, the "R" portion of the polyisocyanate, which in turn is connected to the formed amine group. The amine terminated polymers may be stored extended periods of time and then reacted with various polymers, prepolymers, monomers, or various combinations thereof to form various block or graft copolymers. That is, the amine terminated polymer may be subsequently reacted with any amine reactive compound such as diepoxy monomers or an epoxy prepolymer in the presence of known epoxy catalysts to give a blocked epoxy copolymer. Similarly, the amine terminated polymer may be reacted with urea prepolymers or urea-forming monomers to yield a block urea copolymer. Reaction of the amine terminated polymer with urethane polymers, urethane prepolymers, or urethane-forming monomers will yield a urethane block copolymer. Reaction of the amine terminated polymer with urethane-urea prepolymers or urethane-urea forming monomers will yield a urethane-urea block copolymer. Similarly, various dianhydride and diamine monomers may be utilized to form an imide block copolymer.
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