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公开(公告)号：US4128703A
公开(公告)日：1978-12-05
申请号：US812641
申请日：1977-07-05
Applicant: Ralph T. Mead , Wilson Greatbatch , Frank W. Rudolph , Norbert W. Frenz, Jr.
Inventor： Ralph T. Mead , Wilson Greatbatch , Frank W. Rudolph , Norbert W. Frenz, Jr.
CPC classification number: H01M6/182
Abstract: A lithium-iodine cell comprising a casing of electrically conducting material, an anode including a lithium element within the casing, an electrical conductor operatively connected to the lithium element and extending out from the casing, and a cathode comprising iodine-containing material in operative contact with both the casing and the lithium element. The anode electrical conductor is completely sealed from the rest of the cell, and the casing serves as the cathode current collector. The anode operative surface is provided with a coating of an organic electron donor material. The anode is enclosed within an insulator element within the casing and a ferrule having one end within the insulator and the other end extending from the casing.
Abstract translation: 一种锂 - 碘电池，包括导电材料的壳体，在壳体内包含锂元素的阳极，可操作地连接到锂元素并从壳体延伸出来的电导体，以及包含操作接触的含碘材料的阴极 与壳体和锂元素。 阳极电导体与电池的其余部分完全密封，并且壳体用作阴极集电器。 阳极工作表面设置有有机电子给体材料的涂层。 阳极被封装在壳体内的绝缘体元件内，并且套管具有在绝缘体内的一端，另一端从壳体延伸。
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公开(公告)号：US4071662A
公开(公告)日：1978-01-31
申请号：US647002
申请日：1976-01-07
Applicant: Ralph T. Mead , Wilson Greatbatch , Frank W. Rudolph
Inventor： Ralph T. Mead , Wilson Greatbatch , Frank W. Rudolph
Abstract: A lithium-iodine cell comprising a cathode including a charge transfer complex of an organic donor component and iodine, an anode including a lithium element having a surface operatively contacting the charge transfer complex material, and a coating on the lithium surface of an organic electron donor material, preferably but not necessarily the organic donor component of the charge transfer complex. The organic electron donor material preferably comprises polyvinyl pyridine polymer and in particular two-vinyl pyridine polymer. A solution of two-vinyl pyridine polymer in benzene is brushed onto the anode lithium surface and then exposed to a desiccant. A number of coatings preferably are applied successively to provide a resulting or finished coating of increased thickness.
Abstract translation: 一种锂碘电池，其包含阴极，其包括有机供体组分和碘的电荷转移络合物，包含具有可操作地接触电荷转移络合物材料的表面的锂元素的阳极和有机电子给体的锂表面上的涂层 材料，优选但不一定是电荷转移络合物的有机供体组分。 有机电子给体材料优选包含聚乙烯基吡啶聚合物，特别是二乙烯基吡啶聚合物。 将二乙烯基吡啶聚合物在苯中的溶液刷在阳极锂表面上，然后暴露于干燥剂中。 优选连续施加多个涂层以提供增加厚度的所得或成品涂层。
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公开(公告)号：US4385439A
公开(公告)日：1983-05-31
申请号：US161058
申请日：1980-06-19
Applicant: Ralph T. Mead , Frank W. Rudolph , Norbert W. Frenz, Jr. , Wilson Greatbatch
Inventor： Ralph T. Mead , Frank W. Rudolph , Norbert W. Frenz, Jr. , Wilson Greatbatch
CPC classification number: H01M2/065 , H01M6/182 , Y10T29/49108 , Y10T29/4911
Abstract: A lithium-iodine cell comprising a casing of electrically conducting material, an anode including a lithium element within the casing, an electrical conductor operatively connected to the lithium element and extending out from the casing, and a cathode comprising iodine-containing material in operative contact with both the casing and the lithium element. The anode electrical conductor is completely sealed from the rest of the cell, and the casing serves as the cathode current collector. The anode operative surface is provided with a coating of an organic electron donor material. The anode conductor is enclosed within the combination of an insulator element within the casing, an isolator element between the insulator and the conductor, and a ferrule having one end within the insulator and the other end extending from the casing. During assembly, the cathode material is introduced in heated form and a filling element is employed which serves to keep the edge of the casing open end clean to facilitate subsequent welding of a lid to the casing.
Abstract translation: 一种锂 - 碘电池，包括导电材料的壳体，在壳体内包含锂元素的阳极，可操作地连接到锂元素并从壳体延伸出来的电导体，以及包含操作接触的含碘材料的阴极 与壳体和锂元素。 阳极电导体与电池的其余部分完全密封，并且壳体用作阴极集电器。 阳极工作表面设置有有机电子给体材料的涂层。 阳极导体封装在壳体内的绝缘体元件，绝缘体和导体之间的绝缘元件以及绝缘体内的一端和从壳体延伸的另一端的套圈之间。 在组装期间，阴极材料以加热形式引入，并且使用填充元件，其用于保持壳体的边缘开口端清洁以便于将盖子随后焊接到壳体。
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公开(公告)号：US4105833A
公开(公告)日：1978-08-08
申请号：US722653
申请日：1976-09-16
Applicant: Wilson Greatbatch , Ralph T. Mead , Robert L. McLean , Frank W. Rudolph , Norbert W. Frenz
Inventor： Wilson Greatbatch , Ralph T. Mead , Robert L. McLean , Frank W. Rudolph , Norbert W. Frenz
Abstract: A lithium-bromine cell comprising a casing which can be of electrically conducting material and containing a lithium anode element from which a sealed conductor extends through the casing. A filling element which can be of electrically conducting material and which has a passage therethrough is fixed to the sealed casing with one end of the passage in communication with the interior of the casing and the other end externally exposed. Bromine is introduced through the passage to the interior of the casing into operative relationship with the lithium anode whereupon the passage is closed to complete the cell. The electrically conducting casing serves as a cathode current collector in operative contact with the bromine cathode, and after closing of the passage the electrically conducting filling element serves as an electrical terminal for the cell. An electrical potential difference exists between the terminal and the anode conductor during operation of the cell.
Abstract translation: 一种锂 - 溴电池，其包括可以是导电材料并且包含锂阳极元件的壳体，密封导体从该锂阳极元件穿过壳体。 可以是导电材料并且具有穿过其的通道的填充元件被固定到密封壳体，通道的一端与壳体的内部连通，另一端从外部暴露。 通过通向壳体内部的通道将溴引入与锂阳极的操作关系，由此通道封闭以完成电池。 导电壳体用作与溴阴极有效接触的阴极集电器，并且在通路关闭之后，导电填充元件用作电池的电端子。 在电池工作期间，端子和阳极导体之间存在电位差。
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公开(公告)号：US4058889A
公开(公告)日：1977-11-22
申请号：US708362
申请日：1976-07-26
Applicant: Wilson Greatbatch , Ralph T. Mead , Robert L. McLean , Frank W. Rudolph , Norbert W. Frenz
Inventor： Wilson Greatbatch , Ralph T. Mead , Robert L. McLean , Frank W. Rudolph , Norbert W. Frenz
CPC classification number: H01M6/182 , H01M2/06 , H01M4/60 , Y10T29/49115
Abstract: A solid electrolyte primary cell comprising a lithium anode, a bromine cathode and a lithium bromide electrolyte. A solid lithium element operatively contacts the cathode material, and one form of cathode material is a charge transfer complex of an organic donor component material and bromine. The organic donor component material can be poly-2-vinyl pyridine. Another cathode material is liquid bromine. The surface of the lithium anode element which operatively contacts the cathode material can be provided with a coating of an organic electron donor component material. When the lithium anode operatively contacts the bromine cathode, a solid lithium bromide electrolyte begins to form at the interface and an electrical potential difference exists between conductors operatively connected to the anode and cathode.
Abstract translation: 一种固体电解质原电池，其包含锂阳极，溴阴极和溴化锂电解质。 固体锂元素可操作地接触阴极材料，并且一种形式的阴极材料是有机供体组分材料和溴的电荷转移络合物。 有机供体组分材料可以是聚-2-乙烯基吡啶。 另一种阴极材料是液态溴。 可操作地接触阴极材料的锂阳极元件的表面可以提供有机电子给体组分材料的涂层。 当锂阳极可操作地接触溴阴极时，固体溴化锂电解质开始在界面处形成，并且在可操作地连接到阳极和阴极的导体之间存在电势差。
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Patent Agency Ranking
公开(公告)号：US3981744A
公开(公告)日：1976-09-21
申请号：US513127
申请日：1974-10-08
Applicant: Wilson Greatbatch , Ralph T. Mead
Inventor： Wilson Greatbatch , Ralph T. Mead
CPC classification number: H01M2/00 , H01M6/182 , Y10T29/4911 , Y10T29/49114
Abstract: An enclosure for a lithium-iodine cell including a first casing containing the cell components and a second casing containing the first casing. The first casing is disposed so that the lid thereof is adjacent the bottom of the second casing. Both casings are of a material which is non-reactive with iodine such as epoxy material. The first casing is encapsulated in a polyester material for electrical insulation and sealing against iodine migration. The second casing is placed in an hermetically sealed outer casing of metal, the second casing being spaced from the lid of the outer casing.
Abstract translation: 一种用于锂碘电池的外壳，包括容纳电池组件的第一壳体和包含第一壳体的第二壳体。 第一壳体被设置成使其盖子邻近第二壳体的底部。 两种壳体都是与碘不反应的材料，例如环氧树脂材料。 第一套被封装在聚酯材料中，用于电绝缘和密封以防碘迁移。 第二壳体放置在密封的金属外壳中，第二壳体与外壳的盖隔开。
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公开(公告)号：US4203201A
公开(公告)日：1980-05-20
申请号：US921905
申请日：1978-07-05
Applicant: Ralph T. Mead , Wilson Greatbatch , Frank W. Rudolph , Norbert W. Frenz, Jr.
Inventor： Ralph T. Mead , Wilson Greatbatch , Frank W. Rudolph , Norbert W. Frenz, Jr.
CPC classification number: H01M2/1205 , H01M2/065 , H01M6/182 , Y10T29/49108 , Y10T29/4911
Abstract: A lithium-iodine cell comprising a casing of electrically conducting material, an anode including a lithium element within the casing, an electrical conductor operatively connected to the lithium element and extending out from the casing, and a cathode comprising iodine-containing material in operative contact with both the casing and the lithium element. The anode electrical conductor is completely sealed from the rest of the cell, and the casing serves as the cathode current collector. The anode operative surface is provided with a coating of an organic electron donor material. The anode is enclosed within an insulator element within the casing and a ferrule having one end within the insulator and the other end extending from the casing.
Abstract translation: 一种锂 - 碘电池，包括导电材料的壳体，在壳体内包含锂元素的阳极，可操作地连接到锂元素并从壳体延伸出来的电导体，以及包含操作接触的含碘材料的阴极 与壳体和锂元素。 阳极电导体与电池的其余部分完全密封，并且壳体用作阴极集电器。 阳极工作表面设置有有机电子给体材料的涂层。 阳极被封装在壳体内的绝缘体元件内，并且套管具有在绝缘体内的一端，另一端从壳体延伸。
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公开(公告)号：US4166158A
公开(公告)日：1979-08-28
申请号：US865849
申请日：1977-12-30
Applicant: Ralph T. Mead , Frank W. Rudolph , Norbert W. Frenz, Jr. , Wilson Greatbatch
Inventor： Ralph T. Mead , Frank W. Rudolph , Norbert W. Frenz, Jr. , Wilson Greatbatch
CPC classification number: H01M6/182 , H01M2/065 , Y10T29/49108
Abstract: A lithium-iodine cell comprising a casing of electrically conducting material, an anode including a lithium element within the casing, an electrical conductor operatively connected to the lithium element and extending out from the casing, and a cathode comprising iodine-containing material in operative contact with both the casing and the lithium element. The anode electrical conductor is completely sealed from the rest of the cell, and the casing serves as the cathode current collector. The anode operative surface is provided with a coating of an organic electron donor material. The anode conductor is enclosed within the combination of an insulator element within the casing, an isolator element between the insulator and the conductor, and a ferrule having one end within the insulator and the other end extending from the casing. During assembly, the cathode material is introduced in heated form and a filling element is employed which serves to keep the edge of the casing open end clean to facilitate subsequent welding of a lid to the casing.
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公开(公告)号：US4164070A
公开(公告)日：1979-08-14
申请号：US861527
申请日：1977-12-19
Applicant: Wilson Greatbatch , Ralph T. Mead , Robert L. McLean , Frank W. Rudolph , Norbert W. Frenz
Inventor： Wilson Greatbatch , Ralph T. Mead , Robert L. McLean , Frank W. Rudolph , Norbert W. Frenz
CPC classification number: H01M6/182 , H01M2/065 , H01M4/60 , Y10T29/4911
Abstract: A lithium-bromine cell comprising a casing which can be of electrically conducting material and containing a lithium anode element from which a sealed conductor extends through the casing. A filling element which can be of electrically conducting material and which has a passage therethrough is fixed to the sealed casing with one end of the passage in communication with the interior of the casing and the other end externally exposed. Bromine is introduced through the passage to the interior of the casing into operative relationship with the lithium anode whereupon the passage is closed to complete the cell. The electrically conducting casing serves as a cathode current collector in operative contact with the bromine cathode, and after closing of the passage the electrically conducting filling element serves as an electrical terminal for the cell. An electrical potential difference exists between the terminal and the anode conductor during operation of the cell.
Abstract translation: 一种锂 - 溴电池，其包括可以是导电材料并且包含锂阳极元件的壳体，密封导体从该锂阳极元件穿过壳体。 可以是导电材料并且具有穿过其的通道的填充元件被固定到密封壳体，通道的一端与壳体的内部连通，另一端从外部暴露。 通过通向壳体内部的通道将溴引入与锂阳极的操作关系，由此通道封闭以完成电池。 导电壳体用作与溴阴极有效接触的阴极集电器，并且在通路关闭之后，导电填充元件用作电池的电端子。 在电池工作期间，端子和阳极导体之间存在电位差。
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公开(公告)号：US3994747A
公开(公告)日：1976-11-30
申请号：US617280
申请日：1975-09-29
Applicant: Wilson Greatbatch , Ralph T. Mead , Robert L. McLean , Frank Rudolph , Norbert W. Frenz
Inventor： Wilson Greatbatch , Ralph T. Mead , Robert L. McLean , Frank Rudolph , Norbert W. Frenz
Abstract: A solid electrolyte primary cell comprising a lithium anode, a bromine cathode and a lithium bromide electrolyte. A solid lithium element operatively contacts the cathode material, and one form of cathode material is a charge transfer complex of an organic donor component material and bromine. The organic donor component material can be poly-2-vinyl pyridine. Another cathode material is liquid bromine. The surface of the lithium anode element which operatively contacts the cathode material can be provided with a coating of an organic electron donor component material. When the lithium anode operatively contacts the bromine cathode, a solid lithium bromide electrolyte begins to form at the interface and an electrical potential difference exists between conductors operatively connected to the anode and cathode.
Abstract translation: 一种固体电解质原电池，其包含锂阳极，溴阴极和溴化锂电解质。 固体锂元素可操作地接触阴极材料，并且一种形式的阴极材料是有机供体组分材料和溴的电荷转移络合物。 有机供体组分材料可以是聚-2-乙烯基吡啶。 另一种阴极材料是液态溴。 可操作地接触阴极材料的锂阳极元件的表面可以提供有机电子给体组分材料的涂层。 当锂阳极可操作地接触溴阴极时，固体溴化锂电解质开始在界面处形成，并且在可操作地连接到阳极和阴极的导体之间存在电势差。
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