摘要:
There is provided a process for producing a cyclic olefin copolymer by copolymerizing (A) ethylene and (B) a particular cyclic olefin in the presence of (C) a metallocene catalyst and (D) a small amount of an .alpha.-olefin having 3 to 20 carbon atoms. According to the said process, said copolymer can be produced at a high activity and its molecular weight can be controlled in a wide range. The copolymer produced by the said process has excellent properties inherent to the cyclic olefin copolymer.
摘要:
Provided are cycloolefin copolymer compositions comprising a hydrocarbon elastomer component substantially free from a polymerizable double bond and a cycloolefin random copolymer component obtained by copolymerization of an .alpha.-olefin of at least 2 carbon atoms and a cycloolefin in the presence of said hydrocarbon elastomer component, said composition containing said hydrocarbon elastomer component in an amount of 1-50% by weight, and a method for preparing said cycloolefin copolymer compositions.Also provided are cycloolefin copolymer compositions comprising a hydrocarbon elastomer component having a polymerizable double bond and a cycloolefin copolymer component obtained by copolymerization of an .alpha.-olefin of at least 2 carbon atoms and a cycloolefin in the presence of said hydrocarbon elastomer component, said composition containing said hydrocarbon elastomer component in an amount of 1-50% by weight.Such cycloolefin copolymer compositions as mentioned above are excellent in transparency and mechanical strength and also excellent particularly in impact resistance.In particular, when a cycloolefin elastomer obtained by copolymerization of an .alpha.-olefin of at least 2 carbon atoms, a cycloolefin and a non-conjugated diene of 5-20 carbon atoms is used as the above-mentioned hydrocarbon elastomer component having a polymerizable double bond, the resulting copolymer compositions are excellent particularly in transparency.
摘要:
Disclosed is a cycloolefin copolymer composition (C) obtained by copolymerizing an .alpha.-olefin of two or more carbon atoms (a) and a specific cycloolefin (b) in the presence of an aromatic ring-containing vinyl hydrocarbon/conjugated diene copolymer or a product of hydrogenation thereof (A) which has an intrinsic viscosity (.eta.) of 0.5 to 5.0 dl/g; at least one glass transition temperature (measured by DSC) of lower than 15.degree. C.; polymerizable carbon-to-carbon double bonds in an amount of 2 to 150 in terms of iodine value; and a refractive index n.sub.D (A) of 1.50 to 1.65. In the composition (C), the component (A) is contained in an amount of 1 to 40% by weight, and a difference .DELTA.n.sub.D between the refractive index n.sub.D (A) of the component (A) and a refractive index n.sub.D (B) of a cycloolefin copolymer component (B) obtained by copolymerizing the .alpha.-olefin (a) and the cycloolefin (b) in the absence of the component (A) is not more than 0.015. The cycloolefin copolymer composition is excellent in impact resistance, transparency and heat resistance.
摘要:
Provided are cycloolefin copolymer compositions comprising a hydrocarbon elastomer component substantially free from a polymerizable double bond and a cycloolefin random copolymer component obtained by copolymerization of an .alpha.-olefin of at least 2 carbon atoms and a cycloolefin in the presence of said hydrocarbon elastomer component, said composition containing said hydrocarbon elastomer component in an amount of 1-50% by weight, and a method for preparing said cycloolefin copolymer compositions.Also provided are cycloolefin copolymer compositions comprising a hydrocarbon elastomer component having a polymerizable double bond and a cycloolefin copolymer component obtained by copolymerization of an .alpha.-olefin of at least 2 carbon atoms and a cycloolefin in the presence of said hydrocarbon elastomer component, said composition containing said hydrocarbon elastomer component in an amount of 1-50% by weight.Such cycloolefin copolymer compositions as mentioned above are excellent in transparency and mechanical strength and also excellent particularly in impact resistance.In particular, when a cycloolefin elastomer obtained by copolymerization of an .alpha.-olefin of at least 2 carbon atoms, a cycloolefin and a non-conjugated diene of 5-20 carbon atoms is used as the above-mentioned hydrocarbon elastomer component having a polymerizable double bond, the resulting copolymer compositions are excellent particularly in transparency.
摘要:
There is provided a process for the production of a cycloolefin copolymer which comprises copolymerizing an .alpha.-olefin having 2 or more carbon atoms and a specific cycloolefin in the presence of a specific metallocene type catalyst in a solvent mixture of a hydrocarbon solvent having a solubility parameter (value of .delta.) of 7.7 [(cal/cm.sup.3).sup.1/2 ] or more and a hydrocarbon solvent having a solubility parameter (value of .delta.) of 7.5 [(cal/cm.sup.3).sup.1/2 ] or less as a polymerization solvent. A cycloolefin copolymer having a high molecular weight can be produced in a high concentration by this process at a high yield.
摘要:
There is provided a cycloolefin polymer composition comprising 8 to 40% by weight of a cycloolefin polymer [A] and 92 to 60% by weight of a cycloolefin polymer [B], both having specific properties, wherein a difference .DELTA.n.sub.D =.vertline.n.sub.D (A)-n.sub.D (B).vertline. between the refractive index n.sub.D (A) of the polymer [A] and the refractive index n.sub.D (B) of the polymer [B] is not more than 0.015. This composition is excellent in impact resistance, transparency and heat resistance, and has a good balance of these properties.There is also provided a cycloolefin copolymer composition comprising 8 to 40% by weight of a cycloolefin elastomer component [Aa] of an .alpha.-olefin, a specific cycloolefin and a non-conjugated diene which contains a polymerizable carbon-carbon double bond; and 92 to 60% by weight of a cycloolefin copolymer component [Ba] which is obtained by copolymerizing an .alpha.-olefin and a specific cycloolefin in the presence of the elastomer component [Aa]; wherein a difference .DELTA.n.sub.D =.vertline.n.sub.D (A)-n.sub.D (B).vertline. between the refractive index n.sub.D (Aa) of the component [Aa] and the refractive index n.sub.D (Ba) of the component [Ba] is not more than 0.015. This composition has excellent properties inherent in a cycloolefin random copolymer and is improved especially in impact resistance without tranding off its transparency.There is also provided a cycloolefin copolymer composition comprising 8 to 40% by weight of a cycloolefin elastomer component [A.alpha.] of an .alpha.-olefin and a specific cycloolefin which substantially contains no polymerizable carbon-carbon double bond; and 92 to 60% by weight of a cycloolefin copolymer component [B.alpha.] which is obtained by copolymerizing an .alpha.-olefin and a specific cycloolefin in the presence of the elastomer component [A.alpha.]; wherein a difference .DELTA.n.sub.D =.vertline.n.sub.D (A)-n.sub.D (B).vertline. between the refractive index n.sub.D (A.alpha.) of the component [A.alpha.] and the refractive index n.sub.D (B.alpha.) of the component [B.alpha.] is not more than 0.015. This composition has also excellent properties inherent in a cycloolefin random copolymer and is improved particularly in impact resistance without trading off its transparency.
摘要:
An eddy current flaw detection sensor is provided which can detect a circumferential crack occurring at the deformed portion or peripheral portion thereof of a heat transfer tube with a high degree of sensitivity. Two excitation coils 1a, 1b cause eddy current B to flow in the axial direction of a tubular test object 31. A detection coil 2 disposed between the excitation coils 1a, 1b detects bypass eddy current D which flows in the circumferential direction of the test object 31 while bypassing a circumferential crack E. For this purpose, the coil axes of the excitation coils 1a, 1b are directed to the radial direction of the cylindrical protection member 3 and the coil axis of the detection coil 2 is directed to the axial direction of the protection member 3.
摘要:
The touch panel has a light-transmissive upper substrate, a light-transmissive lower substrate, and a bonding layer. The lower surface of the upper substrate is formed thereon with an upper conductive layer. The top surface of the lower substrate is formed thereon with a lower conductive layer facing the upper conductive layer with an air gap. The bonding layer is formed on at least one of inner edges of the lower surface of the upper substrate and the top surface of the lower substrate, and additionally has an open groove communicating with the air gap. The makeup provides a touch panel reliably operable with a simple structure.
摘要:
A motor starts its rotation, and a clutch is operated to drive both of a first driving force transmission system for color printing, including drum gears, and a second driving force transmission system for monochrome printing, including a drum gear. The clutch is disengaged to stop the first system when a first sensor detects a mark on one photosensitive drum of the first system at the same time that a second sensor detects a mark on one drum driving gear of the first system. Next, when a third sensor detects a mark on another photosensitive drum of the second system at the same time that a fourth sensor detects a mark on another drum driving gear of the second system, the clutch is reengaged. Consequently, positionings of all the photosensitive body drums (drum gears) for color printing to the photosensitive drum (drum gear) for monochrome printing are performed without causing positional differences by inertia at the time of stop.
摘要:
The present invention provides an eddy current testing method and an eddy current testing apparatus that can reduce detection noise to increase the SN ratio thus improving the defect detection accuracy.An eddy current testing sensor includes a pair of excitation coils and a detection coil disposed therebetween. For example, a voltage regulator applies voltages having different amplitudes to the pair of excitation coils so as to reduce detection noise caused by a deformed portion of a heat exchanger tube and a tube plate in a detection signal of the detection coil. Alternatively, for example, an eddy current testing detector applies a first excitation frequency f1, at which tube material noise is reduced to negligible an amplitude, and a second excitation frequency f2, which is higher than the first excitation frequency f1, to the eddy current testing sensor. The phase and gain of a measurement waveform with the second excitation frequency f2 are adjusted and then a differential waveform of the first and second excitation frequencies f1 and f2 is obtained based on an induction voltage detected by the detection coil so as to cancel out tube expansion noise.