公开(公告)号：US20170240664A1

公开(公告)日：2017-08-24

申请号：US15588358

申请日：2017-05-05

申请人： MITSUI CHEMICALS, INC.

发明人： Kou TSURUGI ,  Shiori HANADA ,  Atsushi SHIBAHARA ,  Kazumori KAWAMURA ,  Fumiaki NISHINO ,  Yasuyuki HARADA ,  Wataru YAMADA ,  Akiko MATSUMOTO ,  Isao HARA ,  Tatsuya NAKAMURA ,  Toshihiro MUROTO

IPC分类号： C08F10/02

CPC分类号： C08F10/02 ,  C08F4/02 ,  C08F4/027 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65922 ,  C08F110/02 ,  C08G79/10 ,  C08F210/16 ,  C08F4/65927

摘要： An object of the invention is to provide a solid polyaluminoxane composition suitably used as a cocatalyst and a catalyst carrier in combination with an olefin oligomerization or polymerization catalyst, without the use of solid inorganic carriers such as silica. The solid polyaluminoxane composition of the invention includes a polyalkylaluminoxane and a trialkylaluminum, and has a solubility in n-hexane at 25° C. of less than 0.50 mol % as measured by a specific method (i), a solubility in toluene at 25° C. of less than 1.0 mol % as measured by a specific method (ii), and a 13 mol % or more molar fraction of alkyl groups derived from the trialkylaluminum moieties relative to the total number of moles of alkyl groups derived from the polyalkylaluminoxane moieties and the alkyl groups derived from the trialkylaluminum moieties as measured with respect to tetrahydrofuran-d8 soluble components by a specific method (iii).

公开(公告)号：US20170225155A1

公开(公告)日：2017-08-10

申请号：US15515390

申请日：2015-09-24

申请人： Sumitomo Chemical Company, Limited

发明人： Kenji SOGOH ,  Yohei KASHIWAME ,  Takahiro HINO

IPC分类号： B01J31/14 ,  B01J31/22 ,  C08F4/02 ,  C07F7/08 ,  C08G79/12 ,  B01J31/16 ,  C07F5/06

CPC分类号： B01J31/143 ,  B01J31/1616 ,  B01J31/22 ,  B01J31/2226 ,  B01J31/2295 ,  B01J2231/20 ,  B01J2531/40 ,  B01J2531/46 ,  C07C2/30 ,  C07C2/32 ,  C07F5/068 ,  C07F7/08 ,  C08F4/02 ,  C08G79/10 ,  C08G79/12

摘要： A modified solid polyalkylaluminoxane is provided, which is capable of providing α-olefin suppressing adhesion of any polymer produced as a by-product onto the reactor wall and the stirrer, and which is capable of providing a highly active olefin oligomerization reaction catalyst. An olefin oligomerization reaction catalyst containing the modified solid polyalkylaluminoxane is also provided. The modified solid polyalkylaluminoxane for olefin oligomerization reactions contains structural units represented by general formula (a) and structural units represented by general formula (b), whose median diameter is equal to or larger than 0.1 μm and equal to or smaller than 50 μm, in which R′ in the general formula (a) represents an alkyl group having 1 to 20 carbon atoms, and R″ in the general formula (b) represents a halogenated alkoxy group having 1 to 20 carbon atoms or a halogenated aryloxy group having 6 to 20 carbon atoms.

公开(公告)号：US20160222171A1

公开(公告)日：2016-08-04

申请号：US14950940

申请日：2015-11-24

申请人： THE UNIVERSITY OF CONNECTICUT

发明人： Gregory Allen Sotzing ,  Aaron Baldwin

IPC分类号： C08G79/00 ,  C08G79/14 ,  C08G79/10

CPC分类号： C08G79/00 ,  C08G63/681 ,  C08G63/81 ,  C08G79/10 ,  C08G79/14

摘要： Disclosed are transition metal or group II metal ester polymers where the metal is an alkaline earth, transition metal or aluminum; methods of manufacture, and uses thereof. The metal ester polymers exhibit both high dielectric constant and low conductivity suitable for use as dielectric insulating materials.

摘要翻译： 公开了过渡金属或II族金属酯聚合物，其中金属是碱土金属，过渡金属或铝; 制造方法及其用途。 金属酯聚合物表现出适合用作介电绝缘材料的高介电常数和低导电性。

公开(公告)号：US20150376306A1

公开(公告)日：2015-12-31

申请号：US14766396

申请日：2014-02-07

申请人： Mitsui Chemicals, Inc.

发明人： Kou TSURUGI ,  Siori HANADA ,  Atsushi SHIBAHARA ,  Kazumori KAWAMURA ,  Fumiaki NISHINO ,  Yasuyuki HARADA ,  Wataru YAMADA ,  Akiko MATSUMOTO ,  Isao HARA ,  Tatsuya NAKAMURA ,  Toshihiro MUROTO

IPC分类号： C08F110/02

CPC分类号： C08F10/02 ,  C08F4/02 ,  C08F4/027 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65922 ,  C08F110/02 ,  C08G79/10 ,  C08F210/16 ,  C08F4/65927

摘要： An object of the invention is to provide a solid polyaluminoxane composition suitably used as a cocatalyst and a catalyst carrier in combination with an olefin oligomerization or polymerization catalyst, without the use of solid inorganic carriers such as silica. The solid polyaluminoxane composition of the invention includes a polyalkylaluminoxane and a trialkylaluminum, and has a solubility in n-hexane at 25° C. of less than 0.50 mol % as measured by a specific method (i), a solubility in toluene at 25° C. of less than 1.0 mol % as measured by a specific method (ii), and a 13 mol % or more molar fraction of alkyl groups derived from the trialkylaluminum moieties relative to the total number of moles of alkyl groups derived from the polyalkylaluminoxane moieties and the alkyl groups derived from the trialkylaluminum moieties as measured with respect to tetrahydrofuran-d8 soluble components by a specific method (iii).

摘要翻译： 本发明的目的是提供一种适合用作助催化剂的固体聚铝氧烷组合物和与烯烃低聚或聚合催化剂组合的催化剂载体，而不使用固体无机载体如二氧化硅。 本发明的固体聚铝氧烷组合物包括聚烷基铝氧烷和三烷基铝，并且通过特定方法（i）测量，在25℃下在正己烷中的溶解度小于0.50mol％，在25℃下在甲苯中的溶解度 通过特定方法（ii）测量的小于1.0摩尔％的C，并且相对于衍生自多烷基铝氧烷部分的烷基的总摩尔数，衍生自三烷基铝部分的烷基的摩尔分数为13摩尔％以上 和通过特定方法（iii）测量的相对于四氢呋喃-d8可溶性成分测得的来自三烷基铝部分的烷基。

公开(公告)号：US20090226817A1

公开(公告)日：2009-09-10

申请号：US11932889

申请日：2007-10-31

申请人： Charles Austen Angell ,  Wu Xu

发明人： Charles Austen Angell ,  Wu Xu

IPC分类号： H01M6/18

CPC分类号： H01M10/052 ,  C08G65/32 ,  C08G65/328 ,  C08G79/08 ,  C08G79/10 ,  H01M10/0565 ,  H01M2300/0082 ,  H01M2300/0085 ,  Y10T29/49108

摘要： Novel chain polymers comprising weakly basic anionic moieties chemically bound into a polyether backbone at controllable anionic separations are presented. Preferred polymers comprise orthoborate anions capped with dibasic acid residues, preferably oxalato or malonato acid residues. The conductivity of these polymers is found to be high relative to that of most conventional salt-in-polymer electrolytes. The conductivity at high temperatures and wide electrochemical window make these materials especially suitable as electrolytes for rechargeable lithium batteries.

摘要翻译： 提出了包含弱碱性阴离子部分的新型链状聚合物，其以可控的阴离子分离化学键合到聚醚主链中。 优选的聚合物包括用二元酸残基（优选草酸或丙二酸残基）封端的原硼酸根阴离子。 发现这些聚合物的电导率相对于大多数常规的聚合物电解质的电导率高。 在高温和宽电化学窗口的电导率使这些材料特别适合用作可再充电锂电池的电解质。

公开(公告)号：US06800724B2

公开(公告)日：2004-10-05

申请号：US10131491

申请日：2002-04-25

申请人： Congji Zha ,  Graham Atkins

发明人： Congji Zha ,  Graham Atkins

IPC分类号： C08G6534

CPC分类号： G02B1/045 ,  C08G77/56 ,  C08G77/58 ,  C08G79/00 ,  C08G79/10 ,  C08G79/14 ,  C09D183/14 ,  G02B6/02033 ,  G02B6/1221 ,  G02B6/13 ,  G02B6/3801 ,  G02B6/4201 ,  G02B2006/12102

摘要： The present invention relates generally to a method of synthesising a metal alkoxide polymer involving the following general steps: 1. acidolysis; 2. condensation; and 3. subsequent processing. The acidolysis step is preferably performed without addition of water, in the presence of a mutual solvent. The acidolysis step involves acidolysis of a metal alkoxide compound with an acid to produce an intermediate acidolysed solution. The condensation step involves condensation of the intermediate solution in the presence of a metal alkoxide compound to produce the metal alkoxide polymer.

摘要翻译： 本发明一般涉及一种合成金属醇盐聚合物的方法，涉及以下一般步骤：1.酸解; 冷凝; 和3.后续处理。 在相互溶剂的存在下，优选不加入水来进行酸解步骤。 酸解步骤包括用酸酸解金属醇盐化合物以产生中间酸解溶液。 缩合步骤包括在金属醇盐化合物的存在下中间体溶液的缩合以制备金属醇盐聚合物。

公开(公告)号：US20040054126A1

公开(公告)日：2004-03-18

申请号：US10311643

申请日：2003-09-03

发明人： Charles A. Angell ,  Wu Xu

IPC分类号： C08G079/08

CPC分类号： H01M10/052 ,  C08G65/32 ,  C08G65/328 ,  C08G79/08 ,  C08G79/10 ,  H01M10/0565 ,  H01M2300/0082 ,  H01M2300/0085 ,  Y10T29/49108

摘要： Novel chain polymers comprising weakly basic anionic moieties chemically bound into a polyether backbone at controllable anionic separations are presented. Preferred polymers comprise orthoborate anions capped with dibasic acid residues, preferably oxalato or malonato acid residues. The conductivity of these polymers is found to be high relative to that of most conventional salt-in-polymer electrolytes. The conductivity at high temperatures and wide electrochemical window make these materials especially suitable as electrolytes for rechargeable lithium batteries.

摘要翻译： 提出了包含弱碱性阴离子部分的新型链状聚合物，其以可控的阴离子分离化学键合到聚醚主链中。 优选的聚合物包括用二元酸残基（优选草酸或丙二酸残基）封端的原硼酸根阴离子。 发现这些聚合物的电导率相对于大多数常规的聚合物电解质的电导率高。 在高温和宽电化学窗口的电导率使这些材料特别适合用作可再充电锂电池的电解质。

公开(公告)号：US5002750A

公开(公告)日：1991-03-26

申请号：US409052

申请日：1989-09-19

申请人： Hidekimi Kadokura ,  Masaji Harakawa ,  Takesi Matumoto

发明人： Hidekimi Kadokura ,  Masaji Harakawa ,  Takesi Matumoto

IPC分类号： C04B35/622 ,  C08G77/58 ,  C08G79/10 ,  D01F9/08 ,  D01F9/10

CPC分类号： D01F9/08 ,  C04B35/62245 ,  C08G77/58 ,  C08G79/10

摘要： A process for producing an alumina-based fiber, which involves mixing an aluminum compound represented by the general formula AIR.sub.1 R.sub.2 R.sub.3 (wherein R.sub.1 R.sub.2 and R.sub.3 are each an organic group or a halogen) with water in a molar ratio of ([H.sub.2 O]/[AIR.sub.1 R.sub.2 R.sub.3 ]) of 1.10 to 1.40 to produce a polyaluminoxane, mixing the polyaluminoxane with at least one silicon-containing compound in an amount such that desired alumina-based fiber has, after calcining, a silica content of up to 70%, spinning the resulting mixture of polyaluminoxane and silicon-containing compound under an atmosphere controlled at a temperature of above 28.degree. C. and a relative humidity of above 35% to obtain precursor fiber, and then calcinating the precursor fiber to obtain an alumina-based fiber.

公开(公告)号：US4886860A

公开(公告)日：1989-12-12

申请号：US326399

申请日：1989-03-17

申请人： Mikiro Arai ,  Osamu Funayama ,  Yuuji Tashiro ,  Takeshi Isoda

发明人： Mikiro Arai ,  Osamu Funayama ,  Yuuji Tashiro ,  Takeshi Isoda

IPC分类号： C04B35/571 ,  C04B35/589 ,  C08G77/58 ,  C08G77/62 ,  C08G79/00 ,  C08G79/10

CPC分类号： C08G79/00 ,  C04B35/571 ,  C04B35/589 ,  C08G77/58 ,  C08G77/62 ,  C08G79/10

摘要： A novel polymetalosilazane having a metal/silicon atomic ratio of from 0.001 to 3 and a number average molecular weight of about 200 to 500,000 is prepared by a process comprising: reacting a polysilazane having a number average molecular weight of about 100 to 500,000, which has a skelton consisting substantially of units ##STR1## at least one R being hydrogen, with a metal alkoxide in which the metal is selected from metals of the groups IIA and III to V of the Periodic Table.

摘要翻译： 金属/硅原子比为0.001〜3，数均分子量为200〜500,000的新型聚金属硅氮烷通过以下方法制备，该方法包括使数均分子量为约100〜500,000的聚硅氮烷与 基本上由单元（R 2 SiNR），至少一个R为氢的金属与金属醇盐组成，其中金属选自元素周期表IIA和III至V族的金属。

公开(公告)号：US4826934A

公开(公告)日：1989-05-02

申请号：US96527

申请日：1987-09-15

申请人： Pierre Malfroid ,  Qui L. Nguyen ,  Jean-Marie Blondin

发明人： Pierre Malfroid ,  Qui L. Nguyen ,  Jean-Marie Blondin

IPC分类号： C08F2/44 ,  C08F14/00 ,  C08F283/00 ,  C08F283/02 ,  C08F283/06 ,  C08G65/02 ,  C08G65/06 ,  C08G65/32 ,  C08G79/10

CPC分类号： C08G79/10 ,  C08F283/02 ,  C08F283/06 ,  C08G65/02

摘要： In a first stage, a heterocyclic oxygen compound is polymerized by an ionic route in a vinyl halide and, in a second stage, the vinyl halide, to which other unsaturated monomers capable of being polymerized by a radical route may be added if desired, is polymerized by a radical route in aqueous dispersion and in the presence of the polymerization mixture originating from the first stage.

摘要翻译： 在第一阶段中，杂环氧化合物在乙烯基卤化物中通过离子路线聚合，并且在第二阶段中，可以根据需要加入能够通过自由基途径聚合的其它不饱和单体的乙烯基卤化物 通过自由基途径在水分散体中聚合，并在起始于第一阶段的聚合混合物存在下进行。