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1.发明授权公开(公告)号：US08361658B2
公开(公告)日：2013-01-29
申请号：US12775185
申请日：2010-05-06
CPC分类号： H01M4/134 , H01M4/131 , H01M4/364 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/525 , H01M10/052 , H01M10/0587
摘要： A negative electrode material for non-aqueous electrolyte secondary batteries, characterized in that the negative electrode material comprises a composite particle including solid phases A and B, the solid phase A being dispersed in the solid phase B, and the ratio (IA/IB) of the maximum diffracted X-ray intensity (IA) attributed to the solid phase A to the maximum diffracted X-ray intensity (IB) attributed to the solid phase B satisfies 0.001≦IA/IB≦0.1, in terms of a diffraction line obtained by a wide-angle X-ray diffraction measurement of the composite particle.
摘要翻译： 一种非水电解质二次电池用负极材料，其特征在于，所述负极材料包括固相A和B的复合粒子，所述固相A分散在固相B中，所述比例（IA / IB） 归因于固相B的固相A的最大衍射X射线强度（IA）与归于固相B的最大衍射X射线强度（IB）的折射率相对于衍射线满足0.001≤n1E; IA / IB＆N1; 0.1 通过复合粒子的广角X射线衍射测定得到。
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公开(公告)号：US06593030B2
公开(公告)日：2003-07-15
申请号：US09798846
申请日：2001-03-01
申请人： Yasuhiko Bito , Toshitada Sato , Yoshiaki Nitta
发明人： Yasuhiko Bito , Toshitada Sato , Yoshiaki Nitta
IPC分类号： H01M438
CPC分类号： H01M4/136 , H01M4/38 , H01M4/386 , H01M4/387 , H01M10/052 , H01M2004/027
摘要： The present invention provides a rechargeable negative electrode for a non-aqueous electrolyte secondary battery comprising an alloy material which absorbs lithium during charge and desorbs lithium during discharge, and having a long cycle life. The negative electrode includes an alloy having a hexagonal closest packing structure and a Ni2In type structure composed of at least two elements.
摘要翻译： 本发明提供一种用于非水电解质二次电池的可再充电负极，其包括在充电期间吸收锂并在放电期间解吸锂并且具有长循环寿命的合金材料。 负极包括具有六边形最接近填充结构的合金和由至少两个元素组成的Ni2In型结构。
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3.发明申请公开(公告)号：US20100216033A1
公开(公告)日：2010-08-26
申请号：US12775185
申请日：2010-05-06
CPC分类号： H01M4/134 , H01M4/131 , H01M4/364 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/525 , H01M10/052 , H01M10/0587
摘要： A negative electrode material for non-aqueous electrolyte secondary batteries, characterized in that the negative electrode material comprises a composite particle including solid phases A and B, the solid phase A being dispersed in the solid phase B, and the ratio (IA/IB) of the maximum diffracted X-ray intensity (IA) attributed to the solid phase A to the maximum diffracted X-ray intensity (IB) attributed to the solid phase B satisfies 0.001≦IA/IB≦0.1, in terms of a diffraction line obtained by a wide-angle X-ray diffraction measurement of the composite particle.
摘要翻译： 一种非水电解质二次电池用负极材料，其特征在于，所述负极材料包括固相A和B的复合粒子，所述固相A分散在固相B中，所述比例（IA / IB） 归因于固相B的固相A的最大衍射X射线强度（IA）与归于固相B的最大衍射X射线强度（IB）的折射率相对于衍射线满足0.001≤n1E; IA / IB＆N1; 0.1 通过复合粒子的广角X射线衍射测定得到。
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4.发明授权公开(公告)号：US07736806B2
公开(公告)日：2010-06-15
申请号：US10508341
申请日：2003-03-17
CPC分类号： H01M4/134 , H01M4/131 , H01M4/364 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/525 , H01M10/052 , H01M10/0587
摘要： A negative electrode material for non-aqueous electrolyte secondary batteries, characterized in that the negative electrode material comprises a composite particle including solid phases A and B, the solid phase A being dispersed in the solid phase B, and the ratio (IA/IB) of the maximum diffracted X-ray intensity (IA) attributed to the solid phase A to the maximum diffracted X-ray intensity (IB) attributed to the solid phase B satisfies 0.001≦IA/IB≦0.1, in terms of a diffraction line obtained by a wide-angle X-ray diffraction measurement of the composite particle.
摘要翻译： 一种非水电解质二次电池用负极材料，其特征在于，所述负极材料包括固相A和B的复合粒子，所述固相A分散在固相B中，所述比例（IA / IB） 归因于固相B的固相A的最大衍射X射线强度（IA）与归于固相B的最大衍射X射线强度（IB）的折射率相对于衍射线满足0.001≤n1E; IA / IB＆N1; 0.1 通过复合粒子的广角X射线衍射测定得到。
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5.发明申请公开(公告)号：US20050287439A1
公开(公告)日：2005-12-29
申请号：US10508341
申请日：2003-03-17
IPC分类号： H01M4/131 , H01M4/134 , H01M4/38 , H01M4/52 , H01M4/525 , H01M10/052 , H01M10/0587 , H01M10/36 , H01M4/58
CPC分类号： H01M4/134 , H01M4/131 , H01M4/364 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/525 , H01M10/052 , H01M10/0587
摘要： The present invention relates to a negative electrode material for non-aqueous electrolyte secondary batteries, characterized in that the negative electrode material comprises a composite particle including solid phases A and B, the solid phase A being dispersed in the solid phase B, and the ratio (IA/IB) of the maximum diffracted X-ray intensity (IA) attributed to the solid phase A to the maximum diffracted X-ray intensity (IB) attributed to the solid phase B satisfies 0.001≦IA/IB≦0.1, in terms of a diffraction line obtained by a wide-angle X-ray diffraction measurement of the composite particle. This negative electrode material is capable of suppressing of pulverization thereof due to repeated cycles. Further, the use of this negative electrode material allows production of a non-aqueous electrolyte secondary battery having a high capacity and an excellent cycle life characteristic.
摘要翻译： 非水电解质二次电池用负极材料技术领域本发明涉及一种非水电解质二次电池用负极材料，其特征在于，所述负极材料包括固相A和固体B的复合粒子，固相A分散在固相B中， （固体A）的最大衍射X射线强度（I A A）的最大衍射峰值（I / A / B） 归因于固相B的X射线强度（I B B）满足0.001≤I≤A
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公开(公告)号：US06761998B2
公开(公告)日：2004-07-13
申请号：US10088398
申请日：2002-03-18
IPC分类号： H01M458
CPC分类号： H01M4/13 , B22F1/025 , B22F2998/00 , B22F2999/00 , C22C1/04 , H01M4/02 , H01M4/38 , H01M4/405 , H01M10/052 , B22F2201/10 , B22F2201/02 , B22F2201/03 , B22F9/082 , B22F2201/00
摘要： A non-aqueous electrolyte secondary battery containing an alloy particle capable of absorbing and desorbing lithium in the negative electrode has a short cycle life and is insufficient in high-rate discharge characteristics, since the alloy particle is pulverized during charge/discharge cycles. In order to solve this problem, a negative electrode is employed, which comprises an alloy particle containing: at least two selected from the group consisting of metal elements and semimetal elements; oxygen; and nitrogen. It is preferred that the alloy particle have a phase A capable of electrochemically absorbing and desorbing lithium ion and a phase B having lithium ion conductivity or lithium ion permeability and that the phase B contain larger amounts of oxygen and nitrogen than the phase A.
摘要翻译： 含有能够在负极中吸收和解吸锂的合金粒子的非水电解质二次电池由于在充放电循环中粉碎合金粒子，所以循环寿命短，高倍率放电特性不足。 为了解决这个问题，使用负极，其包括含有选自金属元素和半金属元素中的至少两种的合金粒子; 氧; 和氮气。 合金粒子优选具有电化学吸收和解吸锂离子的相A和具有锂离子传导性或锂离子渗透性的相B，并且相B含有比A相更大的氧和氮。
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公开(公告)号：US06882130B2
公开(公告)日：2005-04-19
申请号：US10451508
申请日：2002-04-17
申请人： Hiroyuki Handa , Takuya Ishii , Yasufumi Nakajima , Yasuhiko Bito , Shinji Kasamatsu , Yoshiaki Nitta
发明人： Hiroyuki Handa , Takuya Ishii , Yasufumi Nakajima , Yasuhiko Bito , Shinji Kasamatsu , Yoshiaki Nitta
CPC分类号： H02J7/0065 , H02M3/155 , H02M3/1582
摘要： The present invention provides a battery-driven electronic device for which a long time use of the battery can be achieved and mobile communications equipment such as a portable telephone. Even if the time at which the output voltage of a battery 201 becomes below the supply voltage required by a load 206 including a power amplifier for wireless communications comes earlier than a conventional lithium ion battery because of its discharge characteristics that the battery voltage change ratio is 0.25 or more, a step-up and -down converter 200 operates as follows. When the output voltage of the battery is higher than the supply voltage required by the load, the voltage is set to a predetermined supply voltage by the step-down operation mode. When the output voltage of the battery is decreased and becomes lower than the supply voltage required by the load, the voltage is set to a predetermined supply voltage by the step-up operation mode. Thus, even for a battery employing a new material having a high energy density, a long term use of the battery can be achieved.
摘要翻译： 本发明提供了一种电池驱动的电子设备，其可以实现电池的长时间使用和诸如便携式电话的移动通信设备。 即使电池201的输出电压低于包括无线通信功率放大器的负载206所需的电源电压的时间比常规的锂离子电池要早，因为其放电特性使电池电压变化率为 升压和降压转换器200如下操作。 当电池的输出电压高于负载所需的电源电压时，通过降压操作模式将电压设定为预定的电源电压。 当电池的输出电压降低并且变得低于负载所需的电源电压时，通过升压操作模式将电压设置为预定的电源电压。 因此，即使对于采用具有高能量密度的新材料的电池，也可以长期使用电池。
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8.发明授权Negative active material for lithium secondary battery and negative electrode and lithium secondary battery comprising same 有权锂二次电池和负极的负极活性物质和包含该负极的锂二次电池公开(公告)号：US08440352B2
公开(公告)日：2013-05-14
申请号：US13328888
申请日：2011-12-16
申请人： Kyou-Yoon Sheem , Sang-Jin Kim , Joon-Sup Kim , Sung-Soo Kim , Yoshiaki Nitta , Sang-Min Lee , Han-Su Kim
发明人： Kyou-Yoon Sheem , Sang-Jin Kim , Joon-Sup Kim , Sung-Soo Kim , Yoshiaki Nitta , Sang-Min Lee , Han-Su Kim
CPC分类号： H01M4/0471 , H01M4/133 , H01M4/366 , H01M4/587 , H01M10/052 , H01M10/0525 , H01M2004/021 , H01M2004/027
摘要： A negative electrode for a lithium secondary battery of the present invention includes a negative active material including a plate-shaped carbon powder particle agglomerated in a primary structure in which the plate-shaped particle is oriented in a plane direction and laminated. Fine carbon powder particles are then agglomerated to form a secondary structure on the surface of the primary structure such that the resulting particles include fine pores formed on the surface.
摘要翻译： 本发明的锂二次电池用负极包括负极活性物质，该负极活性物质包括在板状颗粒沿平面方向取向并层叠的一次结构中凝聚的板状碳粉末颗粒。 然后将细碳粉末颗粒附聚在一次结构的表面上形成二级结构，使得所得到的颗粒包括在表面上形成的细孔。
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9.发明申请CURRENT COLLECTOR FOR SECONDARY BATTERY AND SECONDARY BATTERY USING THE SAME 审中-公开用于二次电池的电流收集器和使用该电池的二次电池公开(公告)号：US20120034521A1
公开(公告)日：2012-02-09
申请号：US13263241
申请日：2010-04-09
申请人： Chizuru Matsuyama , Yasuyuki Tanaka , Takashi Honda , Shigeo Ibuka , Yoshiaki Nitta , Satoru Ichikawa , Manabu Kaseda , Tomoya Kubota , Haruyuki Saito , Keisuke Shimamoto , Kana Sato , Yukinari Kato , Hideaki Horie
发明人： Chizuru Matsuyama , Yasuyuki Tanaka , Takashi Honda , Shigeo Ibuka , Yoshiaki Nitta , Satoru Ichikawa , Manabu Kaseda , Tomoya Kubota , Haruyuki Saito , Keisuke Shimamoto , Kana Sato , Yukinari Kato , Hideaki Horie
CPC分类号： H01M4/668 , H01M4/661 , H01M4/667 , H01M10/0525 , H01M10/0583 , H01M10/0585 , Y02T10/7011
摘要： A current collector for a secondary battery (1) of the present invention includes a resin layer (2) having electrical conductivity, and an ion barrier layer (3) provided on the surface of the resin layer (2). The ion barrier layer (3) contains ion trapping particles (6) in which metal compounds (5) are provided on the surfaces of metal containing particles (4). The ion trapping particles (6) are continuously provided from an interface (7) between the resin layer (2) and the ion barrier layer (3) toward a surface (3a) of the ion barrier layer (3). Thus, the ion barrier layer (3) prevents from the entry of ions, so that the ion adsorption in the current collector (1) can be decreased.
摘要翻译： 本发明的二次电池（1）的集电体包括具有导电性的树脂层（2）和设置在树脂层（2）的表面上的离子阻挡层（3）。 离子阻挡层（3）含有金属化合物（5）设置在含金属颗粒（4）的表面上的离子捕获颗粒（6）。 从树脂层（2）和离子阻挡层（3）之间的界面（7）向离子阻挡层（3）的表面（3a）连续提供离子捕获粒子（6）。 因此，离子阻挡层（3）防止离子的入射，从而可以降低集电体（1）中的离子吸附。
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10.发明授权Negative active material for a rechargeable lithium battery, a method of preparing the same, and a rechargeable lithium battery comprising the same 有权用于可再充电锂电池的负极活性材料，其制备方法以及包含该锂电池的可再充电锂电池公开(公告)号：US07517614B2
公开(公告)日：2009-04-14
申请号：US12207366
申请日：2008-09-09
申请人： Goo-Jin Jeong , Sang-Min Lee , Sung-Soo Kim , Yoshiaki Nitta
发明人： Goo-Jin Jeong , Sang-Min Lee , Sung-Soo Kim , Yoshiaki Nitta
CPC分类号： H01M4/485 , C01B33/24 , H01M4/13 , H01M4/131 , H01M4/133 , H01M4/1391 , H01M4/1393 , H01M4/364 , H01M4/587 , H01M10/0525 , H01M10/054 , H01M2004/021
摘要： The negative active material for a rechargeable lithium battery of the present invention includes a carbonaceous material and a silicon-based compound represented by Formula 1: Si(1-y)MyO1+x(1) where 0≦y≦1, −0.5≦x≦0.5, and M is selected from the group consisting of Mg, Ca, and mixtures thereof.
摘要翻译： 本发明的可再充电锂电池的负极活性物质包括碳质材料和由式1表示的硅系化合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> Si（1-y）MyO1 + x（1）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中0 <= y <= 1，-0.5 <= x < 0.5，M选自Mg，Ca及其混合物。
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