公开(公告)号：US5545759A

公开(公告)日：1996-08-13

申请号：US379026

申请日：1995-01-27

申请人： Yoshihiko Ikeda ,  Takeo Yamane ,  Eiichi Kaji ,  Kenji Ishimaru

发明人： Yoshihiko Ikeda ,  Takeo Yamane ,  Eiichi Kaji ,  Kenji Ishimaru

IPC分类号： C07F5/02

CPC分类号： C07F5/027

摘要： The invention relates to a production method, wherein, with 1 equivalent of pentafluorobenzene of the formula C.sub.6 HF.sub.5 M, 0.5 to 1.5 equivalents of an organometallic compound of the formula RM, wherein R is a hydrocarbon group of 1 to 10 carbon atoms and m is an alkali metal ion, are reacted at -120.degree. to 80.degree. C. in an ether type solvent, a hydrocarbon type solvent or a mixed solvent of the ether type solvent with the hydrocarbon type solvent to generate a pentafluorophenyl alkali metal salt of the formula C.sub.6 F.sub.5 M. Next, 1 equivalent of a boron compound of the formula BX.sub.3, where X is halogen, OR or NR'R" is reacted with 2.1 to 3.9 equivalents of a pentafluorophenyl alkali metal salt of the formula C.sub.6 F.sub.5 M within a temperature range from -120.degree. to 80.degree. C. to produce tris(pentafluorophenyl)borane of the formula (C.sub.6 F.sub.5).sub.3 B or a complex of tris(pentafluorophenyl)borane coordinated with the ether type solvent.

摘要翻译： 本发明涉及一种制备方法，其中使用1当量的式C 6 H 5 F 5的五氟苯，0.5至1.5当量的式R M的有机金属化合物，其中R为1至10个碳原子的烃基，m为碱 金属离子在-120至80℃下在醚类溶剂，烃类溶剂或醚型溶剂与烃类溶剂的混合溶剂中反应，生成式C 6 F 5 M的五氟苯基碱金属盐。 接下来，将1当量的式BX3的硼化合物（其中X是卤素，OR或NR'R“）与2.1至3.9当量的式C 6 F 5 M的五氟苯基碱金属盐在-120℃的温度范围内反应 至80℃以制备式（C6F5）3B的三（五氟苯基）硼烷或与醚类溶剂配位的三（五氟苯基）硼烷的络合物。

公开(公告)号：US5420355A

公开(公告)日：1995-05-30

申请号：US141546

申请日：1993-10-27

申请人： Yoshihiko Ikeda ,  Takeo Yamane ,  Eiichi Kaji ,  Kenji Ishimaru

发明人： Yoshihiko Ikeda ,  Takeo Yamane ,  Eiichi Kaji ,  Kenji Ishimaru

IPC分类号： C07F5/02 ,  C07F5/04

CPC分类号： C07F5/027

摘要： A highly pure borate complex of a trialkylborane with an alkylated or arylated alkali metal is obtained by reacting an aryl magnesium halide with a boron trihalide to produce a triarylborane product. The triarylborane product is then subjected to thorough removal of magnesium salts produced as by-products and removal of unreacted aryl magnesium halide. A solution of alkylated or arylated alkali metal in a hydrocarbon solvent, a straight chain ether solvent or a mixed solvent thereof is then added dropwise to the solution of triarylborane product in a hydrocarbon solvent, straight chain ether solvent or mixed solvent thereof, while keeping the temperature range from -80.degree. to 25.degree. C.

摘要翻译： 三烷基硼烷与烷基化或芳基化碱金属的高度纯度的硼酸盐络合物是通过芳基卤化镁与三卤化硼反应得到三芳基硼烷产物。 然后将三芳基硼烷产物彻底除去作为副产物产生的镁盐并除去未反应的芳基卤化镁。 然后将烷基化或芳基化碱金属在烃溶剂，直链醚溶剂或其混合溶剂中的溶液滴加到三芳基硼烷产物在烃溶剂，直链醚溶剂或其混合溶剂中的溶液中，同时保持 温度范围为-80°至25°C

公开(公告)号：US5362423A

公开(公告)日：1994-11-08

申请号：US169074

申请日：1993-12-20

申请人： Yoshihiko Ikeda ,  Takeo Yamane ,  Eiichi Kaji ,  Kenji Ishimaru

发明人： Yoshihiko Ikeda ,  Takeo Yamane ,  Eiichi Kaji ,  Kenji Ishimaru

IPC分类号： C07F3/02

CPC分类号： C07F3/02

摘要： Disclosed is a production method, wherein, with pentafluorobenzene represented by C.sub.6 HF.sub.5, 0.5 to 1.5 equivalents of organometallic compound represented by a general formulaR.sub.2-n MgXn(wherein n denotes a real number of 0 or 1, X denotes a halogen atom, R denotes a hydrocarbon group with carbon atoms of 1 to 10, and said hydrocarbon group may contain functional groups unaffecting the reaction) are mixed within a temperature range from -40.degree. to 250.degree. C. in an ether type solvent or a mixed nonaqueous solvent of ether type solvent with hydrocarbon type solvent and reacted at 25.degree. C. or higher to obtain pentafluorophenylmagnesium derivatives represented by a following general formula(C.sub.6 F.sub.5).sub.2-n MgXn(wherein n denotes a real number of 0 or 1 and X denotes a halogen atom).

摘要翻译： 公开了一种制备方法，其中使用由C 6 H F 5表示的五氟苯，0.5-1.5当量的由通式R2-nMgXn表示的有机金属化合物（其中n表示实数0或1，X表示卤素原子，R表示 碳原子数为1〜10的烃基，所述烃基可以含有不受反应的官能团）在-40〜250℃的温度范围内在醚型溶剂或醚型混合非水溶剂中混合 溶剂与烃型溶剂反应，并在25℃或更高温度下反应，得到由以下通式（C6F5）2-nMgXn表示的五氟苯基镁衍生物（其中n表示0或1的实数，X表示卤素原子）。

公开(公告)号：US5510536A

公开(公告)日：1996-04-23

申请号：US171639

申请日：1993-12-22

申请人： Yoshihiko Ikeda ,  Takeo Yamane ,  Eiichi Kaji ,  Kenji Ishimaru

发明人： Yoshihiko Ikeda ,  Takeo Yamane ,  Eiichi Kaji ,  Kenji Ishimaru

IPC分类号： C07F5/02 ,  C07F5/00

CPC分类号： C07F5/027

摘要： A method of producing tris(pentafluorophenyl)borane or its ether complex, using pentafluorobenzene as the source of the pentafluorophenyl group. The process comprises reacting pentafluorobenzene with an organo metallic compound (II) of the formula R.sub.2-n MgX.sub.n, wherein n denotes a real number of 0 or 1, X denotes a halogen atom and R denotes a hydrocarbon group of 1 to 10 carbon atoms. The reaction is carried out in an ether solvent at a temperature not less than 25.degree. C. The resulting pentafluorophenylmagnesium compound has the formula (C.sub.6 F.sub.5).sub.2-n MgX.sub.n (III), wherein n denotes a real number of 0 or 1 and X denotes a halogen atom. The pentafluorophenylmagnesium compound of the formula (III) is next reacted with a borane compound of the formula BX.sub.3, wherein X denotes a halogen atom. The reaction is carried out at a temperature in the range of 0.degree. C. to 250.degree. C., preferably 60.degree. C. to 250.degree. C. in an ether solvent such as tetrahydrofurane or diethyl ether, or in a non-aqueous mixture of ether solvent and hydrocarbon solvent. The ether solvent forms a complex coordinated to tris(pentafluorophenyl)borane. The complexed solvent is eliminated by either direct or indirect eliminating processes. The product may then be reacted with 1:1 equivalents of pentafluorophenyllithium to prepare tetrakis (pentafluorophenyl)borate and subsequently mixed with a solution of N,N-dimethylanilinium to produce N,N-dimethylanilinium tetrakis(pentafluorophenyl)borate crystals. The final product is very pure with purities exceeding 98 wt. %. The anilinium product is usable as an auxiliary catalyst for cationic complex polymerization.

摘要翻译： 使用五氟苯作为五氟苯基的来源生产三（五氟苯基）硼烷或其醚络合物的方法。 该方法包括使五氟苯与式R2-nMgXn的有机金属化合物（II）反应，其中n表示实数0或1，X表示卤素原子，R表示1至10个碳原子的烃基。 该反应在醚溶剂中，在不低于25℃的温度下进行。所得的五氟苯基镁化合物具有式（C6F5）2-nMgXn（III），其中n表示0或1的实数，X表示 卤素原子。 接着将式（III）的五氟苯基镁化合物与式BX3的硼烷化合物反应，其中X表示卤素原子。 反应在0℃至250℃，优选60℃至250℃的温度范围内，在醚溶剂如四氢呋喃或乙醚中进行，或在非水混合物中进行 的醚溶剂和烃溶剂。 醚溶剂形成与三（五氟苯基）硼烷配位的络合物。 通过直接或间接消除过程消除复合溶剂。 然后将产物与1:1当量的五氟苯基锂反应以制备四（五氟苯基）硼酸盐，随后与N，N-二甲基苯胺的溶液混合以产生N，N-二甲基苯胺四（五氟苯基）硼酸盐晶体。 最终产品非常纯净，纯度超过98wt。 ％。 苯胺产物可用作阳离子络合物聚合的辅助催化剂。

公开(公告)号：US5493056A

公开(公告)日：1996-02-20

申请号：US171174

申请日：1993-12-22

申请人： Yoshihiko Ikeda ,  Takeo Yamane ,  Eiichi Kaji ,  Kenji Ishimaru

发明人： Yoshihiko Ikeda ,  Takeo Yamane ,  Eiichi Kaji ,  Kenji Ishimaru

IPC分类号： C07F5/02 ,  C07C5/02

CPC分类号： C07F5/027

摘要： The invention relates to a method for producing tetrakis(pentafluorophenyl)borate derivatives of the formula (C.sub.6 F.sub.5).sub.4 BM which comprises reacting 1 equivalent of pentafluorobenzene with 0.5 to 1.5 equivalents of an organometallic compound RM at -120.degree. to 80.degree. C., in an ether type solvent, a hydrocarbon type solvent or a mixture thereof, to generate pentafluorophenyl alkali metal salt represented by the formula C.sub.6 F.sub.5 M, and then reacting either (1) not less than 3.7 equivalents of said pentafluorophenyl alkali metal salt with 1 equivalent of a boron compound BX.sub.3, or (2) not less than 0.8 equivalents of said pentafluorophenyl alkali metal salt with 1 equivalent of tris(pentafluorophenyl)borane.

摘要翻译： 本发明涉及一种制备式（C6F5）4BM的四（五氟苯基）硼酸盐衍生物的方法，其包括在-120℃至80℃下使1当量五氟苯与0.5至1.5当量的有机金属化合物RM反应， 醚型溶剂，烃类溶剂或其混合物，得到式C6F5M所示的五氟苯基碱金属盐，然后使（1）不少于3.7当量的所述五氟苯基碱金属盐与1当量的硼化合物 BX3或（2）不少于0.8当量的五氟苯基碱金属盐与1当量的三（五氟苯基）硼烷。

公开(公告)号：US5387727A

公开(公告)日：1995-02-07

申请号：US168210

申请日：1993-12-17

申请人： Yoshihiko Ikeda ,  Takeo Yamane ,  Eiichi Kaji ,  Kenji Ishimaru

发明人： Yoshihiko Ikeda ,  Takeo Yamane ,  Eiichi Kaji ,  Kenji Ishimaru

IPC分类号： C07C17/00 ,  C07C25/13 ,  C07F1/02 ,  C07F1/04

CPC分类号： C07F1/04 ,  C07C17/00 ,  C07C25/13 ,  C07F1/02

摘要： Disclosed is a production method of generating pentafluorophenyl alkali metal salt represented by a general formula C.sub.6 F.sub.5 M (M denotes an alkali metal ion) by reacting pentafluorobenzene represented by C.sub.6 HF.sub.5 with an organometallic compound represented by a general formula RM (R denotes a hydrocarbon group of 1.about.10 carbon number which may contain a functional group having no influence on the reaction.

摘要翻译： 公开了通过使由C 6 H F 5表示的五氟苯与通式RM表示的有机金属化合物（R表示1位的烃基）反应，生成由通式C 6 F 5 M表示的五氟苯基碱金属盐（M表示碱金属离子） 10碳数，其可以含有对反应没有影响的官能团。

公开(公告)号：US5488169A

公开(公告)日：1996-01-30

申请号：US170762

申请日：1993-12-21

申请人： Yoshihiko Ikeda ,  Takeo Yamane ,  Eiichi Kaji ,  Kenji Ishimaru

发明人： Yoshihiko Ikeda ,  Takeo Yamane ,  Eiichi Kaji ,  Kenji Ishimaru

IPC分类号： C07F5/02 ,  C07F9/02

CPC分类号： C07F5/027

摘要： A method of producing tetrakis(pentafluorophenyl)borate derivatives of the formula [(C.sub.6 F.sub.5).sub.4 B].sub.2-n MgX.sub.n wherein n denotes an integer of 0 or 1 and X denotes a halogen atom, using pentafluorophenylmagnesium derivatives of the formula (C.sub.6 F.sub.5).sub.2-n MgX.sub.n, wherein n denotes an integer of 0 or 1 and X denotes a halogen atom, as a source of the pentafluorophenyl group.

摘要翻译： 使用式（C6F5）4B] 2-nMgXn的四（五氟苯基）硼酸盐衍生物的方法，其中n表示0或1的整数，X表示卤素原子，使用式（C6F5）2-nMgXn的五氟苯基镁衍生物 ，其中n表示0或1的整数，X表示卤素原子作为五氟苯基的来源。

公开(公告)号：US5399780A

公开(公告)日：1995-03-21

申请号：US141545

申请日：1993-10-27

申请人： Yoshihiko Ikeda ,  Takeo Yamane ,  Eiichi Kaji ,  Kenji Ishimaru

发明人： Yoshihiko Ikeda ,  Takeo Yamane ,  Eiichi Kaji ,  Kenji Ishimaru

IPC分类号： C07F5/02

CPC分类号： C07F5/027

摘要： A method of producing a high-purity triarylborane with high yield by reacting, in a solvent inert to the reaction product, a 1.0-8.0 mol/L boron halide solution with a 0.1-3.0 mol/L aryl magnesium halide solution in a straight chain ether solvent, where the molar ratio of aryl magnesium halide to boron trihalide is 3.1-3.5 to 1.0, respectively, and then the straight chain ether solvent is distilled from the reaction mixture. Distillation crystallizes out the halogenated magnesium salt which is produced as a by-product, increasing the recovery rate of the product.

摘要翻译： 通过使反应产物惰性的溶剂中的1.0-8.0mol / L卤化硼溶液与直链中的0.1-3.0mol / L芳基卤化镁溶液反应，从而以高产率制备高纯度三芳基硼烷的方法 醚溶剂，其中芳基卤化镁与三卤化硼的摩尔比分别为3.1-3.5至1.0，然后从反应混合物中蒸馏出直链醚溶剂。 蒸馏结晶出作为副产物生成的卤化镁盐，从而提高了产品的回收率。

公开(公告)号：US08047657B2

公开(公告)日：2011-11-01

申请号：US12939976

申请日：2010-11-04

申请人： Yoshihiko Ikeda ,  Hiroki Mochizuki

发明人： Yoshihiko Ikeda ,  Hiroki Mochizuki

IPC分类号： G03B21/30 ,  G03B21/28

CPC分类号： A47F3/001

摘要： Screens are positioned at front areas of respective placing tables which form placing spaces for placing an article. Each of the screens is a transmission-type screen capable of transmitting projection image light projected on a back side of the screen. A first optical system and a second optical system are arranged inside the display shelf. The first optical system leads first partial image light, which is included in projection image light projected from a projector in the display shelf, to the back sides of the screens. And the second optical system leads second partial image light, which is included in the projection image light, to at least one of the placing spaces.

摘要翻译： 屏幕位于相应放置台的前部区域，其形成用于放置物品的放置空间。 每个屏幕是能够发射投射在屏幕背面的投影图像光的透射型屏幕。 第一光学系统和第二光学系统布置在显示架内。 第一光学系统将包括在从展示架中的投影仪投影的投影图像光中的第一部分图像光引导到屏幕的背面。 并且第二光学系统将包括在投影图像光中的第二部分图像光引导到至少一个放置空间。

公开(公告)号：US20110212362A1

公开(公告)日：2011-09-01

申请号：US13035311

申请日：2011-02-25

申请人： Keisuke Miyamori ,  Takuya Morimoto ,  Ryuji Ohshita ,  Manabu Ohtake ,  Yoshihiko Ikeda

发明人： Keisuke Miyamori ,  Takuya Morimoto ,  Ryuji Ohshita ,  Manabu Ohtake ,  Yoshihiko Ikeda

IPC分类号： H01M10/056

CPC分类号： H01M2/1653 ,  H01M2/145 ,  H01M4/131 ,  H01M4/525 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/4235 ,  H01M2300/0037

摘要： The object of the present invention is to provide a non-aqueous electrolyte secondary cell that excels in safety against overcharging and shows only a small increase in thickness during continuous charge. This object can be achieved by adopting the following configuration: a separator is used that is made of a microporous polyolefin membrane having an average pore diameter of 0.07 to 0.09 μm; a non-aqueous electrolyte contains 0.5 to 3.0 mass % of 1,3-dioxane, 0.05 to 0.3 mass % of adiponitrile, and 0.5 to 3.0 mass % of cyclohexylbenzene and/or tert-amylbenzene relative to the mass of the non-aqueous electrolyte; and preferably the non-aqueous electrolyte further contains 0.5 to 5.0 mass % of a vinylene carbonate and 0.1 to 2.0 mass % of 2-propyn-1-yl 2-(methylsulfonyloxy) propionate.

摘要翻译： 本发明的目的是提供一种在过充电时安全性优异的非水电解质二次电池，并且在连续充电期间仅显示出小的厚度增加。 该目的可以通过以下结构实现：使用由平均孔径为0.07〜0.09μm的微孔聚烯烃膜制成的隔膜; 相对于非水电解质的质量，非水电解质含有0.5〜3.0质量％的1,3-二恶烷，0.05〜0.3质量％的己二腈，0.5〜3.0质量％的环己基苯和/或叔戊基苯 ; 优选非水电解质还含有0.5〜5.0质量％的碳酸亚乙烯酯和0.1〜2.0质量％的2-丙炔-1-基甲基磺酰氧基丙酸酯。