公开(公告)号：US5756612A

公开(公告)日：1998-05-26

申请号：US711795

申请日：1996-09-10

申请人： Yoshiaki Aoyama ,  Norio Tomotsu

发明人： Yoshiaki Aoyama ,  Norio Tomotsu

IPC分类号： C08F4/646 ,  C08F12/04 ,  C08F12/08

CPC分类号： C08F10/00 ,  C08F12/08 ,  C08F2420/04

摘要： There is disclosed a process for producing a styrenic polymer, especially, syndiotactic polystyrene, which comprises polymerizing a styrenic monomer by the use of (a) a transition metal compound, (b) a coordination complex compound comprising an anion in which a plurality of radicals are bonded to a metal and a cation or methylaluminoxane, (c) an alkylating agent (alkyl group-containing aluminum, magnesium or zinc compound) and (d) a reaction product between a straight-chain alkylaluminum having at least two carbon atoms and water (alkylaluminoxane). The above process is capable of simplifying the production process and producing high-performance styrenic polymer having a high degree of syndiotactic configuration in high catalytic activity without deteriorating the catalyst activity, increasing the amounts of residual metals in the objective polymer or leaving the decomposition products of the alkylaluminum therein, thereby curtailing the production cost of the objective polymer.

摘要翻译： 公开了一种生产苯乙烯聚合物，特别是间同立构聚苯乙烯的方法，其包括使用（a）过渡金属化合物聚合苯乙烯单体，（b）包含阴离子的配位络合物，其中多个基团 键合到金属和阳离子或甲基铝氧烷，（c）烷基化剂（含烷基的铝，镁或锌化合物）和（d）具有至少两个碳原子的直链烷基铝和水之间的反应产物 （烷基铝氧烷）。 上述方法能够简化生产工艺，并且在不降低催化剂活性的情况下生产具有高程度间同立构构型的高性能苯乙烯聚合物，而不会降低催化剂活性，增加目标聚合物中剩余金属的量或留下分解产物 其中的烷基铝，从而抑制了目标聚合物的生产成本。

公开(公告)号：US5596055A

公开(公告)日：1997-01-21

申请号：US413224

申请日：1995-03-30

申请人： Yoshiaki Aoyama ,  Norio Tomotsu

发明人： Yoshiaki Aoyama ,  Norio Tomotsu

IPC分类号： C08F12/04 ,  C08F12/08

CPC分类号： C08F12/04 ,  C08F4/65908 ,  C08F4/6592

摘要： There is disclosed a process for producing a styrenic polymer, especially, syndiotactic polystyrene, which comprises polymerizing a styrenic monomer by the use of a (a) transition metal compound, a (b) coordination complex compound comprising an anion in which a plurality of racicals are bonded to a metal and a cation or a Lewis acid, a (c) alkylating agent (alkyl group-containing aluminum, magnesium or zinc compound) and a (d) reaction product between a straight-chain alkylaluminum having at least two carbon atoms and water (alkylaluminoxane). The above process is capable of simplifying the production process and producing high-performance styrenic polymer having a high degree of syndiotactic configuration in high catalytic activity without deteriorating the catalyst activity, increasing the amounts of residual metals in the objective polymer or leaving the decomposition products of the alkylaluminum therein, thereby curtailing the production cost of the objective polymer.

摘要翻译： 公开了一种生产苯乙烯聚合物，特别是间同立构聚苯乙烯的方法，其包括使用（a）过渡金属化合物，（b）包含阴离子的配位络合物，其中多个种类的 键合到金属和阳离子或路易斯酸，（c）烷基化剂（含烷基的铝，镁或锌化合物）和（d）在具有至少两个碳原子的直链烷基铝之间的反应产物 和水（烷基铝氧烷）。 上述方法能够简化生产工艺，并且在不降低催化剂活性的情况下生产具有高程度间同立构构型的高性能苯乙烯聚合物，而不会降低催化剂活性，增加目标聚合物中剩余金属的量或留下分解产物 其中的烷基铝，从而抑制了目标聚合物的生产成本。

公开(公告)号：USRE37064E1

公开(公告)日：2001-02-20

申请号：US09505723

申请日：2000-02-17

申请人： Yoshiaki Aoyama ,  Norio Tomotsu

发明人： Yoshiaki Aoyama ,  Norio Tomotsu

IPC分类号： C08F446

CPC分类号： C08F12/08 ,  C08F4/65908 ,  C08F4/65912 ,  C08F2410/01 ,  C08F4/6592

摘要： There is disclosed a process for producing a styrenic polymer, especially, syndiotactic polystyrene, which comprises polymerizing a styrenic monomer by the use of (a) a transition metal compound, (b) a coordination complex compound comprising an anion in which a plurality of radicals are bonded to a metal and a cation or methylaluminoxane, (c) an alkylating agent (alkyl group-containing aluminum, magnesium or zinc compound) and (d) a reaction product between a straight-chain alkylaluminum having at least two carbon atoms and water (alkylaluminoxane). The above process is capable of simplifying the production process and producing high-performance styrenic polymer having a high degree of syndiotactic configuration in high catalytic activity without deteriorating the catalyst activity, increasing the amounts of residual metals in the objective polymer or leaving the decomposition products of the alkylaluminum therein, thereby curtailing the production cost of the objective polymer.

摘要翻译： 公开了一种生产苯乙烯聚合物，特别是间同立构聚苯乙烯的方法，其包括使用（a）过渡金属化合物聚合苯乙烯单体，（b）包含阴离子的配位络合物，其中多个基团 键合到金属和阳离子或甲基铝氧烷，（c）烷基化剂（含烷基的铝，镁或锌化合物）和（d）具有至少两个碳原子的直链烷基铝和水之间的反应产物 （烷基铝氧烷）。 上述方法能够简化生产工艺，并且在不降低催化剂活性的情况下生产具有高程度间同立构构型的高性能苯乙烯聚合物，而不会降低催化剂活性，增加目标聚合物中剩余金属的量或留下分解产物 其中的烷基铝，从而抑制了目标聚合物的生产成本。

公开(公告)号：US6075102A

公开(公告)日：2000-06-13

申请号：US77319

申请日：1998-06-05

申请人： Yoshiaki Aoyama ,  Norio Tomotsu

发明人： Yoshiaki Aoyama ,  Norio Tomotsu

IPC分类号： C08F4/619 ,  C08F4/6192 ,  C08F4/642 ,  C08F4/645 ,  C08F10/00 ,  C08F12/04 ,  C08F4/02 ,  B01J31/06

CPC分类号： C08F12/08 ,  C08F4/6192 ,  C08F4/65908 ,  C08F4/65912

摘要： The present invention provides a polymerization catalyst comprising (a) a specific transition metal compound, (b) (i) a compound which can form a complex by reaction with the transition metal compound of component (a) or (ii) a specific compound containing oxygen, and optionally, (c) an alkylating agent, and a process for producing polymers in the presence of said polymerization catalyst.By using the polymerization catalyst of the present invention, decrease in the contents of residual metals in obtained polymers, simplification of the process for producing polymers, and reduction of the production cost of polymers can be achieved, and polymers having a high molecular weight can be obtained.

摘要翻译： PCT No.PCT / JP96 / 03600 Sec。 371日期：1998年6月5日 102（e）1998年6月5日PCT 1996年12月9日PCT PCT。 公开号WO97 / 21738 PCT 日期：1997年6月19日本发明提供了包含（a）特定过渡金属化合物的聚合催化剂，（b）（i）可以通过与组分（a）或（ii）的过渡金属化合物反应形成络合物的化合物 ）含氧的具体化合物，和任选的（c）烷基化剂，以及在所述聚合催化剂存在下制备聚合物的方法。 通过使用本发明的聚合催化剂，可以实现所得聚合物中残留金属含量的降低，聚合物的制造方法简化，聚合物的制造成本的降低，高分子量聚合物可以 获得。

公开(公告)号：US5807940A

公开(公告)日：1998-09-15

申请号：US669381

申请日：1996-07-11

申请人： Yoshiaki Aoyama ,  Norio Tomotsu

发明人： Yoshiaki Aoyama ,  Norio Tomotsu

IPC分类号： C08F4/54 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/642 ,  C08F4/6592 ,  C08F4/80 ,  C08F10/00 ,  C08F12/00 ,  C08F12/04 ,  C08F12/08

CPC分类号： C08F10/00 ,  C08F12/04 ,  C08F2420/04 ,  C08F4/619 ,  C08F4/61908 ,  C08F4/61912 ,  C08F4/6192 ,  C08F4/65908 ,  C08F4/65912 ,  Y10S526/943

摘要： The present invention provides a catalyst for polymerization comprising (A) a transition metal compound containing at least one linkage represented by the general formula (I): M.sup.1 --Z--C (I) wherein M.sup.1 represents a metal element of Groups 3 to 6 or the lanthanide series, and Z represents an element of Group 15, in one molecule, (B) (a) a compound which can form an ionic complex by the reaction with the transition metal compound or (b) a specific oxygen-containing compound, and (C) a metal compound containing alkyl group which is optionally used; and a process for producing a styrenic polymer, particularly a styrenic polymer having a highly syndiotactic configuration, comprising using this catalyst for polymerization. In accordance with the present invention, a novel catalyst for polymerization which has a high activity and enables reduction of the content of the residual metal in the polymer, simplification of the production process, decrease in the production cost, and improvement of physical properties of the polymer and a process which efficiently produces syndiotactic polystyrene can be provided.

摘要翻译： PCT No.PCT / JP95 / 02281 Sec。 371日期：1996年7月11日 102（e）日期1996年7月11日PCT提交1995年11月8日PCT公布。 公开号WO96 / 15160 日期：1996年5月23日本发明提供了一种聚合用催化剂，其包含（A）含有至少一个由通式（I）表示的键的过渡金属化合物：M1-ZC（I）其中M1表示第3〜 6或镧系元素，Z表示第15族的元素，在一个分子中，（B）（a）可以通过与过渡金属化合物的反应形成离子络合物的化合物或（b）特定含氧的 化合物，（C）任选使用的含有烷基的金属化合物; 以及制备苯乙烯聚合物，特别是具有高间隔构型的苯乙烯聚合物的方法，包括使用该催化剂进行聚合。 根据本发明，一种新型的聚合催化剂具有活性高，能够降低聚合物中残余金属的含量，简化生产工艺，降低生产成本，提高物理性能 聚合物和可以有效地制备间同立构聚苯乙烯的方法。

公开(公告)号：US5623034A

公开(公告)日：1997-04-22

申请号：US685981

申请日：1996-07-22

申请人： Yoshiaki Aoyama ,  Norio Tomotsu

发明人： Yoshiaki Aoyama ,  Norio Tomotsu

IPC分类号： C08F12/04 ,  C08F12/08

CPC分类号： C08F12/04 ,  C08F4/65908 ,  C08F4/65912

摘要： There is disclosed a process for producing a syndiotactic polystyrene (SPS) which comprises polymerizing a styrenic monomer having a content of indene-based compounds of at most 50 ppm by bringing a polymerization catalyst into contact with the above styrenic monomer, which catalyst preferably comprises an (A) transition metal compound (e.g. Ti compound) and (B) an (a) compound capable of reacting with the above transition metal compound (component (A)) to form an ionic complex (e.g. DMAB) or a (b) oxygen atom-containing compound (e.g. MAO), and optionally a (C) alkyl group-containing metallic compound (e.g. TIBA). By virtue of using the above styrenic monomer, the process enables to minimize the amount of the residual metals in the resultant styrenic polymer without deterioration of the catalytic activity, simplify the process and thereby curtail the production cost of SPS.

摘要翻译： 公开了间同立构聚苯乙烯（SPS）的制造方法，该方法包括使聚合催化剂与上述苯乙烯类单体接触，使含有至多50ppm的茚基化合物的苯乙烯类单体聚合，该催化剂优选含有 （A）能够与上述过渡金属化合物（组分（A））反应形成离子络合物（例如DMAB）或（b）氧化物的过渡金属化合物（例如Ti化合物）和（B） 含有原子的化合物（例如MAO）和任选的含（C）烷基金属化合物（例如TIBA）。 通过使用上述苯乙烯类单体，该方法能够使得到的苯乙烯类聚合物中残留金属的量最小化，而不会降低催化活性，简化了工艺，从而降低了SPS的生产成本。

公开(公告)号：US06815396B1

公开(公告)日：2004-11-09

申请号：US09926453

申请日：2001-11-06

申请人： Yoshiharu Tsujita ,  Norio Tomotsu

发明人： Yoshiharu Tsujita ,  Norio Tomotsu

IPC分类号： B01J2022

CPC分类号： B01J20/261 ,  B01D53/02 ,  B01D2253/202 ,  B01J20/26 ,  B01J20/3007 ,  B01J20/305 ,  C02F1/285

摘要： (1) An adsorbent comprising a styrene polymer, which is producing by dissolving a substantially syndiotactic styrene polymer in an organic compound having an affinity for the polymer, followed by shaping it, and thereafter removing the organic compound from the shaped article. (2) For producing the adsorbent (1), the polymer solution is melt-cast into the shaped article. (3) For producing the adsorbent (1) or (2), the organic compound is removed from the shaped article through evaporation under reduced pressure. The adsorbent provided herein is effective for selectively and efficiently adsorbing an organic compound in gases or liquids.

摘要翻译： （1）一种含有苯乙烯聚合物的吸附剂，其通过将基本上间同立构苯乙烯聚合物溶解在对聚合物具有亲和性的有机化合物中，然后进行成型，然后从成型制品中除去有机化合物来生产。 （2）为了制造吸附剂（1），将聚合物溶液熔融成型成型制品。 （3）为了制造吸附剂（1）或（2），通过减压蒸发从成型制品中除去有机化合物。 本文提供的吸附剂有效地选择性和有效地吸附气体或液体中的有机化合物。

公开(公告)号：US6034191A

公开(公告)日：2000-03-07

申请号：US216875

申请日：1998-12-21

申请人： Tsuyoshi Kondoh ,  Shoji Naganuma ,  Norio Tomotsu

发明人： Tsuyoshi Kondoh ,  Shoji Naganuma ,  Norio Tomotsu

IPC分类号： C07F5/06 ,  C08F4/642 ,  C08F4/643 ,  C08F4/6592 ,  C08F10/00 ,  C08F12/04 ,  C08G79/10 ,  C07F17/00 ,  B01J31/00 ,  C07F7/28

CPC分类号： C08G79/10 ,  C07F5/068 ,  C08F10/00 ,  C08F12/04 ,  C08F2420/04 ,  C08F4/65925 ,  C08F4/65927 ,  Y10S526/943

摘要： An organic aluminoxy compound which shows .sup.27 Al nuclear magnetic resonance spectrum (.sup.27 Al-NMR spectrum) having an A.sub.1 /A.sub.2 ratio of at most 0.1, wherein A.sub.1 is area of a region encompassed by a segment of a line which connects a local minimum point existing between a continuous curve "a" containing a peak appearing at around 150 ppm and a continuous curve "b" containing a peak appearing at around 60 ppm to the point where the above curve "b" comes into contact with the base line and also by the above curve "b" and A.sub.2 is area of a region encompassed by the above curves "a" and "b" and also by the base line; an organic aluminoxy compound containing at least 5%, expressed in terms of aluminum atom, of a portion insoluble in a mixed solvent of toluene and hexane in a ratio by volume of 2:5 at 30.degree. C. or lower; and a catalyst for producing a polymer comprising any of the above organic aluminoxy compounds and a transition metal compound.The above catalyst is a homogeneous catalyst having high and stable activity and used for polymerization of olefins and styrenes.

摘要翻译： 具有A1 / A2比至多为0.1的27Al核磁共振光谱（27Al-NMR光谱）的有机铝氧化合物，其中A1是由线段的区域包围的区域的面积，该区域连接存在于 包含出现在大约150ppm处的峰的连续曲线“a”和包含出现在大约60ppm处的峰到上述曲线“b”与基线接触的点的连续曲线“b” 曲线“b”上方，A2是由上述曲线“a”和“b”所包围的区域以及基线的面积; 在30℃或更低的温度下，以不溶于甲苯和己烷的混合溶剂的比例以2:5的比例含有至少5％（以铝原子表示）的有机铝氧化合物; 以及用于制备包含任何上述有机铝氧化合物和过渡金属化合物的聚合物的催化剂。 上述催化剂是具有高且稳定的活性并用于烯烃和苯乙烯聚合的均相催化剂。

公开(公告)号：US5084585A

公开(公告)日：1992-01-28

申请号：US639002

申请日：1991-01-09

申请人： Hiroshi Maezawa ,  Norio Tomotsu

发明人： Hiroshi Maezawa ,  Norio Tomotsu

IPC分类号： C07F5/06 ,  C08F4/602 ,  C08F10/00

CPC分类号： C07F5/068 ,  C08F10/00 ,  Y10S526/943

摘要： The present invention relates to a process for preparing aluminoxane which comprises reacting an organoaluminum compound and water in a solvent system containing solvent having a higher boiling point than that of the organoaluminum compound, or reacting an organoaluminum compound and water, and then adding a solvent system containing the solvent having a higher boiling point than that of the organoaluminum compound to the reaction mixture; and thereafter condensing the resulting reaction mixture under atmospheric pressure or reduced pressure.

公开(公告)号：US5010151A

公开(公告)日：1991-04-23

申请号：US581196

申请日：1990-09-11

申请人： Norio Tomotsu

发明人： Norio Tomotsu

IPC分类号： C08F4/60 ,  C08F4/62 ,  C08F4/64 ,  C08F4/69 ,  C08F10/00 ,  C08F10/02

CPC分类号： C08F10/02

摘要： A method of preparing ethylene polymers which comprises polymerizing ethylene, or ethylene and one or more .alpha.-olefins other than ethylene in the presence of a composite catalyst which catalyst comprises:(A) a solid composition prepared by depositing one or more chromium compounds and one or more metal compounds other than said chromium compounds onto an inorganic oxide support material and then calcining the resulting solid; and(B) one or more organometallic compounds that are each independently represented by the following general formula:MR.sup.1 aR.sup.2 bR.sup.3 c wherein M is a metal of Group I, II or III of the periodic table and the R.sup.1, R.sup.2 and R.sup.3 moieties are each independently hydrogen, a hydrocarbon radical of C.sub.1 -C.sub.14, or an alkoxy group of C.sub.1 -C.sub.14 with the proviso that the case that all the moieties are each equally hydrogen is excluded; and, a, b and c are each independently a real number of not less than zero with the proviso that the sum of numbers a, b and c is equal to the formal valence of metal M.