摘要:
A softener composition, which contains tri-long-chain alkyl quaternary ammonium salt that has been considered to be difficult to use as a softener base agent, and which can provide a softener composition that provides a sufficient softening performance, is provided with (A) a cationic surfactant comprising at least one selected from the group consisting of quaternary ammonium salts represented by the formulae (I), (II) or (III), wherein the ratio of quaternary ammonium salt represented by the formula (I) to the total amount of these salts exceeds 50 weight %, with the ratio thereof represented by (III) being set to not more than 10%, and (B) at least one nonionic surfactant. In this case, (A) may include tertiary amine. (wherein, R1, R2 and R3 represent long-chain alkyl groups, etc. having total carbon atoms of 8 to 40, which may be intersected by an ether group, an ester group or an amide group; R4 represents an alkyl group, etc. having carbon atoms of 1 to 6, and X− represents an anionic group.)
摘要:
A softener composition, which contains tri-long-chain alkyl quaternary ammonium salt that has been considered to be difficult to use as a softener base agent, and which can provide a softener composition that provides a sufficient softening performance, is provided with (A) a cationic surfactant comprising at least one selected from the group consisting of quaternary ammonium salts represented by the formulae (I), (II) or (III), wherein the ratio of quaternary ammonium salt represented by the formula (I) to the total amount of these salts exceeds 50 weight %, with the ratio thereof represented by (III) being set to not more than 10%, and (B) at least one nonionic surfactant. In this case, (A) may include tertiary amine. (wherein, R1, R2 and R3 represent long-chain alkyl groups, etc. having total carbon atoms of 8 to 40, which may be intersected by an ether group, an ester group or an amide group; R4 represents an alkyl group, etc. having carbon atoms of 1 to 6, and X− represents an anionic group.)
摘要:
A softener composition, which contains tri-long-chain alkyl quaternary ammonium salt that has been considered to be difficult to use as a softener base agent, and which can provide a softener composition that provides a sufficient softening performance, is provided with (A) a cationic surfactant comprising at least one selected from the group consisting of quaternary ammonium salts represented by the formulae (I), (II) or (III), wherein the ratio of quaternary ammonium salt represented by the formula (I) to the total amount of these salts exceeds 50 weight %, with the ratio thereof represented by (III) being set to not more than 10%, and (B) at least one nonionic surfactant. In this case, (A) may include tertiary amine. (wherein, R1, R2 and R3 represent long-chain alkyl groups, etc. having total carbon atoms of 8 to 40, which may be intersected by an ether group, an ester group or an amide group; R4 represents an alkyl group, etc. having carbon atoms of 1 to 6, and X− represents an anionic group.)
摘要:
To provide a liquid softener composition which is satisfactory in respects of softening effect, storage stability and water absorption properties, is excellent in biodegradability and is gentle with the environment. A liquid softener composition comprising 3 to 40% by weight of a quaternary ammonium salt (7-I) and water ##STR1## wherein R.sup.1 represents C.sub.20 -C.sub.44 alkyl or alkenyl group; R.sup.2, R.sup.3, and R.sup.4 are the same of different from each other and are C.sub.1 -C.sub.5 alkyl or hydroxyalkyl group; Y represents C.sub.2 -C.sub.4 alkylene group; m is a number of 0 to 20; n is an integer of 1 to 6; and X.sup.- represents an anion group.
摘要:
Provided is a process for preparing a sulfuric acid amine salt (I) represented by the formula (I), which is a neutralization compound between a sulfated compound having a long chain alkyl or alkenyl group and an amine having a long chain alkyl or alkenyl group, useful as softener. wherein R31 is a linear or branched C18-36 alkyl or alkenyl group, or a group represented by the formula R36—(OA)n- (wherein R36 is a linear or branched C12-36 alkyl or alkenyl group, OA is an oxyalkylene group having 2 to 4 carbon atoms and n is a number of from 0.1 to 10 on average), R32 is a is a linear or branched C10-36 alkyl or alkenyl group, X is —CONH—, —NHCO—, —COO— or —OCO—, R33 is a linear or branched C1-6 alkylene group, R34 is a linear or branched C1-6 alkyl or hydroxyalkyl group, or a group represented by R5—[B—R6]b—, R35 is a linear or branched C1-6 alkyl or hydroxyalkyl group, wherein R5 is a linear or branched C10-36 alkyl or alkenyl group, R6 is a linear or branched C1-6 alkylene group, B is a group selected from the group consisting of —COO—, —OCO—, —CONH— and —NHCO—, b is a number of 0 or 1 and m is a number of 0 or 1. A sulfonic acid amine salt may be obtained.
摘要:
Provided is a process for preparing a sulfuric acid amine salt (I) represented by the formula (I), which is a neutralization compound between a sulfated compound having a long chain alkyl or alkenyl group and an amine having a long chain alkyl or alkenyl group, useful as softener. wherein R31 is a linear or branched C18-36 alkyl or alkenyl group, or a group represented by the formula R36−(OA)n- (wherein R36 is a linear or branched C12-36 alkyl or alkenyl group, OA is an oxyalkylene group having 2 to 4 carbon atoms and n is a number of from 0.1 to 10 on average), R32 is a is a linear or branched C10-36alkyl or alkenyl group, X is —CONH—, —NHCO—, —COO— or —OCO—, R33 is a linear or branched C1-6 alkylene group, R34 is a linear or branched C1-6 alkyl or hydroxyalkyl group, or a group represented by R5—[B—R6]b—, R35 is a linear or branched C1-6 alkyl or hydroxyalkyl group, wherein R5 is a linear or branched C10-36 alkyl or alkenyl group, R6 is a linear or branched C1-6 alkylene group, B is a group selected from the group consisting of —COO—, —OCO—, —CCNH— and —NHCO—, b is a number of 0 or 1 and m is a number of 0 or 1. A sulfonic acid amine salt may be obtained.
摘要:
Provided is a process for preparing a sulfuric acid amine salt (I) represented by the formula (I), which is a neutralization compound between a sulfated compound having a long chain alkyl or alkenyl group and an amine having a long chain alkyl or alkenyl group, useful as softener. wherein R31 is a linear or branched C18-36 alkyl or alkenyl group, or a group represented by the formula R36—(OA)n- (wherein R36 is a linear or branched C12-36 alkyl or alkenyl group, OA is an oxyalkylene group having 2 to 4 carbon atoms and n is a number of from 0.1 to 10 on average), R32 is a is a linear or branched C10-36 alkyl or alkenyl group, X is —CONH—, —NHCO—, —COO— or —OCO—, R33 is a linear or branched C1-6 alkylene group, R34 is a linear or branched C1-6 alkyl or hydroxyalkyl group, or a group represented by R5—[B—R6]b—, R35 is a linear or branched C1-6 alkyl or hydroxyalkyl group, wherein R5 is a linear or branched C10-36 alkyl or alkenyl group, R6 is a linear or branched C1-6 alkylene group, B is a group selected from the group consisting of —COO—, —OCO—, —CONH— and —NHCO—, b is a number of 0 or 1 and m is a number of 0 or 1. A sulfonic acid amine salt may be obtained.
摘要:
A liquid softener composition comprising a quaternary ammonium salt represented by the general formula (1) and a method for its preparation: ##STR1## wherein R.sup.1, R.sup.2, and R.sup.3 are an alkyl group or hydroxyalkyl group of 1 to 4 carbon atoms, R.sup.4 and R.sup.5 are an unsubstituted or hydroxyl group-substituted linear or branched alkyl group or alkenyl group of 8 to 36 carbon atoms, A is a linear or branched alkylene group of 2 or 3 carbon atoms, X is an anion group, n is an integer in the range of 1 to 6, and m is a numeral in the range of 0 to 20.
摘要:
To provide efficient table partitioning, a database is described for distributively locating a plurality of sub-tables resulting from partitioning of a table in a database. This includes an acquiring section that monitors access occurrences to each of the sub-tables to acquire a history of access occurrences. Also a deciding section decides a table storage area in which a sub-table is to be located, based on the history of access occurrences to each of the sub-tables.
摘要:
The present invention provides a method for producing polyoxyalkylene alkyl ether carboxylic acid and a salt thereof, including supplying polyoxyalkylene alkyl ether, oxygen, and water to a continuous stirred tank reactor containing a noble metal catalyst to oxidize the polyoxyalkylene alkyl ether with oxygen, in which the molar ratio of the salt of polyoxyalkylene alkyl ether carboxylic acid to the polyoxyalkylene alkyl ether in the continuous stirred tank reactor is controlled to 0.33 to 49.