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公开(公告)号：US20090131657A1
公开(公告)日：2009-05-21
申请号：US12304669
申请日：2007-06-04
IPC分类号： C07D201/02 , C07C231/12
CPC分类号： C07C231/12 , C07D207/267 , C07D209/48 , C07D223/10 , C07C233/03
摘要： The present invention relates to a process for preparing N-(1-alkenyl)carboxamides of the formula I, which comprises reacting a carboxamide of the formula II with an alkyne of the formula III in the presence of a catalyst selected from among carbonyl complexes, halides and oxides of rhenium, manganese, tungsten, molybdenum, chromium and iron.
摘要翻译： 本发明涉及一种制备式I的N-（1-烯基）甲酰胺的方法，该方法包括使式Ⅱ的羧酰胺与式III的炔在选自羰基络合物， 铼，锰，钨，钼，铬和铁的卤化物和氧化物。
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公开(公告)号：US08044233B2
公开(公告)日：2011-10-25
申请号：US12092222
申请日：2006-11-22
IPC分类号： C07C67/04 , C07C227/18
CPC分类号： C07C227/18 , B33Y70/00 , B33Y80/00 , C07C67/04 , C07C2601/14 , C07C2602/20 , C07C69/34 , C07C69/75 , C07C69/76 , C07C69/80 , C07C69/92 , C07C69/56 , C07C69/60 , C07C69/78 , C07C69/44 , C07C69/24 , C07C69/753 , C07C69/54 , C07C69/82 , C07C229/60
摘要： The present invention relates to a process for preparing vinyl carboxylates, wherein a carboxylic acid is reacted with an alkyne compound in the presence of a catalyst which is selected from carbonyl complexes, halides and oxides of rhenium, of manganese, of tungsten, of molybdenum, of chromium and of iron and rhenium metal at a temperature of ≦300° C.The process gives the desired vinyl esters with high yield.
摘要翻译： 本发明涉及一种制备乙烯基羧酸盐的方法，其中羧酸与炔化合物在选自钼，钨，钼的羰基络合物，铼的卤化物和氧化物，锰，钨的催化剂存在下反应， 的铬和铁和铼金属在300℃的温度下进行。该方法以高产率得到所需的乙烯基酯。
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公开(公告)号：US20080308765A1
公开(公告)日：2008-12-18
申请号：US12092222
申请日：2006-11-22
CPC分类号： C07C227/18 , B33Y70/00 , B33Y80/00 , C07C67/04 , C07C2601/14 , C07C2602/20 , C07C69/34 , C07C69/75 , C07C69/76 , C07C69/80 , C07C69/92 , C07C69/56 , C07C69/60 , C07C69/78 , C07C69/44 , C07C69/24 , C07C69/753 , C07C69/54 , C07C69/82 , C07C229/60
摘要： The present invention relates to a process for preparing vinyl carboxylates, wherein a carboxylic acid is reacted with an alkyne compound in the presence of a catalyst which is selected from carbonyl complexes, halides and oxides of rhenium, of manganese, of tungsten, of molybdenum, of chromium and of iron and rhenium metal at a temperature of ≦300° C.The process gives the desired vinyl esters with high yield.
摘要翻译： 本发明涉及一种制备乙烯基羧酸盐的方法，其中羧酸与炔化合物在选自钼，钨，钼的羰基络合物，铼的卤化物和氧化物，锰，钨的催化剂存在下反应， 的铬和铁和铼金属在<= 300℃的温度下进行。该方法以高产率得到所需的乙烯基酯。
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公开(公告)号：US07399876B2
公开(公告)日：2008-07-15
申请号：US10977436
申请日：2004-11-01
IPC分类号： C07F9/02
CPC分类号： C07F9/4015
摘要： Process for preparing an alkenylphosphonic acid derivative by reacting a phosphonic acid derivative with an alkyne in the presence of a catalyst complex system, wherein the catalyst complex system comprises (a) nickel, (b) a phosphine having at least two trivalent phosphorus atoms and in addition (c) a phosphine having one trivalent phosphorus atom.
摘要翻译： 在催化剂络合物体系存在下使膦酸衍生物与炔烃反应制备链烯基膦酸衍生物的方法，其中所述催化剂络合物体系包含（a）镍，（b）具有至少两个三价磷原子的膦和 加入（c）具有一个三价磷原子的膦。
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公开(公告)号：US20050113602A1
公开(公告)日：2005-05-26
申请号：US10977449
申请日：2004-11-01
CPC分类号： C07F9/4015
摘要： Process for preparing an alkenylphosphonic acid derivative by reacting a phosphonic acid derivative with an alkyne in the presence of a catalyst complex system, wherein the catalyst complex system comprises (a) nickel and (b) a phosphine having at least two trivalent phosphorus atoms and/or (c) a phosphine having one trivalent phosphorus atom and the alkyne is added only after the phosphonic acid derivative has been brought into contact with the catalyst complex system for at least one minute.
摘要翻译： 在催化剂络合物体系存在下使膦酸衍生物与炔烃反应制备烯基膦酸衍生物的方法，其中催化剂络合物体系包含（a）镍和（b）具有至少两个三价磷原子的膦和/ 或者（c）仅在使膦酸衍生物与催化剂络合物体系接触至少1分钟后才加入具有一个三价磷原子的膦和炔烃。
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公开(公告)号：US20050113593A1
公开(公告)日：2005-05-26
申请号：US10977436
申请日：2004-11-01
CPC分类号： C07F9/4015
摘要： Process for preparing an alkenylphosphonic acid derivative by reacting a phosphonic acid derivative with an alkyne in the presence of a catalyst complex system, wherein the catalyst complex system comprises (a) nickel, (b) a phosphine having at least two trivalent phosphorus atoms and in addition (c) a phosphine having one trivalent phosphorus atom.
摘要翻译： 在催化剂络合物体系存在下使膦酸衍生物与炔烃反应制备链烯基膦酸衍生物的方法，其中所述催化剂络合物体系包含（a）镍，（b）具有至少两个三价磷原子的膦和 加入（c）具有一个三价磷原子的膦。
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7.发明申请公开(公告)号：US20110034706A1
公开(公告)日：2011-02-10
申请号：US12745604
申请日：2008-11-26
申请人： Wolfgang Staffel , Stefan Kaeshammer , Roland Kessinger , Regina Vogelsang , Axel Paul , Lembit Tuttelberg
发明人： Wolfgang Staffel , Stefan Kaeshammer , Roland Kessinger , Regina Vogelsang , Axel Paul , Lembit Tuttelberg
IPC分类号： C07D207/267
CPC分类号： C07D207/267
摘要： A process for preparing N-vinylpyrrolidone by reacting 2-pyrrolidone with acetylene, wherein the 2-pyrrolidone used as a starting material (referred to hereinafter as starting 2-pyrrolidone) comprises less than 1 part by weight of γ-butyrolactone per 100 parts by weight of 2-pyrrolidone.
摘要翻译： 以2-吡咯烷酮与乙炔反应制备N-乙烯基吡咯烷酮的方法，其中用作起始原料的2-吡咯烷酮（以下简称为起始2-吡咯烷酮）包含少于1重量份的γ-丁内酯/ 100份 重量的2-吡咯烷酮。
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公开(公告)号：US20110245510A1
公开(公告)日：2011-10-06
申请号：US13129544
申请日：2009-11-12
IPC分类号： C07D207/267 , C07C231/24
CPC分类号： C07C231/24 , C07D201/16 , C07D207/267 , C07C233/05
摘要： A process for removing by-products from N-vinylamide-rich product mixtures (crude N-vinylamide), which comprises performing an extraction of the crude N-vinylamide with an organic solvent as the extractant.
摘要翻译： 一种从富含N-乙烯基酰胺的产物混合物（粗N-乙烯基酰胺）中除去副产物的方法，其包括用有机溶剂萃取剂萃取粗N-乙烯基酰胺。
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公开(公告)号：US08318968B2
公开(公告)日：2012-11-27
申请号：US12530838
申请日：2008-03-17
IPC分类号： C07F9/40
CPC分类号： C07F9/4006
摘要： Process for preparing an alkenylphosphonic acid derivative by reacting a phosphonic acid derivative with an alkyne in the presence of a complex catalyst system and a base whose conjugate acid has a pKa in dimethyl sulfoxide (25° C., 1 bar) of at least 6.
摘要翻译： 通过使膦酸衍生物与炔在复合催化剂体系的存在下与共轭酸在二甲基亚砜（25℃，1巴）中的pKa至少为6的碱反应来制备烯基膦酸衍生物的方法。
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公开(公告)号：US20060016695A1
公开(公告)日：2006-01-26
申请号：US11186100
申请日：2005-07-21
IPC分类号： C25B3/00
CPC分类号： C25B3/02
摘要： Process for preparing 2-alkyne 1-acetals of the general formula I, where the radicals have the following meanings: R1 is hydrogen, C1-C20-alkyl, C2-C20-alkenyl, C2-C20-alkynyl, C3-C12-cycloalkyl, C4-C20-cycloalkylalkyl, C4-C10-aryl, with these radicals optionally being able to be substituted by hydroxy, halogen, C1-C6-alkoxy, (C1-C6-alkoxy)carbonyl, carboxyl or nitrile groups, R2 is C1-C6-alkyl or a radical of the general formula II where R1 is as defined above, R3 has the same meaning as the radical R2, by electrochemically oxidizing a compound of the general formula III where the radical R1 has the same meaning as in the general formula I, in the presence of C1-C6-alkyl alcohols (alcohol A) or as such.
摘要翻译： 制备通式I的2-炔炔-1-缩醛的方法，其中基团具有以下含义：R 1是氢，C 1 -C 20 C 2 -C 20烷基，C 2 -C 20 - 烯基，C 2 -C 20 - 炔基 C 3 -C 12 - 环烷基，C 4 -C 20 - 环烷基烷基，C 4 C 1 -C 10 - 芳基，这些基团任选地可以被羟基，卤素，C 1 -C 6 - - 烷氧基，（C 1 -C 6 - 烷氧基）羰基，羧基或腈基，R 2是C 1 - C 1 -C 6 - 烷基或通式II的基团，其中R 1如上所定义，R 3和R 3具有相同的含义 作为基团R 2，通过电化学氧化通式III化合物，其中基团R 1具有与通式I中相同的含义，在 C 1 -C 6 - 烷基醇（醇A）或这样。
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