公开(公告)号：US06602956B2

公开(公告)日：2003-08-05

申请号：US10008866

申请日：2001-11-13

申请人： Xia Zhao ,  Hoan Tran ,  Charles G. Reid ,  Ruidong Ding

发明人： Xia Zhao ,  Hoan Tran ,  Charles G. Reid ,  Ruidong Ding

IPC分类号： C08F29900

CPC分类号： C08F8/42 ,  C08F2810/20 ,  C08F110/06 ,  C08F210/16

摘要： The melt strength is increased and the gloss level is reduced in olefinic TPE compositions through the addition of sufficient amounts of free radical generators (A) and co-curative agents (B). The free radical generators (A) include peroxides, organic peroxides, the persulfates, and the diazo compounds, and mixtures thereof. The co-curative agents (B) includes metal salts of alpha, beta-unsaturated carboxylic acids and alpha, beta-unsaturated carboxylic acids where the pending acid group has been neutralized, or mixtures thereof, and the metals for forming the metal salts of co-curative agent (B) include zinc, lithium, calcium, magnesium, sodium or aluminum, or mixtures thereof.

公开(公告)号：US06646056B2

公开(公告)日：2003-11-11

申请号：US09978126

申请日：2001-10-16

申请人： Xia Zhao ,  Hoan Tran ,  Charles G. Reid

发明人： Xia Zhao ,  Hoan Tran ,  Charles G. Reid

IPC分类号： C08L900

CPC分类号： C08L23/16 ,  C08L23/10 ,  C08L2312/00 ,  C08L2666/04

摘要： The invention relates to polymer compositions useful as thermoplastic elastomers for extrusion, calendering, blow molding, thermoforming, and foam processing, and to articles made therefrom. Such improved melt strength thermoplastic elastomers include a blend of propylenic resin (A) and ethylenic elastomer (B), wherein the (A) resin is partially branched and/or the (B) elastomer is partially crosslinked by the addition of multifunctional acrylic monomer (C) containing at least three acrylate groups.

摘要翻译： 本发明涉及可用作挤出，压延，吹塑，热成型和泡沫加工的热塑性弹性体的聚合物组合物以及由其制成的制品。 这种改进的熔融强度热塑性弹性体包括丙烯树脂（A）和乙烯类弹性体（B）的共混物，其中（A）树脂是部分支化的和/或（B）弹性体通过加入多官能丙烯酸单体 C）含有至少三个丙烯酸酯基团。

公开(公告)号：US06890990B2

公开(公告)日：2005-05-10

申请号：US10448301

申请日：2003-05-30

申请人： Kevin Cai ,  Howard Colvin ,  Charles G. Reid ,  Hoan Tran

发明人： Kevin Cai ,  Howard Colvin ,  Charles G. Reid ,  Hoan Tran

IPC分类号： C08L23/10 ,  C08L23/16 ,  C08F8/00 ,  C08L9/00 ,  C08L33/02 ,  C08L35/02 ,  C08L45/00

CPC分类号： C08L23/16 ,  C08L23/10 ,  C08L23/18 ,  C08L2312/02 ,  C08L2666/02 ,  C08L2666/06

摘要： A thermoplastic elastomer with increased oil resistance and decreased compression set compared to conventionally cured thermoplastic elastomers may be made from a dynamically vulcanized blend of propylene resin and ethylene/alpha-olefin/non-conjugated diene elastomers via a curing system containing a free radical initiator, a first co-agent including diene-containing polymers with a 1,2-vinyl content greater than 50% by weight, and a second co-agent including multifunctional acrylates containing at least two acrylate groups, multifunctional maleimides containing at least two imide groups, or mixtures of both, where the elastomer gel content in the modified blend is at least 97%.

摘要翻译： 与常规固化的热塑性弹性体相比，具有增加的耐油性和降低的压缩永久变形的热塑性弹性体可以由丙烯树脂和乙烯/α-烯烃/非共轭二烯弹性体的动态硫化共混物通过含有自由基引发剂， 包括1,2-乙烯基含量大于50重量％的含二烯烃聚合物的第一助剂和包含至少两个丙烯酸酯基团的多官能丙烯酸酯的第二助剂，含有至少两个酰亚胺基的多官能马来酰亚胺， 或两者的混合物，其中改性共混物中的弹性体凝胶含量为至少97％。

公开(公告)号：US6086792A

公开(公告)日：2000-07-11

申请号：US345061

申请日：1999-06-30

申请人： Charles G. Reid ,  Norman M. Burns, Jr.

发明人： Charles G. Reid ,  Norman M. Burns, Jr.

IPC分类号： C08L23/00 ,  C08K3/04 ,  C08L23/08 ,  C08L31/00 ,  C08L33/06 ,  H01B1/24 ,  H01B7/30 ,  H01B9/02 ,  H01B7/17

CPC分类号： H01B1/24

摘要： A semiconducting composition comprising (i) an olefinic polymer and (ii) about 25 to about 45 percent by weight, based on the weight of the composition, of a carbon black having the following properties:(a) a particle size of at least about 29 nanometers;(b) a tint strength of less than about 100 percent;(c) a loss of volatiles at 950 degrees C in a nitrogen atmosphere of less than about 1 weight percent based on the weight of the carbon black;(d) a DBP oil absorption of about 80 to about 300 cubic centimeters per 100 grams;(e) a nitrogen surface adsorption area of about 30 to about 300 square meters per gram or an iodine adsorption number of about 30 to about 300 grams per kilogram;(f) a CTAB surface area of about 30 to about 150 square meters per gram; and(g) a ratio of property (e) to property (f) of greater than about 1.1.

摘要翻译： 一种半导体组合物，其包含（i）烯属聚合物和（ii）基于组合物重量的约25至约45重量％的具有以下性质的炭黑：（a）至少约 29纳米; （b）色调强度小于约100％; （c）在氮气气氛中950℃下挥发物的损失小于约1重量％，基于炭黑的重量; （d）每100克约80至约300立方厘米的DBP吸油量; （e）约30至约300平方米/克的氮表面吸附面积或每千克约30至约300克的碘吸附数; （f）CTAB表面积约为30至150平方米/克; 和（g）性质（e）与性质（f）之比大于约1.1。

公开(公告)号：US07291677B2

公开(公告)日：2007-11-06

申请号：US10877976

申请日：2004-06-29

申请人： Kevin Cai ,  Anthony Nguyen ,  Charles G. Reid

发明人： Kevin Cai ,  Anthony Nguyen ,  Charles G. Reid

IPC分类号： C08F8/00 ,  C08L35/00 ,  C08L9/00 ,  C08L23/00 ,  C08L23/04

CPC分类号： C08L23/10 ,  C08L23/16 ,  C08L51/06 ,  C08L2312/00 ,  C08L2666/02

摘要： A thermoplastic elastomer that is adherent to polar materials may be made from a dynamically vulcanized blend of propylene resin, ethylene/alpha-olefin/non-conjugated diene elastomers, and a bonding agent via a curing system containing a free radical initiator, at least one co-agent including multifunctional acrylates containing at least two acrylate groups, multifunctional maleimides containing at least two imide groups, or mixtures of both, where the elastomer gel content in the modified blend is at least about 97 percent. Reaction mixtures, articles made therefrom, and methods of dynamically vulcanizing are also disclosed.

摘要翻译： 粘附到极性材料的热塑性弹性体可以由丙烯树脂，乙烯/α-烯烃/非共轭二烯弹性体和粘结剂通过含有自由基引发剂的固化体系的动态硫化共混物，至少一种 包括含有至少两个丙烯酸酯基团的多官能丙烯酸酯，含有至少两个酰亚胺基团的多官能马来酰亚胺或两者的混合物的共助剂，其中改性共混物中的弹性体凝胶含量为至少约97％。 还公开了反应混合物，由其制成的制品和动态硫化的方法。