公开(公告)号：US4430272A

公开(公告)日：1984-02-07

申请号：US347178

申请日：1982-02-09

申请人： Winfried Ehrl ,  Siegfried Jung

发明人： Winfried Ehrl ,  Siegfried Jung

IPC分类号： A62D1/02 ,  C07C67/00 ,  C07C301/00 ,  C07C303/02 ,  C07C303/32 ,  C07C309/14 ,  C07C143/14

CPC分类号： A62D1/0085

摘要： Fluorine-containing alkylsulfobetaines of the general formula ##STR1## wherein R.sub.f denotes a perfluoroalkyl radical having 3 to 16 C atoms, R.sub.1 and R.sub.2, which can be identical or different, denote alkyl radicals or hydroxyalkyl radicals having 1 to 4 C atoms, a is zero or 1, b assumes the value 1 when a is equal to 1 and the values 1 to 4 when a is equal to 0, and c is 3 or 4, are described. These are prepared by reacting the corresponding fluorine-containing amines with propanesultone or butanesultone in organic solvents. The compounds are distinguished in particular by high interfacial activity at the interface of water with non-miscible organic liquids and by compatibility with other surfactants. They are suitable for use as aftertreatment agents (auxiliary dispersing agents) in dispersions of fluoropolymers and as components in fire-extinguishing agents.

摘要翻译： 具有通式“IMAGE”的含氟烷基磺基甜菜碱其中Rf表示具有3至16个C原子的全氟烷基，可以相同或不同的R 1和R 2表示具有1至4个C原子的烷基或羟基烷基，a是 0或1，当a等于1时，b假设值为1，当a等于0时，值为1到4，c为3或4。 这些通过相应的含氟胺与丙磺酸内酯或丁磺酸内酯在有机溶剂中反应来制备。 特别是化合物在水与不可混溶的有机液体的界面处的高界面活性以及与其它表面活性剂的相容性的区别。 它们适用于作为后处理剂（辅助分散剂）用于氟聚合物分散体和灭火剂中的组分。

公开(公告)号：US4564520A

公开(公告)日：1986-01-14

申请号：US423271

申请日：1982-09-24

申请人： Winfried Ehrl ,  Alwin Reng ,  Jochen M. Quack

发明人： Winfried Ehrl ,  Alwin Reng ,  Jochen M. Quack

IPC分类号： A61K8/00 ,  A61K8/46 ,  A61Q5/02 ,  C07C305/06 ,  C07C309/14 ,  C11D1/18 ,  C11D1/92 ,  A61K7/06 ,  C07C143/00

CPC分类号： A61K8/463 ,  A61Q19/10 ,  A61Q5/00 ,  A61Q5/02 ,  C11D1/92 ,  A61Q5/006 ,  A61Q5/12

摘要： Hair shampoo and body cleansing agent having a content of alkyl-sulfatobetaine of the formula ##STR1## wherein R.sub.1 is C.sub.8 -C.sub.22 alkyl or C.sub.8 -C.sub.22 alkenyl, preferably C.sub.12 -C.sub.18 alkyl, R.sub.2 is C.sub.1 -C.sub.4 alkyl, preferably methyl, R.sub.3 is C.sub.1 -C.sub.4 hydroxyalkyl or a group of the formula --(CH.sub.2 CH.sub.2 O).sub.n H and n is an integer of from 1 to 10.

摘要翻译： 其中R1是C8-C22烷基或C8-C22链烯基，优选C 12 -C 18烷基，R 2是C 1 -C 4烷基，优选甲基，R 3是C 1 -C 4羟烷基或C 1 -C 4烷氧基烷基， 式 - （CH 2 CH 2 O）n H的基团，n为1〜10的整数。

公开(公告)号：US4709074A

公开(公告)日：1987-11-24

申请号：US901247

申请日：1986-08-28

申请人： Heinrich Bathelt ,  Winfried Ehrl ,  Frank Wehowsky ,  Rolf Kleber ,  Werner Lotz ,  Wolfgang Glenz ,  Hubert Herdt ,  Lothar Jackel ,  Jan-Hilbert Mast ,  Karl Hintermeier ,  Manfred Muller

发明人： Heinrich Bathelt ,  Winfried Ehrl ,  Frank Wehowsky ,  Rolf Kleber ,  Werner Lotz ,  Wolfgang Glenz ,  Hubert Herdt ,  Lothar Jackel ,  Jan-Hilbert Mast ,  Karl Hintermeier ,  Manfred Muller

IPC分类号： C09K3/18 ,  B27K3/38 ,  C07C67/00 ,  C07C239/00 ,  C07C271/28 ,  C08G65/32 ,  C09K3/00 ,  C14C9/00 ,  D06M13/02 ,  D06M13/224 ,  D06M13/322 ,  D06M13/342 ,  D06M13/345 ,  D06M13/425 ,  D06M13/428 ,  D06M13/463 ,  D06M101/00 ,  D06M101/02 ,  D06M101/10 ,  D06M101/12 ,  C07C125/073

CPC分类号： D06M13/428 ,  C14C9/00 ,  B27K2240/70 ,  B27K3/38 ,  B27K3/50

摘要： The novel urethanes correspond to the formula I below ##STR1## in which a denotes a number from 5 to 17 and b denotes a number from 1 to 7. These urethanes are prepared by reacting the corresponding perfluoroalkylethanol/epichlorohydrin adducts with toluelene diisocyanates. The novel aqueous dispersions are essentially composed of the novel urethanes, cationic or betaine emulsifiers and non-ionic emulsifiers, water-insoluble carboxylic and/or dicarboxylic acid esters and alkanediols or polyalkanediols which can be etherified on one or both sides, in water.The novel urethanes and the novel aqueous dispersions are used to impart an oleophobic and hydrophobic finish to textiles, leather and furs. They are also suitable for the treatment of unpainted timber, for example unpainted furniture.

摘要翻译： 新型氨基甲酸酯对应于下面的式I，其中a表示5至17的数，b表示1至7的数。这些氨基甲酸酯通过相应的全氟烷基乙醇/表氯醇加合物与甲苯二异氰酸酯反应制备。 新型水性分散体基本上由新型氨基甲酸酯，阳离子或甜菜碱乳化剂和非离子乳化剂，水不溶性羧酸和/或二羧酸酯和烷二醇或聚烷二醇组成，其可以在水中在一侧或两侧进行醚化。 新型氨基甲酸酯和新型水性分散体用于对纺织品，皮革和毛皮赋予疏油和疏水整理剂。 它们也适用于未涂漆的木材的处理，例如未上漆的家具。

公开(公告)号：US4209456A

公开(公告)日：1980-06-24

申请号：US956870

申请日：1978-11-01

申请人： Siegfried Billenstein ,  Winfried Ehrl

发明人： Siegfried Billenstein ,  Winfried Ehrl

IPC分类号： B01F17/04 ,  A62D1/02 ,  B01F17/18 ,  C07C67/00 ,  C07C301/00 ,  C07C303/22 ,  C07C303/24 ,  C07C305/02 ,  C11D1/00 ,  C11D1/90 ,  C07C141/10

CPC分类号： C11D1/004 ,  A62D1/0085

摘要： Fluorine-containing alkyl-sulfato-betaines of the formula ##STR1## in which R.sub.f is perfluoroalkyl with 3 to 16 C atoms, R.sup.1 is alkyl with 1 to 4 C atoms, R.sub.2 is alkyl with 1 to 4 C atoms, Q is --CH.sub.2 --CH.sub.2 -- or ##STR2##m is numbers 0 or 1 and, if m is 0, p is an integer from 1 to 4 and, if m is 1, p is the number 1, are prepared by reacting a compound of the formula ##STR3## in which R.sub.f, Q, m and p are as defined above, with at least one known sulfating agent at -30 to +60.degree. C. in the presence of at least one solvent (a) which dissolves the abovementioned amine and does not react with the sulfating agent, dissolving the resulting product, after removing the solvent (a), in at least one polar solvent (b), neutralizing the solution with at least one known alkali and then reacting the neutral solution at 40 to 130.degree. C. and under a pressure of about 1 to about 6 bars with a compound of the formula R.sub.2 Z, in which Z is Cl, Br, I or --OSO.sub.2 OR.sup.2 and R.sup.2 is as defined above.

摘要翻译： Rf为具有3至16个C原子的全氟烷基，R 1为具有1至4个C原子的烷基，R 2为具有1至4个C原子的烷基，Q为-CH 2的烷基 - 磺酸根合甜菜碱 -CH2-或

公开(公告)号：US4173679A

公开(公告)日：1979-11-06

申请号：US862516

申请日：1977-12-20

申请人： Rolf Kleber ,  Winfried Ehrl

发明人： Rolf Kleber ,  Winfried Ehrl

IPC分类号： D06M13/02 ,  C07F9/09 ,  C08G65/32 ,  D06M13/244 ,  D06M13/282 ,  D06M13/292 ,  D06M13/295 ,  C07F9/02 ,  A23J7/00 ,  C11C3/00

CPC分类号： D06M13/292 ,  C07F9/098 ,  D06M7/00 ,  D06M2200/40 ,  Y10T428/2933

摘要： Fiber conditioning agent containing a reaction product of polyphosphoric acid and an oxalkylate of C.sub.8-18 alkyl- or alkenylcarboxylic acids with 1 to 22 ethylene oxide units and having a content of free polyethylene glycol of less than 2% by weight, the reaction product being present in acidic form or in the form of its alkali metal salts. These fiber conditioning agents are applied by conventional methods. They show good antistatic properties, are stable to heat and show good lubricating and sliding properties.

摘要翻译： 纤维调理剂含有多聚磷酸与C8-18烷基或链烯基羧酸的烷氧基烷基化物与1至22个环氧乙烷单元的反应产物，其游离聚乙二醇含量小于2重量％，反应产物存在 呈酸性或其碱金属盐的形式。 这些纤维调理剂通过常规方法施加。 它们具有良好的抗静电性能，对热稳定，表现出良好的润滑和滑动性能。