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    One-stage reductive amination
    3.
    发明授权
    One-stage reductive amination 失效
    一步还原胺化

    公开(公告)号：US08415500B2

    公开(公告)日：2013-04-09

    申请号：US12808268

    申请日：2008-12-10

    申请人： Tobias Staeb ,  Thilo Hahn ,  Wolfgang Siegel

    发明人： Tobias Staeb ,  Thilo Hahn ,  Wolfgang Siegel

    IPC分类号： C07C211/27 ,  C07C209/62

    CPC分类号： C07C209/26 ,  C07B2200/07 ,  C07C209/62 ,  C07C211/07 ,  C07C211/27

    摘要： A process for preparing amines of the formula I, by reacting a carbonyl compound of the formula II with an amine of the formula III where R1 and R2 are different and are each an organic radical which has from 1 to 20 carbon atoms and may optionally also comprise heteroatoms, R3 is a C1-C6-alkyl group and R4 is an aryl group which may be partly or fully halogenated and/or may bear from one to three radicals from the group of cyano, nitro, C1-C6-alkyl, C1-C6-haloalkyl, hydroxyl, C1-C6-hydroxyalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, hydroxycarbonyl, C1-C6-alkoxycarbonyl, C1-C6-alkylamino, di(C1-C6-alkyl)amino, aryl and aryl(C1-C6-alkyl); and * represents the S or R configuration, and ** represents the S and/or R configuration; which comprises performing the reaction in the presence of a heterogeneous imination catalyst, of a hydrogenation catalyst and of hydrogen.

    摘要翻译： 一种制备式I的胺的方法，通过使式II的羰基化合物与式III的胺反应，其中R 1和R 2不同，并且各自是具有1至20个碳原子的有机基团， 包括杂原子，R 3是C 1 -C 6烷基，R 4是可以部分或完全卤化的和/或可以从氰基，硝基，C 1 -C 6 - 烷基，C 1〜 C 1 -C 6 - 卤代烷基，羟基，C 1 -C 6羟基烷基，C 1 -C 6 - 烷氧基，C 1 -C 6 - 卤代烷氧基，羟基羰基，C 1 -C 6 - 烷氧基羰基，C 1 -C 6烷基氨基， 和芳基（C 1 -C 6 - 烷基）; 和*表示S或R构型，**表示S和/或R构型; 其包括在非均相模拟催化剂，氢化催化剂和氢气存在下进行反应。

    ONE-STAGE REDUCTIVE AMINATION
    4.
    发明申请
    ONE-STAGE REDUCTIVE AMINATION 失效
    一级减少化学

    公开(公告)号：US20100274054A1

    公开(公告)日：2010-10-28

    申请号：US12808268

    申请日：2008-12-10

    申请人： Tobias Staeb ,  Thilo Hahn ,  Wolfgang Siegel

    发明人： Tobias Staeb ,  Thilo Hahn ,  Wolfgang Siegel

    IPC分类号： C07C211/27 ,  C07C209/62

    CPC分类号： C07C209/26 ,  C07B2200/07 ,  C07C209/62 ,  C07C211/07 ,  C07C211/27

    摘要： A process for preparing amines of the formula I, by reacting a carbonyl compound of the formula II with an amine of the formula III where R1 and R2 are different and are each an organic radical which has from 1 to 20 carbon atoms and may optionally also comprise heteroatoms, R3 is a C1-C6-alkyl group and R4 is an aryl group which may be partly or fully halogenated and/or may bear from one to three radicals from the group of cyano, nitro, C1-C6-alkyl, C1-C6-haloalkyl, hydroxyl, C1-C6-hydroxyalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, hydroxycarbonyl, C1-C6-alkoxycarbonyl, C1-C6-alkylamino, di(C1-C6-alkyl)amino, aryl and aryl(C1-C6-alkyl); and * represents the S or R configuration, and ** represents the S and/or R configuration; which comprises performing the reaction in the presence of a heterogeneous imination catalyst, of a hydrogenation catalyst and of hydrogen.

    摘要翻译： 一种制备式I的胺的方法，通过使式II的羰基化合物与式III的胺反应，其中R 1和R 2不同，并且各自是具有1至20个碳原子的有机基团， 包括杂原子，R 3是C 1 -C 6烷基，R 4是可以部分或完全卤化的和/或可以从氰基，硝基，C 1 -C 6 - 烷基，C 1〜 C 1 -C 6 - 卤代烷基，羟基，C 1 -C 6羟基烷基，C 1 -C 6 - 烷氧基，C 1 -C 6 - 卤代烷氧基，羟基羰基，C 1 -C 6 - 烷氧基羰基，C 1 -C 6烷基氨基， 和芳基（C 1 -C 6 - 烷基）; 和*表示S或R构型，**表示S和/或R构型; 其包括在非均相模拟催化剂，氢化催化剂和氢气存在下进行反应。

    Method for producing ethylenediamine
    5.
    发明授权
    Method for producing ethylenediamine 有权
    乙二胺的制备方法

    公开(公告)号：US07915454B2

    公开(公告)日：2011-03-29

    申请号：US12529107

    申请日：2008-02-28

    申请人： Alfred Oftring ,  Kirsten Dahmen ,  Randolf Hugo ,  Thilo Hahn ,  Katrin Baumann ,  Johann-Peter Melder

    发明人： Alfred Oftring ,  Kirsten Dahmen ,  Randolf Hugo ,  Thilo Hahn ,  Katrin Baumann ,  Johann-Peter Melder

    IPC分类号： C07C209/48

    CPC分类号： C07C209/48 ,  C07C211/10

    摘要： The invention relates to a process for preparing ethylenediamine by hydrogenation of aminoacetonitrile over a catalyst, wherein the hydrogenation is carried out in a solution comprising aminoacetonitrile, water in a proportion of from 0 to 60% by weight and a solvent and the aminoacetonitrile comprised in the solution is fed into the reaction vessel at a rate which is not greater than the rate at which the aminoacetonitrile reacts with hydrogen in the hydrogenation.

    摘要翻译： 本发明涉及一种通过氨基乙腈在催化剂上氢化制备乙二胺的方法，其中氢化是在包含氨基乙腈的溶液中，以0至60重量％的比例的水和溶剂和包含在其中的氨基乙腈 溶液以不大于氨基乙腈在氢化中与氢反应的速率进料到反应容器中。

    Method For Producing A Xylylene Diamine
    8.
    发明申请
    Method For Producing A Xylylene Diamine 审中-公开
    生产二甲苯二胺的方法

    公开(公告)号：US20080214871A1

    公开(公告)日：2008-09-04

    申请号：US11814390

    申请日：2006-01-19

    申请人： Martin Ernst ,  Thilo Hahn ,  Kirsten Wenz ,  Randolf Hugo ,  Johann-Peter Melder

    发明人： Martin Ernst ,  Thilo Hahn ,  Kirsten Wenz ,  Randolf Hugo ,  Johann-Peter Melder

    IPC分类号： C07C211/27

    CPC分类号： C07C209/48 ,  C07C211/27

    摘要： A process for preparing a xylylenediamine by heterogeneously catalyzed hydrogenation of a phthalonitrile, wherein the hydrogenation is carried out in the presence of a cobalt skeletal catalyst, of an alkali metal hydroxide and of an alcohol and/or ether as the solvent, at an absolute pressure in the range from 1 to 100 bar and a temperature in the range from 40 to 150° C.

    摘要翻译： 通过邻苯二甲腈的非均相催化氢化制备苯二甲胺的方法，其中氢化是在钴骨架催化剂存在下，碱金属氢氧化物和醇和/或醚作为溶剂在绝对压力下进行的 在1至100巴的范围内，温度在40至150℃的范围内。

    Method For Producing a Xylylenediamine
    9.
    发明申请
    Method For Producing a Xylylenediamine 审中-公开
    生产甲苯二胺的方法

    公开(公告)号：US20080154061A1

    公开(公告)日：2008-06-26

    申请号：US11816878

    申请日：2006-02-23

    申请人： Martin Ernst ,  Kirsten Wenz ,  Randolf Hugo ,  Johann-Peter Melder ,  Thilo Hahn

    发明人： Martin Ernst ,  Kirsten Wenz ,  Randolf Hugo ,  Johann-Peter Melder ,  Thilo Hahn

    IPC分类号： C07C211/07

    CPC分类号： C07C209/48 ,  C07C211/27

    摘要： A process for preparing a xylylenediamine by heterogeneously catalyzed hydrogenation of a phthalonitrile, wherein the hydrogenation is carried out in the presence of a nickel catalyst, of water, of an alkali metal hydroxide and of an ether as a solvent, at an absolute pressure in the range from 1 to 100 bar, at a temperature in the range from 40 to 150° C. and without addition of ammonia.

    摘要翻译： 通过邻苯二甲腈的非均相催化氢化制备苯二甲胺的方法，其中氢化在镍催化剂存在下，水，碱金属氢氧化物和作为溶剂的醚作为溶剂在绝对压力下进行 范围为1至100巴，温度范围为40至150℃，不加氨。