公开(公告)号：US4226812A

公开(公告)日：1980-10-07

申请号：US854919

申请日：1977-11-25

申请人： Wim J. M. Pieters ,  William E. Gates ,  Franz Wenger

发明人： Wim J. M. Pieters ,  William E. Gates ,  Franz Wenger

IPC分类号： C07C17/23 ,  C07C21/18 ,  B01J27/00 ,  C07C19/045 ,  C07C21/06

CPC分类号： C07C17/23

摘要： An improved process is described for producing chlorotrifluoroethylene, a useful monomer for making high strength chlorofluoropolymers, comprising passing a mixture of 1,1,2-trichloro-1,2,2-trifluoroethane, ethylene, hydrogen chloride and elemental oxygen in the vapor phase, at a temperature from about 350.degree. to 525.degree. C., over a catalyst consisting essentially of a mixture of copper chloride and an alkali metal chloride, preferably a eutectic mixture, occluded in a molecular sieve, having an average pore size diameter in the range of about 5 to 11 angstroms.A new catalyst composition is also described, useful in oxyhydrochlorination processes conducted at temperatures above 350.degree. C., consisting essentially of a mixture of copper chloride and an alkali metal chloride, preferably a eutectic mixture, occluded in a molecular sieve, having an average pore size diameter in the range of about 5 to 11 angstroms.

摘要翻译： 描述了一种用于制备氯三氟乙烯（一种用于制备高强度氯氟聚合物的有用单体）的改进方法，其包括使气相中的1,1,2-三氯-1,2,2-三氟乙烷，乙烯，氯化氢和元素氧的混合物 在大约350℃至525℃的温度下，在基本上由氯化铜和碱金属氯化物的混合物组成的催化剂，优选共晶混合物，封闭在分子筛中，其平均孔径直径在 范围约5至11埃。 还描述了一种新的催化剂组合物，其用于在高于350℃的温度下进行的氧化氢氯化方法，其基本上由氯化铜和碱金属氯化物，优选共晶混合物的混合物组成，其被吸留在分子筛中，具有平均孔 尺寸直径在约5至11埃的范围内。

公开(公告)号：US4224293A

公开(公告)日：1980-09-23

申请号：US12086

申请日：1979-02-14

申请人： Wim J. M. Pieters ,  Franz Wenger

发明人： Wim J. M. Pieters ,  Franz Wenger

IPC分类号： C01B7/01 ,  C01B7/07 ,  B01D53/34

CPC分类号： C01B7/0743 ,  C01B7/012

摘要： Hydrogen contamination of chlorine-containing gas, such as the chlorine gas from the electrolytic chlorine/caustic process and especially the tail gas from the chlorine liquefaction operation, is eliminated by reaction of the hydrogen directly in the gas mixture at elevated temperature in the presence of a catalyst, to effect combination of the hydrogen with chlorine to form hydrogen chloride, followed by scrubbing of the hydrogen chloride from the gas.

摘要翻译： 含氯气体的氢污染，例如电解氯/苛性碱工艺中的氯气，特别是来自氯液化操作的尾气，通过直接在气体混合物中在升高的温度下，在存在 催化剂，以实现氢与氯的组合以形成氯化氢，然后从气体洗涤氯化氢。